Bioinspired Reduced Graphene Oxide Based Nanohybrids for Photocatalysis and Antibacterial Applications

Author(s):  
Mayuri S. Umekar ◽  
Ganesh S. Bhusari ◽  
Ajay K. Potbhare ◽  
Aniruddha Mondal ◽  
Bharat P. Kapgate ◽  
...  

Ultra-thin graphene has been receiving a spacious significance in the diverse sections of material science, owing to its exceptional physicochemical and thermo-mechanical characteristics. Currently, the fabrication of high-grade graphene in an economical target and green procedures area is a massive concern. Among the diverse techniques, chemical-mediated fabrication is believed to be the finest process, since it is simple, scalable, and low-priced, however, therein involved noxious or hazardous chemical reducers to produce the functional graphene-based nanocomposites (NCs). Hence, globally scientists are continuously endeavoring to adopt the bioinspired procedures to manufacture the functional reduced graphene oxide (rGO) and reduced graphene oxide-metal/metal oxide (rGO-M/MO) NCs. Hence, keeping this issue in our mind, the present review article summarizes and integrates the current state of knowledge on diverse strategies for bioinspired fabrication of rGO and rGO-M/MO NCs and their photocatalytic, antibacterial, and cytotoxicity assessments.

Metals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1078
Author(s):  
Belén Chico ◽  
Blanca Teresa Pérez-Maceda ◽  
Sara San José ◽  
María Lorenza Escudero ◽  
María Cristina García-Alonso ◽  
...  

Improvements in the lubrication of metal–metal joint prostheses are of great clinical interest in order to minimize the particles released during wear–corrosion processes. In this work, electrochemically reduced graphene oxide (ErGO) on CoCr was functionalized with hyaluronic acid (ErGOHA). Functionalization was carried out by soaking for 24 h in phosphate buffer saline (PBS) solution containing 3 g/L hyaluronic acid (HA). The corrosion performance of CoCrErGO and CoCrErGOHA surfaces was studied by electrochemical impedance spectroscopy (EIS) for 7 days in PBS. Biocompatibility and cytotoxicity were studied in mouse macrophages J774A.1 cell line by the measurement of mitochondrial activity (WST-1 assay) and plasma membrane damage (LDH assay). The inflammatory response was examined through TNF-α and IL-10 cytokines in macrophages culture supernatants, used as indicators of pro-inflammatory and anti-inflammatory responses, respectively. EIS diagrams of CoCrErGOHA revealed two time constants: the first one, attributed to the hydration and diffusion processes of the HA layer adsorbed on ErGO, and the second one, the corrosion resistance of ErGOHA/CoCr interface. Macrophage assays showed better behavior on CoCrErGOHA than CoCr and CoCrErGO surfaces based on their biocompatible, cytotoxic, and inflammatory responses. Comparative analysis of IL-10 showed that functionalization with HA induces higher values of anti-inflammatory cytokine, suggesting an improvement in inflammatory behavior.


ChemCatChem ◽  
2017 ◽  
Vol 9 (22) ◽  
pp. 4295-4300 ◽  
Author(s):  
Thazhe Veettil Vineesh ◽  
Archana Sekar ◽  
Sivamathini Rajappa ◽  
Shubhadeep Pal ◽  
Subbiah Alwarappan ◽  
...  

2020 ◽  
Author(s):  
Christos E. Athanasiou ◽  
Mok Yun Jin ◽  
Cristina Ramirez ◽  
Nitin P. Padture ◽  
Brian W. Sheldon

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