Kinetic Study of Advanced Oxidation of Eosin Dye by Fenton's Reagent

2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Phalguni Banerjee ◽  
Sunando DasGupta ◽  
Sirshendu De
Keyword(s):  
Hydrogen Peroxide ◽  
Ferrous Sulfate ◽  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Advanced Oxidation ◽  
Fenton’S Reagent ◽  
Fenton's Reagent ◽  
Oxidation Study ◽  
Dye Decomposition ◽  
Detailed Kinetic Model

An advanced oxidation study using Fenton's reagent, i.e., ferrous sulfate and hydrogen peroxide was carried out for studying oxidation of eosin dye. Effects of concentration of various reagents on the degradation of dye were explored during an advanced oxidation process. It was found that ferrous concentration plays a major role in dye decomposition. Rate of dye decomposition is faster with an increase in ferrous sulfate concentration compared to the increase in hydrogen peroxide concentration. A detailed kinetic model was proposed. Profiles for eosin, hydrogen peroxide and various intermediates were also generated. The rate constant of the reaction of eosin with a hydroxyl radical was found to be of the order of 109 l/mol.s.

Optimizing Potable Water Reuse Systems: Chloramines or Hydrogen Peroxide for UV-Based Advanced Oxidation Process?

2019 ◽  
Vol 53 (22) ◽  
pp. 13323-13331 ◽  
Author(s):  
Kiranmayi P. Mangalgiri ◽  
Samuel Patton ◽  
Liang Wu ◽  
Shanhui Xu ◽  
Kenneth P. Ishida ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Water Reuse ◽  
Potable Water ◽  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Advanced Oxidation

Reuse of Homogeneous Fenton’s Sludge from Detergent Industry as Fenton’s Catalyst

2013 ◽  
Vol 16 (2) ◽  
Author(s):  
André F. Rossi ◽  
Rui C. Martins ◽  
Rosa M. Quinta-Ferreira
Keyword(s):  
Hydrogen Peroxide ◽  
Hydroxyl Radicals ◽  
Heterogeneous Catalysts ◽  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Iron Catalyst ◽  
Advanced Oxidation ◽  
Detergent Industry ◽  
Oxidizing Agent ◽  
Fenton’S Reaction

AbstractFenton’s reaction is an advanced oxidation process where, classically, hydrogen peroxide is the oxidizing agent and an iron catalyst promotes the formation of hydroxyl radicals (•OH). Among the studies that evaluated different metals as Fenton-like catalysts, our group of investigation has recently used cerium-based solids as heterogeneous catalysts in slurry reaction and, in this work, iron sludge coming from an industrial Fenton’s reactor used for the wastewater depuration of a detergent production factory is being appraised while treating a synthetic effluent containing 0.1 g.L

Degradation of the Pesticide Chlorpyrifos in Aqueous Solutions with UV/H2O2: Optimization and Effect of Interfering Anions

2014 ◽  
Vol 17 (1) ◽  
Author(s):  
André Gadelha de Oliveira ◽  
Jefferson Pereira Ribeiro ◽  
Juliene Tome de Oliveira ◽  
Denis De Keukeleire ◽  
Maíra Saldanha Duarte ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Solutions ◽  
Uv Radiation ◽  
Advanced Oxidation Process ◽  
Oxidation Process ◽  
Advanced Oxidation ◽  
Inorganic Anions ◽  
Pesticide Concentration ◽  
Effects Of Temperature

AbstractThis study investigates the use of an advanced oxidation process (AOP) for removal of the pesticide chlorpyrifos in a recirculated system, especially considering the effects of temperature, hydrogen peroxide dosage, pH, pesticide concentration and added inorganic anions. The results indicate that a temperature of 45 °C gave the best performance using only UV-radiation, while for the UV/H

scholarly journals Comparison of Landfill Leachate Treatment Efficiency Using the Advanced Oxidation Processes

2013 ◽  
Vol 39 (2) ◽  
pp. 107-115 ◽  
Author(s):  
Barbara Pieczykolan ◽  
Izabela Płonka ◽  
Krzysztof Barbusiński ◽  
Magdalena Amalio-Kosel
Keyword(s):  
Hydrogen Peroxide ◽  
Organic Compounds ◽  
Advanced Oxidation Processes ◽  
Potassium Dichromate ◽  
Advanced Oxidation ◽  
Fenton’S Reagent ◽  
Nitrogen And Phosphorus ◽  
Leachate Treatment ◽  
Fenton's Reagent ◽  
Oxidation Processes

Abstract Treatment of leachate from an exploited since 2004 landfill by using two methods of advanced oxidation processes was performed. Fenton’s reagent with two different doses of hydrogen peroxide and iron and UV/H2O2 process was applied. The removal efficiency of biochemically oxidizable organic compounds (BOD5), chemically oxidizable compounds using potassium dichromate (CODCr) and nutrient (nitrogen and phosphorus) was examined. Studies have shown that the greatest degree of organic compounds removal expressed as a BOD5 index and CODCr index were obtained when Fenton’s reagent with greater dose of hydrogen peroxide was used - efficiency was respectively 72.0% and 69.8%. Moreover, in this case there was observed an increase in the value of ratio of BOD5/CODCr in treated leachate in comparison with raw leachate. Application of Fenton’s reagent for leachate treatment also allowed for more effective removal of nutrients in comparison with the UV/H2O2 process.

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