BIOCATALYST FOR ENVIRONMENTALLY FRIENDLY PROCESSES OF ORGANIC SYNTHESIS AND BIODIESEL PRODUCTION

Tsitologiya ◽  
2018 ◽  
Vol 60 (7) ◽  
pp. 567-571
Author(s):  
A. I. Sidorenko ◽  
◽  
A. V. Sklyarenko ◽  
S. V. Yarotsky ◽  
◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Environmentally Friendly ◽  
Biodiesel Production

Heterogeneous System in Organic Synthesis: A Review

2020 ◽  
Vol 17 (6) ◽  
pp. 740-753
Author(s):  
Bishwajit Changmai ◽  
Gunindra Pathak ◽  
Jasha Momo H. Anal ◽  
Lalthazuala Rokhum
Keyword(s):  
Organic Synthesis ◽  
Heterogeneous System ◽  
Heterogeneous Catalysts ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Environmentally Friendly ◽  
Henry Reaction ◽  
Phase Synthesis ◽  
Recent Developments ◽  
Recovery And Reuse

Due to its inherent advantages such as easy recovery and reuse of the catalysts/ reagents, and environmentally friendly nature, the heterogeneous system has gain popularity in the realm of organic synthesis. In recent years, several chemically or biologically potent molecules are achieved through heterogeneous synthesis strategies. By recalling some of the classical fundamentals of the heterogeneous system in important organic synthesis, this mini-review outlines the recent developments in the applications heterogeneous catalysts and reagents; particularly in the solid phase synthesis, esterification and transesterification reactions to produce biodiesel, and Henry reaction.

scholarly journals Cycloaddition of Thiourea- and Guanidine-Substituted Furans to Dienophiles: A Comparison of the Environmentally-Friendly Methods

2020 ◽  
Vol 3 (1) ◽  
pp. 57
Author(s):  
Luka Barešić ◽  
Davor Margetić ◽  
Zoran Glasovac
Keyword(s):  
High Pressure ◽  
Functional Groups ◽  
Organic Synthesis ◽  
High Speed ◽  
Environmentally Friendly ◽  
Microwave Assisted ◽  
Pressure Synthesis ◽  
Ultrasound Assisted ◽  
Substituted Furans ◽  
Guanidine Moiety

The cycloaddition strategy was employed in order to obtain a 7-oxanorbornene framework substituted with a guanidine moiety or its precursor functional groups: protected amine or thiourea. In order to optimize the conditions for the cycloaddition, several environmentally-friendly methods—microwave assisted organic synthesis, high pressure synthesis, high speed vibrational milling, and ultrasound assisted synthesis—were employed. The outcomes of the cycloaddition reactions were interpreted in terms of endo/exo selectivity, the conversion of the reactants to the product, and the isolated yields. In general, our results indicated the HP and HSVM approaches as the methods of choice to give good yields and conversions.

LED Light Sources in Organic Synthesis: An Entry to A Novel Approach

2021 ◽  
Vol 18 ◽  
Author(s):  
Aparna Das
Keyword(s):  
Organic Compounds ◽  
Organic Synthesis ◽  
Photochemical Reaction ◽  
Low Cost ◽  
Environmentally Friendly ◽  
Photochemical Reactions ◽  
Light Sources ◽  
Blue Led ◽  
Oxidation Reduction ◽  
Novel Approach

: In recent years, photocatalytic technology has shown great potential as a low-cost, environmentally friendly, and sustainable technology. Compared to other light sources in photochemical reaction, LEDs have advantages in terms of efficiency, power, compatibility, and environmentally-friendly nature. This review highlights the most recent advances in LED-induced photochemical reactions. The effect of white and blue LEDs in reactions such as oxidation, reduction, cycloaddition, isomerization, and sensitization is discussed in detail. No other reviews have been published on the importance of white and blue LED sources in the photocatalysis of organic compounds. Considering all the facts, this review is highly significant and timely.

Study on the synthesis of thioamides from aldehyde N-tert-butylsulfinyl amide and sulfur in aqueous media

2021 ◽  
pp. 54-60
Author(s):  
Pham Xuan Thao
Keyword(s):  
Organic Chemistry ◽  
Metal Complex ◽  
Organic Synthesis ◽  
Noble Metal ◽  
High Temperatures ◽  
Bioactive Compounds ◽  
Plant Protection ◽  
Aqueous Media ◽  
Environmentally Friendly ◽  
Straightforward Method

Thioamides have been widely used in the fields of medicine and organic chemistry, some of which are essential bioactive compounds, plant protection agents, and drugs. It could also be used as a vulcanizing agent, an additive to lubricants and greases, and a ligand in organic synthesis. Usually, thioamide is synthesized at high temperatures or in the microwave using an expensive noble metal complex as catalysts. This paper presented a straightforward method for synthesizing thioamides by using N-tert-butylsulfinyl amide, aldehyde, and sulfur. The reaction was carried out in water, which is an environmentally friendly solvent. The reaction selectivity and yield were up to 89%.

Direct extraction of carbonyl from waste polycarbonate with amines under environmentally friendly conditions: scope of waste polycarbonate as a carbonylating agent in organic synthesis

RSC Advances ◽  
2015 ◽  
Vol 5 (5) ◽  
pp. 3454-3460 ◽  
Author(s):  
Sukhdeep Singh ◽  
Yong Lei ◽  
Andreas Schober
Keyword(s):  
Bisphenol A ◽  
Organic Synthesis ◽  
Environmentally Friendly ◽  
Direct Extraction ◽  
Green Method ◽  
Urea Derivatives

An efficient green method for converting polycarbonate into urea derivatives and bisphenol-A by sequestration of carbonyl from waste polycarbonate.

scholarly journals Use of Dimethyldioxirane in the Epoxidation of the Main Constituents of the Essential Oils Obtained from Tagetes Lucida, Cymbopogon Citratus, Lippia Alba and Eucalyptus citriodora

2011 ◽  
Vol 6 (7) ◽  
pp. 1934578X1100600 ◽  
Author(s):  
Luz A. Veloza ◽  
Lina M. Orozco ◽  
Juan C. Sepúlveda-Arias
Keyword(s):  
Essential Oils ◽  
Organic Synthesis ◽  
Oxygen Transfer ◽  
Environmentally Friendly ◽  
Acetone Solution ◽  
Oxidation Reactions ◽  
Eucalyptus Citriodora ◽  
Cymbopogon Citratus ◽  
Lippia Alba

Dimethyldioxirane (DMDO), a widely used oxidant in organic synthesis is considered an environmentally friendly oxygen transfer reagent because acetone is the only byproduct formed in its oxidation reactions. This work describes the isolation of the main constituents (terpenes) in the essential oils obtained from Tagetes lucida, Cymbopogon citratus, Lippia alba and Eucalyptus citriodora, their epoxidation with DMDO in acetone solution and the characterization of the resulting epoxides by GC-MS (EI) and NMR. This is one of the first reports involving the application of dioxirane chemistry to essential oils in order to generate modified compounds with potential uses in several areas of medicine and industry.

ChemInform Abstract: Novel Supported Solid Acid Catalysts for Environmentally Friendly Organic Synthesis

ChemInform ◽  
2001 ◽  
Vol 32 (16) ◽  
pp. no-no
Author(s):  
Karen Wilson ◽  
J. Kate Shorrock ◽  
Angelique Renson ◽  
Wolfgang Hoyer ◽  
Bertrand Gosselin ◽  
...  
Keyword(s):  
Organic Synthesis ◽  
Solid Acid ◽  
Environmentally Friendly ◽  
Solid Acid Catalysts ◽  
Acid Catalysts
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