THE USE OF A MONOMOLECULAR PROTECTIVE FILM ON THE SURFACE OF FRICTION UNITS TO INCREASE THE RELIABILITY OF AGRICULTURAL MACHINERY

2021 ◽  
Vol 3 (144) ◽  
pp. 155-164
Author(s):  
Ekaterina P. Parlyuk ◽  

One of the factors limiting the reliability of machines and mechanisms is the wear of the contacting surfaces of friction units, which affects their service life. To prevent it, the friction units are treated with lubricants. Surfactants containing fluorinated hydrocarbon radicals are of the greatest interest as an additive to lubricants. (Research purpose) The research purpose is in studying the effect of a protective monomolecular film of fluorinated surfactants on the processes of friction and wear occurring on the surfaces of friction units under conditions of boundary and hydrodynamic friction. (Materials and methods) The structure of the metal was studied before and after the application of a monomolecular protective film, the contact potential difference and the hardness of the samples were determined. The influence of surface energy on the oil absorption of materials was evaluated. (Results and discussion) It was revealed using the contact potential difference method, the process of applying a monomolecular protective film ends after 1.5-3.0 minutes and further exposure in the composition does not lead to a change in the contact potential difference. The values of the adhesion action and wetting energy for surfaces with this coating indicate that the surface energy does not depend on the material, but is determined by the coating of the monomolecular protective film of the test sample. The compositions of 0.05 percent of solutions of fluorinated surfactants form a more porous coating compared to the concentration of 0.5 percent. (Conclusions) Fluorinated surfactants have a high tribotechnical efficiency as antifriction and anti-wear nanomaterials. Their use makes it possible to protect the contact surfaces with a film 3-6 nm thick both under boundary and under hydrodynamic friction. The specified protective film performs the function of a "compensator" for various lubrication modes.

Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1803
Author(s):  
Zhen Zheng ◽  
Junyang An ◽  
Ruiling Gong ◽  
Yuheng Zeng ◽  
Jichun Ye ◽  
...  

In this work, we report the same trends for the contact potential difference measured by Kelvin probe force microscopy and the effective carrier lifetime on crystalline silicon (c-Si) wafers passivated by AlOx layers of different thicknesses and submitted to annealing under various conditions. The changes in contact potential difference values and in the effective carrier lifetimes of the wafers are discussed in view of structural changes of the c-Si/SiO2/AlOx interface thanks to high resolution transmission electron microscopy. Indeed, we observed the presence of a crystalline silicon oxide interfacial layer in as-deposited (200 °C) AlOx, and a phase transformation from crystalline to amorphous silicon oxide when they were annealed in vacuum at 300 °C.


2009 ◽  
Vol 20 (26) ◽  
pp. 264012 ◽  
Author(s):  
S A Burke ◽  
J M LeDue ◽  
Y Miyahara ◽  
J M Topple ◽  
S Fostner ◽  
...  

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