Cocoa butter equivalent from enzymatic interesterification of tea seed oil and fatty acid methyl esters

2006 ◽  
Vol 97 (4) ◽  
pp. 661-665 ◽  
Author(s):  
Hai-Xiong Wang ◽  
Hou Wu ◽  
Chi-Tang Ho ◽  
Xin-Chu Weng
2018 ◽  
Vol 41 (5) ◽  
pp. 1013-1018 ◽  
Author(s):  
Hanh Ngoc Thi Le ◽  
Kiyoshi Imamura ◽  
Norie Watanabe ◽  
Masakazu Furuta ◽  
Norimichi Takenaka ◽  
...  

2010 ◽  
Vol 88 (6) ◽  
pp. 851-861 ◽  
Author(s):  
Kosuke Ichihashi ◽  
Dai Yuki ◽  
Hiroshi Kurokawa ◽  
Akinori Igarashi ◽  
Toshio Yajima ◽  
...  

2012 ◽  
Vol 2012 ◽  
pp. 1-7 ◽  
Author(s):  
Adewale Adewuyi ◽  
Andrea Göpfert ◽  
Thomas Wolff ◽  
B. V. S. K. Rao ◽  
R. B. N. Prasad

The replacement of petrochemicals by oleochemical feedstocks in many industrial and domestic applications has resulted in an increase in demand for biobased products and as such recognizing and increasing the benefits of using renewable materials. In line with this, the oil extracted from the seed of Hura crepitans was characterized by an iodine value of 120.10±0.70 g Iodine/100 g and a saponification number of 210.10±0.40 mg KOH/g with the dominant fatty acid being C18:2 (52.8±0.10%). The epoxidised fatty acid methyl esters prepared from the oil were used to synthesise the azidohydrin with a yield of 91.20%. The progress of the reaction was monitored and confirmed using FTIR and NMR. This showed the seed oil of Hura crepitans as a renewable resource that can be used to make valuable industrial and domestic products.


Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 811
Author(s):  
Shazia Perveen ◽  
Muhammad Asif Hanif ◽  
Razyia Nadeem ◽  
Umer Rashid ◽  
Muhammad Waqar Azeem ◽  
...  

Depleting petroleum resources coupled with the environmental consequences of fossil fuel combustion have led to the search for renewable alternatives, such as biodiesel. In this study, sunflower (Helianthus annus), mustard (Brassica compestres) and pearl millet (Pennisetum americanum) seed oils were converted into biodiesel (fatty acid methyl esters) by acid-, base- and lipase-catalyzed transesterification, and the resultant fuel properties were determined. The methyl esters displayed superior iodine values (102–139), low densities, and a high cetane number (CN). The highest yield of biodiesel was obtained from mustard seed oil, which provided cloud (CP) and pour (PP) points of −3.5 and 5 °C, respectively, and a CN of 53. The sunflower seed oil methyl esters had a density of 0.81–0.86 kg/L at 16 °C, CP of 2 °C, PP of −8 °C, and a CN of 47. The pearl millet seed oil methyl esters yielded a density 0.87–0.89 kg/L, CP and PP of 4 °C and −5 °C, respectively, and a CN of 46. The major fatty acids identified in the sunflower, mustard, and pearl millet seed oils were linolenic (49.2%), oleic acid (82.2%), and linoleic acid (73.9%), respectively. The present study reports biodiesel with ideal values of CP and PP, to extend the use of biodiesel at the commercial level.


Author(s):  
Hendro Juwono ◽  
Triyono Triyono ◽  
Sutarno Sutarno ◽  
Endang Tri Wahyuni ◽  
Harmami Harmami ◽  
...  

The production of hydrocarbon (C7-C20) and alcohol (C11-C19)  from fatty acid methyl esters (FAMEs) compound are produced from the transesterification of the seed oil of the Nyamplung that has been conducted by the catalytic hydrocracking using Al-MCM-41 and Pd2+-impregnated-Al-MCM-41 catalysts. The performance of catalysts were compared by various analysis including the acidity that was determined by pyridine and FTIR, the crystal structure observed by XRD, the surface area and pore volume analyzed by BET/BJH, the surface morphology observed by TEM, the metal on the surface of catalyst observed by XPS and the product of the hydrocracking analyzed by GC-MS. Hexagonal structure of the MCM-41(100) was shown in the 2θ = 3o-5o of the diffractogram. The presence of impregnated Al and Pd observed at the 2θ = 20o and 34o, respectively. The Pd/Al-MCM-41 catalyst was more acidic than Al-MCM-41 catalyst. The surface area and pore volume of the catalyst decreased after the impregnation process. The tendency of catalytic hydrocracking of hydrocarbon produced was indicated that more amount of Palladium have more hydrocarbons aliphatic than alcohol. Copyright © 2017 BCREC Group. All rights reservedReceived: 21st November 2016; Revised: 24th May 2017; Accepted: 25th May 2017; Available online: 27th October 2017; Published regularly: December 2017How to Cite: Juwono, H., Triyono, T., Sutarno, S., Wahyuni, E.T., Harmami, H., Ulfin, I., Kurniawan, F. (2017). Production of Hydrocarbon (C7-C20) from Hydrocracking of Fatty Acid Methyl Esters on Pd/Al-MCM-41 Catalyst. Bulletin of Chemical Reaction Engineering & Catalysis, 12 (3): 337-342 (doi:10.9767/bcrec.12.3.811.337-342) 


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