LED Light Sources in Organic Synthesis: An Entry to A Novel Approach

2021 ◽  
Vol 18 ◽  
Author(s):  
Aparna Das
Keyword(s):  
Organic Compounds ◽  
Organic Synthesis ◽  
Photochemical Reaction ◽  
Low Cost ◽  
Environmentally Friendly ◽  
Photochemical Reactions ◽  
Light Sources ◽  
Blue Led ◽  
Oxidation Reduction ◽  
Novel Approach

: In recent years, photocatalytic technology has shown great potential as a low-cost, environmentally friendly, and sustainable technology. Compared to other light sources in photochemical reaction, LEDs have advantages in terms of efficiency, power, compatibility, and environmentally-friendly nature. This review highlights the most recent advances in LED-induced photochemical reactions. The effect of white and blue LEDs in reactions such as oxidation, reduction, cycloaddition, isomerization, and sensitization is discussed in detail. No other reviews have been published on the importance of white and blue LED sources in the photocatalysis of organic compounds. Considering all the facts, this review is highly significant and timely.

scholarly journals Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Shi Cao ◽  
Wei Hong ◽  
Ziqi Ye ◽  
Lei Gong
Keyword(s):  
Asymmetric Catalysis ◽  
Organic Synthesis ◽  
Photochemical Reaction ◽  
Low Cost ◽  
Bioactive Molecules ◽  
Atom Economy ◽  
Mild Conditions ◽  
Wide Range ◽  
Unsaturated Carbonyl Compound ◽  
Direct Functionalization

AbstractThe direct and selective C(sp3)-H functionalization of cycloalkanes and alkanes is a highly useful process in organic synthesis owing to the low-cost starting materials, the high step and atom economy. Its application to asymmetric catalysis, however, has been scarcely explored. Herein, we disclose our effort toward this goal by incorporation of dual asymmetric photocatalysis by a chiral nickel catalyst and a commercially available organophotocatalyst with a radical relay strategy through sulfur dioxide insertion. Such design leads to the development of three-component asymmetric sulfonylation involving direct functionalization of cycloalkanes, alkanes, toluene derivatives or ethers. The photochemical reaction of a C(sp3)-H precursor, a SO2 surrogate and a common α,β-unsaturated carbonyl compound proceeds smoothly under mild conditions, delivering a wide range of biologically interesting α-C chiral sulfones with high regio- and enantioselectivity (>50 examples, up to >50:1 rr and 95% ee). This method is applicable to late-stage functionalization of bioactive molecules, and provides an appealing access to enantioenriched compounds starting from the abundant hydrocarbon compounds.

scholarly journals Alternative Green Extraction Phases Applied to Microextraction Techniques for Organic Compound Determination

Separations ◽  
2019 ◽  
Vol 6 (3) ◽  
pp. 35 ◽  
Author(s):  
Eduardo Carasek ◽  
Gabrieli Bernardi ◽  
Sângela N. do Carmo ◽  
Camila M.S. Vieira
Keyword(s):  
Organic Compound ◽  
Sample Preparation ◽  
Organic Compounds ◽  
Low Cost ◽  
Environmentally Friendly ◽  
New Materials ◽  
Green Extraction ◽  
Fields Of Study ◽  
Microextraction Techniques

The use of green extraction phases has gained much attention in different fields of study, including in sample preparation for the determination of organic compounds by chromatography techniques. Green extraction phases are considered as an alternative to conventional phases due to several advantages such as non-toxicity, biodegradability, low cost and ease of preparation. In addition, the use of greener extraction phases reinforces the environmentally-friendly features of microextraction techniques. Thus, this work presents a review about new materials that have been used in extraction phases applied to liquid and sorbent-based microextractions of organic compounds in different matrices.

scholarly journals On the Sustainability of Photochemical Reactions

2019 ◽  
Vol 73 (9) ◽  
pp. 720-723 ◽  
Author(s):  
Christian G. Bochet
Keyword(s):  
Uv Light ◽  
Environmentally Friendly ◽  
Photochemical Reactions ◽  
Light Sources ◽  
Photoredox Catalysis ◽  
Recent Introduction ◽  
Short Essay ◽  
A Current

Photochemical reactions are often presented as intrinsically environmentally friendly ('green'). This may be indeed the case, but only in particular circumstances. This short essay comments on various aspects of the greenness of photochemical reactions, both in a historical (when only mercury-based hard UV light sources were available) and a current (with the recent introduction of LED technology and photoredox catalysis) perspective.

Biocatalytic routes toward pharmaceutically important precursors and novel polymeric systems

2005 ◽  
Vol 77 (1) ◽  
pp. 209-226 ◽  
Author(s):  
Sunil K. Sharma ◽  
Mofazzal Husain ◽  
Rajesh Kumar ◽  
Lynne A. Samuelson ◽  
Jayant Kumar ◽  
...  
Keyword(s):  
Organic Compounds ◽  
Organic Synthesis ◽  
Organic Solvents ◽  
Low Cost ◽  
Polymeric Materials ◽  
Environmental Friendliness ◽  
Polymeric Systems ◽  
Wide Range ◽  
Synthetic Sequence

The synthetic potential of enzymes related to organic synthesis has been applied profusely, especially since the introduction of their use in organic solvents. Enzymes offer the opportunity to carry out highly chemo-, regio-, and enantioselective transformations. The use of enzymes in the synthetic sequence provides unique advantages of efficiency and environmental friendliness. Owing to their low cost and applicability to a broad range of substrates, lipases have become the most versatile class of biocatalysts in organic synthesis. We have screened a battery of lipases to carry out highly selective reactions for the synthesis of a wide range of organic compounds and polymeric materials.

