scholarly journals THE INFLUENCE OF Pd IMPREGNATION INTO Al-MCM-41 ON THE CHARACTERS AND ACTIVITY FOR BIOGASOLINE PRODUCTION BY CATALYTIC HYDROCRACKING OF FAMEs FROM NYAMPLUNG SEED OIL (Calophyllum Inophyllum)

2013 ◽  
Vol 13 (2) ◽  
pp. 171-175 ◽  
Author(s):  
Hendro Juwono ◽  
Triyono Triyono ◽  
Sutarno Sutarno ◽  
Endang Tri Wahyuni
Keyword(s):  
Catalytic Activity ◽  
Fatty Acid ◽  
Surface Area ◽  
Fatty Acid Methyl Esters ◽  
Seed Oil ◽  
Methyl Esters ◽  
Research Result ◽  
Structural Morphology ◽  
Acid Methyl ◽  
Mcm 41

Biogasoline have been synthesized through catalytic hydrocracking reaction against FAMEs compounds (fatty acid methyl esters) obtained from the transesterification of Nyamplung seed oil. The performance of Al-MCM-41 and Pd/Al-MCM-41 as the catalytic hydrocracking was compared. In this research, the influence of Pd impregnation into Al-MCM-41 catalyst on the characters and catalytic activity has been evaluated. The characters determined were crystallinity by using X-Ray Diffractometer (XRD), Si/Al ratio by Inductively Coupled Plasma (ICP), the acidity by pyridine adsorption, the surface area and pore volume by surface area analyzer and the morphology by Scanning Electron Microscopy (SEM). Catalytic activity was examined for hydrocracking of free fatty acid methyl esters (FAMEs) produced from the transesterification of Nyamplung seed oil, by Hydrogen flowing. The research result showed that impregnation of Pd into Al-MCM-41 has been successfully carried out, which did not destroy the structural morphology of the catalyst. It was also discovered that the Pd impregnation could increase Si/Al ratio and the acidity but it leads to decrease in the catalyst surface area and the volume. Furthermore, Pd impregnated Al-MCM-41 showed superior activity compared to Al-MCM-41 for FAMEs hydrocracking. The superiority was indicated by higher effectiveness and yields selectiveness, that were 100% hydrocarbon composed of C9-C18 that was dominated by C12 emerging the gasoline fraction, compared of that by the results used Al-MCM-41 catalyst that were 97% hydrocarbon consisted of C8-C20 with equal abundance.

scholarly journals Production of Hydrocarbon (C7-C20) from Hydrocracking of Fatty Acid Methyl Esters on Pd/Al-MCM-41 Catalyst

2017 ◽  
Vol 12 (3) ◽  
pp. 337 ◽  
Author(s):  
Hendro Juwono ◽  
Triyono Triyono ◽  
Sutarno Sutarno ◽  
Endang Tri Wahyuni ◽  
Harmami Harmami ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Surface Area ◽  
Pore Volume ◽  
Fatty Acid Methyl Esters ◽  
Seed Oil ◽  
Methyl Esters ◽  
Hexagonal Structure ◽  
Reaction Engineering ◽  
Acid Methyl ◽  
Mcm 41

The production of hydrocarbon (C7-C20) and alcohol (C11-C19)  from fatty acid methyl esters (FAMEs) compound are produced from the transesterification of the seed oil of the Nyamplung that has been conducted by the catalytic hydrocracking using Al-MCM-41 and Pd2+-impregnated-Al-MCM-41 catalysts. The performance of catalysts were compared by various analysis including the acidity that was determined by pyridine and FTIR, the crystal structure observed by XRD, the surface area and pore volume analyzed by BET/BJH, the surface morphology observed by TEM, the metal on the surface of catalyst observed by XPS and the product of the hydrocracking analyzed by GC-MS. Hexagonal structure of the MCM-41(100) was shown in the 2θ = 3o-5o of the diffractogram. The presence of impregnated Al and Pd observed at the 2θ = 20o and 34o, respectively. The Pd/Al-MCM-41 catalyst was more acidic than Al-MCM-41 catalyst. The surface area and pore volume of the catalyst decreased after the impregnation process. The tendency of catalytic hydrocracking of hydrocarbon produced was indicated that more amount of Palladium have more hydrocarbons aliphatic than alcohol. Copyright © 2017 BCREC Group. All rights reservedReceived: 21st November 2016; Revised: 24th May 2017; Accepted: 25th May 2017; Available online: 27th October 2017; Published regularly: December 2017How to Cite: Juwono, H., Triyono, T., Sutarno, S., Wahyuni, E.T., Harmami, H., Ulfin, I., Kurniawan, F. (2017). Production of Hydrocarbon (C7-C20) from Hydrocracking of Fatty Acid Methyl Esters on Pd/Al-MCM-41 Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (3): 337-342 (doi:10.9767/bcrec.12.3.811.337-342) 

scholarly journals Synthesis, characterization and application of [CTA+]MCM-41 in the catalytic conversion of soybean oil to fatty acid methyl esters

