scholarly journals Distribution and forms of manganese in vertisols of Serbia

2011 ◽  
Vol 76 (8) ◽  
pp. 1177-1190 ◽  
Author(s):  
Jelena Milivojevic ◽  
Ivica Djalovic ◽  
Miodrag Jelic ◽  
Srecko Trifunovic ◽  
Darinka Bogdanovic ◽  
...  

Soil samples taken from the Ap horizont of arable land and meadows at ten different localities were analyzed for different forms of manganese, including total (HF), pseudo-total (HNO3), 0.1 M HClextractable and DTPA-extractable. A sequential fractional procedure was used for Mn portioning into fractions: water soluble and exchangeable Mn (I), specifically adsorbed Mn with carbonates (II), reductant releasable Mn in oxides (III), Mn bonded with organic matter (IV) and Mn structurally bonded in silicates (residual fraction) (V). Serbian vertisols have a normal Mn content, comparable with similar soils. The total (HF) and pseudo-total (HNO3) Mn contents were not correlated with soil properties, whereas the humus content positively influenced the 0.1 M HCl-extractable Mn in soil (r = 0.49

2003 ◽  
Vol 60 (1) ◽  
pp. 167-173 ◽  
Author(s):  
Clístenes Williams Araújo do Nascimento ◽  
Renildes Lúcio Ferreira Fontes ◽  
Adilson César Fortes Dias Melicio

The knowledge of the chemical forms of copper in soils and the relationships of these forms with soil copper availability are important for predicting the copper behavior in the soil-plant system. The present work studies the influence of liming on the available contents of copper as well as on the forms of copper fractions in six types of Oxisols. Soil samples, with and without liming, received copper at rates of 0.0, 20.0 and 40.0 mg dm-3 and remained incubated for 30 days. Then, available copper was extracted with Mehlich-1, Mehlich-3, DTPA and EDTA solutions, and analyzed by atomic absorption spectrophotometry. Additionally, soil samples were extracted in a sequential procedure to determine Cu in fractions of soil, as follows: exchangeable-Cu fraction, organic matter-Cu fraction, Mn oxide-Cu fraction, amorphous Fe oxide-Cu fraction, crystalline Fe oxide-Cu fraction, residual-Cu fraction, and the total Cu content in the soil. Soil samples to which Cu was added presented higher Cu retention in the organic matter fraction with a small percentage retained in the exchangeable-Cu fraction. Liming resulted in a decrease of Cu in the exchangeable and organic matter fractions and an increase in the Fe and Mn oxide fractions and in the residual fraction. Without liming, the organic matter fraction presented the highest contribution to Cu content found in the soil extracts obtained with all extractors, except EDTA. For treatments with liming, Cu contents in the organic matter fraction were better correlated to Cu contents in extracts obtained with DTPA and Mehlich-3.


1972 ◽  
Vol 52 (3) ◽  
pp. 427-438 ◽  
Author(s):  
A. J. MacLEAN ◽  
R. L. HALSTEAD ◽  
B. J. FINN

Liming of six acid soil samples in an incubation experiment with rates to raise the soil pH to 6.0 or above eliminated Al soluble in 0.01 M CaCl2, reduced soluble Mn and Zn, increased NO3-N markedly, and at the highest pH increased the amounts of NaHCO3-soluble P in some of the soils. In corresponding pot experiments, liming increased the yield of alfalfa and in three of the soils the yield of barley also. Liming reduced the concentrations of the metals in the plants and at the highest pH tended to increase the P content of the plants. Liming to a pH of about 5.3 eliminated or greatly reduced soluble Al and the soils were base saturated as measured by the replacement of Al, Ca, and Mg by a neutral salt. There was some evidence that liming to reduce soluble Al and possibly Mn was beneficial for plant growth. Gypsum increased the concentrations of Al, Mn, and Zn in 0.01 M CaCl2 extracts of the soils whereas phosphate reduced them. The changes in the Mn content of the plants following these treatments were in agreement with the amounts of Mn in the CaCl2 extracts.


