scholarly journals Construction of isotherms in solvent extraction of copper

2009 ◽  
Vol 63 (4) ◽  
pp. 309-312 ◽  
Author(s):  
Vladimir Cvetkovski ◽  
Vesna Conic ◽  
Milovan Vukovic ◽  
Goran Stojanovski ◽  
Milena Cvetkovska

The aim of this work is construction of equilibrium isotherms in solvent extraction. Technological parameters have been predicted for treatment of mine water by solvent extraction and electrowining. Two stages of extractions and one stage of stripping have been predicted for copper recovery by analyzing the equilibrium isotherms. The process was performed on mine water with 2,5 g/dm3 Cu2+, 3 g/dm Fe2+, pH 1,8, using 9 vol% LIX 984N in kerosene (organic solvent), with 95 and 98% stages efficiencies, respectively. This course produced an advanced electrolyte solution, suitable for electrowining and cathodic copper recovery, containing 51 g/dm3 Cu2+ and 160g/dm3 H2SO4 from a 30 g/dm3 Cu and 190 g/dm3 H2SO4.

1972 ◽  
Vol 69 (2) ◽  
pp. 257-266 ◽  
Author(s):  
Bryant Benson ◽  
Mary Jane Matthews ◽  
Alvin E. Rodin

ABSTRACT Continuing investigation of pineal gland function indicates that the anti-gonadotrophic activity of this organ cannot be attributed solely to the postulated hormone melatonin, the concentration of which is negligible in the pineal body compared to quantities required to produce unequivocal physiological effects. A non-melatonin antigonadotrophic substance recently isolated from bovine pineal glands was further purified by organic solvent extraction, ultrafiltration and gel filtration. Studies of partial blockage of compensatory ovarian hypertrophy in unilaterally ovariectomized Charles River CD-1 mice indicated that this substance is significantly more potent than melatonin in this test system.


Holzforschung ◽  
2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Xiaodi Wang ◽  
Yongchao Zhang ◽  
Luyao Wang ◽  
Xiaoju Wang ◽  
Qingxi Hou ◽  
...  

AbstractAn efficient separation technology for hydrolysates towards a full valorization of bamboo is still a tough challenge, especially regarding the lignin and lignin-carbohydrate complexes (LCCs). The present study aimed to develop a facile approach using organic solvent extraction for efficiently fractionating the main components of bamboo hydrolysates. The high-purity lignin with only a trace of carbohydrates was first obtained by precipitation of the bamboo hydrolysate. The water-soluble lignin (WSL) fraction was extracted in organic solvent through a three-stage organic solvent extraction process, and the hemicellulosic sugars with increased purity were also collected. Furthermore, a thorough characterization including various NMR techniques (31P, 13C, and 2D-HSQC), GPC, and GC-MS was conducted to the obtained lignin-rich-fractions. It was found that the WSL fraction contained abundant functional groups and tremendous amount of LCC structures. As compared to native LCC of bamboo, the WSL fraction exhibited more typical LCC linkages, i.e. phenyl glycoside linkage, which is the main type of chemical linkage between lignin and carbohydrate in both LCC samples. The results demonstrate that organic phase extraction is a highly efficient protocol for the fractionation of hydrolysate and the isolation of LCC-rich streams possessing great potential applications.


2009 ◽  
Vol 877 (18-19) ◽  
pp. 1751-1757 ◽  
Author(s):  
Zhang Ying ◽  
A Jiye ◽  
Guangji Wang ◽  
Huang Qing ◽  
Yan Bei ◽  
...  

2018 ◽  
Vol 3 (3) ◽  
pp. 2473011418S0011
Author(s):  
Marc Sokolowski ◽  
Lukas Zwicky ◽  
Christine Schweizer ◽  
Beat Hintermann

Category: Ankle Arthritis Introduction/Purpose: It has been shown that total ankle replacement (TAR) is effective in reducing pain and maintaining function in posttraumatic ankle osteoarthritis (OA). Compared to ankle fusion, TAR restores hindfoot kinematics more physiological. However, the assumption that the maintenance of ankle motion has a protective effect on the subtalar joint is still a matter of debate. Only a scarce number of long-term studies exist to support this statement.The purpose of this study was (1) to evaluate to which extent the integrity of the subtalar joint can be preserved by treating patients with a TAR, (2) to determine the rate of subtalar fusion following TAR, and (3) to determine whether the need of subsequent subtalar fusion was predictable at time of TAR. Methods: A consecutive series of 1140 primary TAR (508 female, 632 male, median age 63.5 years), performed between May 2000 and December 2015, were prospectively documented. The indication for TAR was posttraumatic OA in 78%, primary and systemic OA in 10% each, and other secondary OA in 3% of the cases. 199 subtalar joints were either fused before (n=73) or during TAR surgery (n=126), leaving 941 subtalar joints available for analysis. Radiographs before implantation and at latest follow-up were classified using the Kellgren and Lawrence Grading Score (KLS). In case of a subtalar fusion, the radiograph prior to the fusion was classified. Results: After a median radiographic follow-up of 6.1 years, the KLS remained unchanged in 66% of all cases. While it was increased by one stage in 30%, it was increased by two stages in 3%; whereas, signs of OA decreased by one stage in 1%. Cases with an increase of two stages on the KLS had a longer follow-up compared to cases without increase (p=0.047).37 cases (3.9%) underwent a subtalar joint fusion, of which the indication was progressive OA in 19 cases (51%), instability in 10 cases (27%) and others in 8 cases (22%). Subtalar joints that required a fusion after TAR did not show higher preoperative KLS than the group which did not need a subtalar joint fusion. Conclusion: Apparently, TAR protects the subtalar joint from secondary degeneration, as found in 67% with no increase in KLS. Although 33% showed an increase in the KLS, only 2% required a subtalar fusion due to progressive OA. Overall, the rate of subtalar joint fusion after TAR was low and comparable to the rates reported in the literature. Subtalar joints requiring fusion after TAR did not show higher preoperative rates of OA. Therefore, the KLS classification of subtalar OA on conventional radiographs provides only limited information about the need for postoperative subtalar fusion, and thus need to be interpreted with caution.


2021 ◽  
Vol 21 (1) ◽  
pp. 32-48
Author(s):  
Svetlana S. Popova ◽  
◽  
Hussein Ali Hussein ◽  
Lyubov’ N. Olshanskaya ◽  
Sergei V. Arzamastsev ◽  
...  

It was established that at the cathodic treatment of titanium in aqueous dimethyl sulfoxide solutions of sodium molybdate, containing phosphoric acid, at the potential of the cathodic incorporation of sodium (Ec = −2.6 V) in the potentiostatic mode, the composition formed on the electrode surface layer depended not only on the composition of the solution, but also on the volume ratio of the aqueous electrolyte solution and the organic solvent (dimethyl sulfoxide).


2002 ◽  
Vol 118 (2) ◽  
pp. 136-140
Author(s):  
Takahiro YOSHIDA ◽  
Toshimasa TAKANOHASHI ◽  
Kinya SAKANISHI ◽  
Ikuo SAITO ◽  
Masaharu FUJITA ◽  
...  

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