scholarly journals Biosorption: A Review of the Latest Advances

Processes ◽  
2020 ◽  
Vol 8 (12) ◽  
pp. 1584
Author(s):  
Enrique Torres
Keyword(s):  
Aqueous Solutions ◽  
Organic Compounds ◽  
Emerging Contaminants ◽  
Low Cost ◽  
Environmentally Friendly ◽  
Biological Origin ◽  
Recent Advances

Biosorption is a variant of sorption techniques in which the sorbent is a material of biological origin. This technique is considered to be low cost and environmentally friendly, and it can be used to remove pollutants from aqueous solutions. The objective of this review is to report on the most significant recent works and most recent advances that have occurred in the last couple of years (2019–2020) in the field of biosorption. Biosorption of metals and organic compounds (dyes, antibiotics and other emerging contaminants) is considered in this review. In addition, the use and possibilities of different forms of biomass (live or dead, modified or immobilized) are also considered.

scholarly journals Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization

2021 ◽  
Author(s):  
Shi Cao ◽  
Wei Hong ◽  
Ziqi Ye ◽  
Lei Gong
Keyword(s):  
Asymmetric Catalysis ◽  
Organic Synthesis ◽  
Photochemical Reaction ◽  
Low Cost ◽  
Bioactive Molecules ◽  
Atom Economy ◽  
Mild Conditions ◽  
Wide Range ◽  
Unsaturated Carbonyl Compound ◽  
Direct Functionalization

Abstract The direct and selective C(sp3)-H functionalization of cycloalkanes and alkanes is a highly useful process in organic synthesis owing to the low-cost starting materials, the high step and atom economy. Its application to asymmetric catalysis, however, has been scarcely explored. Herein, we disclose our effort toward this goal by incorporation of dual asymmetric photocatalysis by a chiral nickel catalyst and a commercially available organophotocatalyst with a radical relay strategy through sulfur dioxide insertion. Such design leads to the development of three-component asymmetric sulfonylation involving direct functionalization of cycloalkanes, alkanes, toluene derivatives or ethers. The photochemical reaction of a C(sp3)-H precursor, a SO2 surrogate and a common α,β-unsaturated carbonyl compound proceeds smoothly under mild conditions, delivering a wide range of biologically interesting α-C chiral sulfones with high regio- and enantioselectivity (> 50 examples, up to > 50:1 rr and 95% ee). This method is applicable to late-stage functionalization of bioactive molecules, and provides new access to enantioenriched compounds starting from the abundant hydrocarbon compounds.

Phosphors and Fluorescent Converters in Light Sources with Blue LED Crystals

2018 ◽  
pp. 105-112 ◽  
Author(s):  
Victoriya A. Lapina ◽  
Peter P. Pershukevich ◽  
Alexei V. Trofimov ◽  
Natalya N. Trofimova ◽  
Yuri B. Tsaplev
Keyword(s):  
Quantum Dots ◽  
Organic Compounds ◽  
White Light ◽  
Coordination Compounds ◽  
Ultra Violet ◽  
Light Sources ◽  
Blue Led ◽  
Fluorescent Material ◽  
Metal Organic ◽  
Complex Coordination

The article presents a review of fluorescent material use: inorganic phosphors, organic polymeric and molecular phosphors, complex (coordination) compounds, quantum dots and frame metal-organic compounds as component materials of fluorescent converters to transform radiation of blue and ultra-violet diode crystals to white light.

BIOCATALYST FOR ENVIRONMENTALLY FRIENDLY PROCESSES OF ORGANIC SYNTHESIS AND BIODIESEL PRODUCTION

Tsitologiya ◽  
2018 ◽  
Vol 60 (7) ◽  
pp. 567-571
Author(s):  
A. I. Sidorenko ◽  
◽  
A. V. Sklyarenko ◽  
S. V. Yarotsky ◽  
◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Environmentally Friendly ◽  
Biodiesel Production

Heterogeneous System in Organic Synthesis: A Review

2020 ◽  
Vol 17 (6) ◽  
pp. 740-753
Author(s):  
Bishwajit Changmai ◽  
Gunindra Pathak ◽  
Jasha Momo H. Anal ◽  
Lalthazuala Rokhum
Keyword(s):  
Organic Synthesis ◽  
Heterogeneous System ◽  
Heterogeneous Catalysts ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Environmentally Friendly ◽  
Henry Reaction ◽  
Phase Synthesis ◽  
Recent Developments ◽  
Recovery And Reuse

Due to its inherent advantages such as easy recovery and reuse of the catalysts/ reagents, and environmentally friendly nature, the heterogeneous system has gain popularity in the realm of organic synthesis. In recent years, several chemically or biologically potent molecules are achieved through heterogeneous synthesis strategies. By recalling some of the classical fundamentals of the heterogeneous system in important organic synthesis, this mini-review outlines the recent developments in the applications heterogeneous catalysts and reagents; particularly in the solid phase synthesis, esterification and transesterification reactions to produce biodiesel, and Henry reaction.

Demonstration of environmental chemistry with microscale chemistry and a low-cost four-led based photom

2018 ◽  
Vol 16 (4) ◽  
pp. 510
Author(s):  
Wai Kin Kee ◽  
Wing Hong Chan
Keyword(s):  
Phenolic Compounds ◽  
Environmental Chemistry ◽  
Low Cost ◽  
Light Sources ◽  
Electrochemical Degradation

<span>In this article, a four-LED based photometer, in which four LEDs are used as light sources, are demonstrated to be a useful instrument for the study of pollution problems caused by phenols and of their remediation by electrochemical degradation method and the iron (II) catalyzed homogeneous Fenton’s reaction. The fate of phenols can be monitored by the photometer via the 4-aminoantipyrine method. The results revealed that the latter method was a superior method to treat the phenolic compounds.</span>

Sign in / Sign up

Export Citation Format

Share Document