2020 ◽  
pp. 6-12
Author(s):  
Tahsina Sharmin Hoque ◽  
Shafia Afrin ◽  
Israt Jahan ◽  
Md. Joinul Abedin Mian ◽  
Mohammad Anwar Hossain

Soil depth can significantly influence the availability of nutrients in soil. An experiment was conducted with seven soil samples from seven land use types to observe the effect of soil depth on soil properties under various land use systems. Soil pH, electrical conductivity (EC), organic matter, available phosphorus (P), available sulphur (S) and different forms of potassium (K) such as water soluble, exchangeable and non-exchangeable were determined from the soil samples collected from four soil depths (viz. 0-10, 10-20, 20-30 and 30-40 cm). Soil pH varied from 6.30-7.39 irrespective of depths and land uses and it increased with increasing soil depth. Electrical conductivity of the soils ranged from 42-310 µS cm-1 and organic matter status of most of the soils was very low to medium in level. Both EC and organic matter content decreased with the increase of soil depth. Available P concentration showed no specific changing trend with soil depth whereas available S concentration under different land use systems decreased with increasing soil depth. The concentrations of water soluble, exchangeable and non-exchangeable K in soils varied from 12.30-39.60, 20.90-53.16 and 163.30-684.30 mg kg-1, respectively and showed no specific changing pattern with soil depth. Water soluble K content was higher in rice growing fertilizer and manure-treated soil but higher exchangeable and non-exchangeable K contents were observed in banana growing soil. In rice growing soils, nutrient concentration is mostly higher in nitrogen (N), P and K + farm yard manure (FYM) - treated plots compared to rice growing control plots.


2012 ◽  
Vol 58 (4) ◽  
pp. 131-137
Author(s):  
Vladimír Šimanský ◽  
Erika Tobiašová

Abstract The effect of different doses of NPK fertilizer on the changes in quantity and quality of soil organic matter (SOM) in Rendzic Leptosol was evaluated. Soil samples were taken from three treatments of different fertilization: (1) control - without fertilization, (2) NPK 1 - doses of NPK fertilizer in 1st degree intensity for vine, and (3) NPK 3 - doses of NPK fertilizer in 3rd degree intensity for vine in the vineyard. Soil samples were collected in years 2008-2011 during the spring. The higher dose of NPK fertilizer (3rd degree intensity of vineyards fertilization) was responsible for the higher content of labile carbon (by 21% in 0-0.3 m and by 11% as average of the two depths 0-0.3 m and 0.3-0.6 m). However, by application of a higher dose of NPK (1.39%) in comparison to no fertilizer treatment (1.35%) or NPK 1 (1.35%) the tendency of total organic carbon content increase and hot-water soluble carbon decrease were determined. Fertilization had a negative effect on SOM stability. Intensity of fertilization affected the changes in quantity and quality of SOM; therefore it is very important to pay attention to the quantity and quality of organic matter in productive vineyards.


2020 ◽  
Vol 45 (4) ◽  
Author(s):  
A.O. Abdullahi ◽  
A. Usman ◽  
A.H. Zakari ◽  
J.R. Tukur

This research work is aimed at determining the chemical speciation of metals Zn, Mn, Fe and Pb in soil samples from three major dumpsites within Gombe metropolis, Gombe state. The renowned five steps Tessier sequential extraction method was employed in the extraction of the heavy metals. The metals were extracted into five fractions namely: Exchangeable (F1), carbonate bound (F2), Fe-Mn oxide bound (F3), Bound to organic matter (F4) and the residual fraction (F5) in order of decreasing mobility. The elemental analysis of the fractions was carried out using atomic absorption spectrometric technique. The results showed Zn was predominantly bounded to the exchangeable fraction with 32.66±0.31 mg/kg (54.18%) and least in the Fe – Mn oxide fraction with 0.01±0.00 mg/kg (0.02%). The trend in its abundance is in the order F1> F2>F5>F4>F3. Mn was predominantly associated with the bound to carbonates fraction with the value of 103.3.±3.30 mg/kg (56.14%) and least in the exchangeable with the value of 1.30±1.85mg/kg (2.13%) its occurred in the order F2>F3>F4>F5>F1. The concentration of Fe was highest in the residual fraction with the value of 25.90±1.75mg/kg (45.45%)and least in the carbonate bound fraction wi th 5.10±0.40 mg/kg (2.13%) the order is F5>F4>F3>F2>F1. Pb was not detected in most of the fraction but highest in bond to carbonate and bond to organic matter fraction with the values of 6.64±4.12 mg/Kg (70.64 %) and 2.76±0.10 mg/Kg (29.36 %) respectively in two different samples. It was however established that Zn, Mn and Pb were mostly associated with the first three fractions thus, showed high bio-availabilty whereas Fe was found in the residual fraction and is expected to be low in mobility and less bioavailable. 