2016 ◽  
Vol 12 (6) ◽  
pp. 4117-4126 ◽  
Author(s):  
Vinícius Kothe ◽  
Helton José Alves ◽  
Marcos Henrique Luciano Silveira ◽  
Luiz Pereira
Keyword(s):  
Catalytic Activity ◽  
Fatty Acid ◽  
Soybean Oil ◽  
Fatty Acid Methyl Esters ◽  
Methyl Esters ◽  
Solid Catalyst ◽  
Reaction Yield ◽  
Acid Methyl ◽  
Mesoporous Solids ◽  
Mcm 41

The transesterification of vegetable oil and/or animal fats in homogeneous alkaline medium is still the most widely used method for the production of biodiesel. However, this process requires raw materials with low acidity and moisture content to prevent undesirable side reactions such as saponification, which leads to emulsification and promotes losses in the reaction yield. Many solid compounds can be used in catalytic processes to reduce these limitations. Heterogeneous catalysts allow easy separation of the reaction media and have the possibility of reuse in several cycles. In this work, [CTA+]MCM-41 molecular sieves were synthesized and characterized by several methods (XRD, SEM, TGA and BET) to be applied in the methanolysis of soybean oil. The resulting materials were characterized as mesoporous solids of type IV with similar textural properties and thermal stability. The catalytic activity of [CTA+]MCM-41 in soybean oil methanolysis was analyzed by gel permeation chromatography (GPC) and the best solid catalyst was applied in a factorial design that was validated by Analysis of Variance (ANOVA). The oil:methanol molar ratio and the catalyst concentration were the variables with the highest statistical effects, with the latter showing a quadratic profile in relation to the response function. The best conversion was achieved at 343 K, 30 min and 3.75 wt % catalyst, which corresponded to a product with 99.2% in fatty acid methyl esters. Calcination caused a total loss in catalytic activity due to the removal of CTA+ cations from the mesoporous solids. Hence, such activity was associated with the formation of (SiO-)(CTA+) ion pairs at the surface of the solid catalyst

scholarly journals Biodiesel Production from Rubber Seed Oil by Transesterification Using a Co-solvent of Fatty Acid Methyl Esters

2018 ◽  
Vol 41 (5) ◽  
pp. 1013-1018 ◽  
Author(s):  
Hanh Ngoc Thi Le ◽  
Kiyoshi Imamura ◽  
Norie Watanabe ◽  
Masakazu Furuta ◽  
Norimichi Takenaka ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Fatty Acid Methyl Esters ◽  
Seed Oil ◽  
Methyl Esters ◽  
Biodiesel Production ◽  
Rubber Seed Oil ◽  
Rubber Seed ◽  
Acid Methyl

Dynamic Analysis of Phorbol Esters in the Manufacturing Process of Fatty Acid Methyl Esters from Jatropha curcas Seed Oil

2010 ◽  
Vol 88 (6) ◽  
pp. 851-861 ◽  
Author(s):  
Kosuke Ichihashi ◽  
Dai Yuki ◽  
Hiroshi Kurokawa ◽  
Akinori Igarashi ◽  
Toshio Yajima ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Dynamic Analysis ◽  
Jatropha Curcas ◽  
Manufacturing Process ◽  
Fatty Acid Methyl Esters ◽  
Seed Oil ◽  
Phorbol Esters ◽  
Methyl Esters ◽  
Acid Methyl

scholarly journals Synthesis of Azidohydrin from Hura crepitans Seed Oil: A Renewable Resource for Oleochemical Industry and Sustainable Development

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Adewale Adewuyi ◽  
Andrea Göpfert ◽  
Thomas Wolff ◽  
B. V. S. K. Rao ◽  
R. B. N. Prasad
Keyword(s):  
Fatty Acid ◽  
Fatty Acid Methyl Esters ◽  
Seed Oil ◽  
Methyl Esters ◽  
Renewable Resource ◽  
Renewable Materials ◽  
Acid Methyl ◽  
Hura Crepitans ◽  
Dominant Fatty Acid ◽  
Domestic Products

The replacement of petrochemicals by oleochemical feedstocks in many industrial and domestic applications has resulted in an increase in demand for biobased products and as such recognizing and increasing the benefits of using renewable materials. In line with this, the oil extracted from the seed of Hura crepitans was characterized by an iodine value of 120.10±0.70 g Iodine/100 g and a saponification number of 210.10±0.40 mg KOH/g with the dominant fatty acid being C18:2 (52.8±0.10%). The epoxidised fatty acid methyl esters prepared from the oil were used to synthesise the azidohydrin with a yield of 91.20%. The progress of the reaction was monitored and confirmed using FTIR and NMR. This showed the seed oil of Hura crepitans as a renewable resource that can be used to make valuable industrial and domestic products.

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