2020 ◽  
Vol 5 (2) ◽  
pp. 65-71
Author(s):  
Israt Jahan ◽  
AKM Abul Ahsan ◽  
MMR Jahangir ◽  
Mahmud Hossain ◽  
Md Anwarul Abedin

Soil physico-chemical properties are an important phenomenon for sustainable crop production and maintenance of optimum soil health. Hence, a laboratory measurement was conducted with soil samples of three years long experimental field of the Department of Soil Science, Bangladesh Agricultural University, Mymensingh to assess the changes in five selected soil physico-chemical properties viz. soil texture, bulk density, soil pH, total nitrogen and organic matter. The experiment was laid out in a split plot design with two water regimes (continuous flooding and alternate wetting & drying) in the main plots and five fertilizer treatments (N0 - control, N1- 140 kg N/ha as PU, N2- 104 kg N/ha as USG (2× 1.8 g/ 4 hills), N3 - 5 t CD + PU @ 140 kg N /ha on IPNS basis and N4- 5 t CD + USG (2× 1.8 g/ 4 hills @ 104 kg N/ha)) in the subplots under rice-rice cropping pattern with three replications. After three years, soil samples were collected at 0-5 and 5-10 cm soil depths for measuring bulk density and at 0-10 cm depth for other soil properties and analyzed. Results found that % sand, % silt, % clay, bulk density and soil pH was not changed significantly compared to initial status. Percentage of total nitrogen and organic matter was significantly affected by irrigation and fertilization. Total nitrogen (%) was higher in AWD whereas organic matter (%) was higher in CF practice. The highest total nitrogen (%) and organic matter (%) was found in N4 treatment in which USG was applied in combination with cowdung as organic manure. It can be suggested that N4 treatment was formed good combination for sustaining chemical properties of soil. Further long- term experimentation will be needed to know the changes in soil properties for sustainable crop production and improving soil health. Asian Australas. J. Biosci. Biotechnol. 2020, 5 (2), 65-71


1983 ◽  
Vol 55 (4) ◽  
pp. 345-354
Author(s):  
Helinä Hartikainen

The effect of increasing lime quantities on reactions of native and applied P was investigated in an incubation experiment performed with two acid mineral soils of pH 4.8 (CaCl2). The soil samples differed considerably in the content of organic matter, which was reflected in their pH buffering power: in the fine sand, rich in organic matter (6.4 % org. C), liming raised the pH less than in the muddy fine sand (3.0 % org. C). The level of native water-soluble P was markedly lowered in the incubated soil samples treated with nutrient salts. In the muddy fine sand, the decrease tended to be the smaller, whereas in the fine sand the greater, the more intensive liming was. This held true also of added P. The changes in CHANG and JACKSON’s P fractions did not alone satisfactorily explain the dissimilar response of soil P to lime treatments. The fate of P was concluded to be controlled by the quality and quantity of Al species differing in their affinity for P sorption. The changes in the solubility of P are a net result of processes enhancing and of those depressing the sorption tendency. In the fine sand soil of high initial content of water-soluble P, the detrimental effect of liming seemed to be attributed to the abundance of polymerized Al the affinity of which for P retention increased with intensified liming. Further, the high pH buffering power of this soil reduced the efficiency of lime to produce OH- ions able to compete with phosphate for sorption sites. In the muddy fine sand soil, on the contrary, the formation of sorption-active sites was not equally marked and, owing to the weaker pH buffering, liming raised the OH- concentration more effectively.


Solid Earth ◽  
2014 ◽  
Vol 5 (1) ◽  
pp. 209-225 ◽  
Author(s):  
P. Pereira ◽  
X. Úbeda ◽  
J. Mataix-Solera ◽  
M. Oliva ◽  
A. Novara

Abstract. Fire is a natural phenomenon with important implications on soil properties. The degree of this impact depends upon fire severity, the ecosystem affected, topography of the burned area and post-fire meteorological conditions. The study of fire effects on soil properties is fundamental to understand the impacts of this disturbance on ecosystems. The aim of this work was to study the short-term effects immediately after the fire (IAF), 2, 5, 7 and 9 months after a low-severity spring boreal grassland fire on soil colour value (assessed with the Munsell colour chart), soil organic matter content (SOM) and soil water repellency (SWR) in Lithuania. Four days after the fire a 400 m2 plot was delineated in an unburned and burned area with the same topographical characteristics. Soil samples were collected at 0–5 cm depth in a 20 m × 20 m grid, with 5 m space between sampling points. In each plot 25 samples were collected (50 each sampling date) for a total of 250 samples for the whole study. SWR was assessed in fine earth (< 2 mm) and sieve fractions of 2–1, 1–0.5, 0.5–0.25 and < 0.25 mm from the 250 soil samples using the water drop penetration time (WDPT) method. The results showed that significant differences were only identified in the burned area. Fire darkened the soil significantly during the entire study period due to the incorporation of ash/charcoal into the topsoil (significant differences were found among plots for all sampling dates). SOM was only significantly different among samples from the unburned area. The comparison between plots revealed that SOM was significantly higher in the first 2 months after the fire in the burned plot, compared to the unburned plot. SWR of the fine earth was significantly different in the burned and unburned plot among all sampling dates. SWR was significantly more severe only IAF and 2 months after the fire. In the unburned area SWR was significantly higher IAF, 2, 5 and 7 months later after than 9 months later. The comparison between plots showed that SWR was more severe in the burned plot during the first 2 months after the fire in relation to the unburned plot. Considering the different sieve fractions studied, in the burned plot SWR was significantly more severe in the first 7 months after the fire in the coarser fractions (2–1 and 1–0.5 mm) and 9 months after in the finer fractions (0.5–0.25 and < 0.25 mm). In relation to the unburned plot, SWR was significantly more severe in the size fractions 2–1 and < 0.25 mm, IAF, 5 and 7 months after the fire than 2 and 9 months later. In the 1–0.5- and 0.5–0.25 mm-size fractions, SWR was significantly higher IAF, 2, 5 and 7 months after the fire than in the last sampling date. Significant differences in SWR were observed among the different sieve fractions in each plot, with exception of 2 and 9 months after the fire in the unburned plot. In most cases the finer fraction (< 0.25 mm) was more water repellent than the others. The comparison between plots for each sieve fraction showed significant differences in all cases IAF, 2 and 5 months after the fire. Seven months after the fire significant differences were only observed in the finer fractions (0.5–0.25 and < 0.25 mm) and after 9 months no significant differences were identified. The correlations between soil Munsell colour value and SOM were negatively significant in the burned and unburned areas. The correlations between Munsell colour value and SWR were only significant in the burned plot IAF, 2 and 7 months after the fire. In the case of the correlations between SOM and SWR, significant differences were only identified IAF and 2 months after the fire. The partial correlations (controlling for the effect of SOM) revealed that SOM had an important influence on the correlation between soil Munsell colour value and SWR in the burned plot IAF, 2 and 7 months after the fire.


2020 ◽  
Vol 30 (3) ◽  
pp. 282-287
Author(s):  
U Kumar ◽  
H Rashid ◽  
NH Tithi ◽  
MY Mia

The study was intended to investigate the status of soil properties and its relation to soil pH in Madhupur tract soil of Tangail district, Bangladesh. Thirty soil samples were collected during the period from June-July, 2016 covering four types of land as high land, medium high land, medium low land and low land. The interpretative data showed that the range of pH was strongly acidic to slightly acidic (5.27- 5.90), mean pH was slightly acidic (5.61). The organic matter (OM) status was medium (2.11 to 2.33 %) and mean OM was medium (2.24 %). The Nitrogen (N) status was low (0.11 to 0.13 %) and mean N status was medium (0.12 %). The range of the Phosphorus (P) status was found very low to medium (1.63 to 11.06 µg g-1 soil) and mean P status was medium (7.37 µg g-1 soil). The Potassium (K) status was low to very high (0.15 to 0.75meq/100 g soil) and mean K status was low (0.18 meq/100 g soil). The range of the Sulfur (S) status was found from low to medium (11.73 to 16.31 µg g-1 soil), mean S status was low (13.26 µg g-1 soil). The range of the Zinc (Zn) status was found from medium to high (0.96 to 2.23 µg g-1 soil), mean Zn status was optimum (1.55 µg g-1 soil). The range of the Boron (B) status was found from medium to very high (0.39 to 0.86 µg g-1 soil), mean B status was high (0.73 µg g-1 soil). The Calcium (Ca) status was medium to optimum (4.42 to 5.23meq/100 g soil), mean Ca status was optimum (4.83 meq/100 g soil). The Magnesium (Mg) status was optimum to high (1.21 to 1.75meq/100 g soil), mean Mg status was optimum (1.37 meq/100 g soil). No significant correlation of OM and other nutrients with pH. Progressive Agriculture 30 (3): 282-287, 2019


2016 ◽  
Author(s):  
Jiří Zbíral ◽  
David Čižmár ◽  
Stanislav Malý ◽  
Elena Obdržálková

Abstract. Determining and characterizing soil organic matter (SOM) cheaply and reliably can help to support decisions concerning sustainable land management and climate policy. Glomalin, a glycoprotein produced by arbuscular mycorrhizal fungi, was recommended as a promising indicator of SOM quality. But extracting glomalin from and determining glomalin in soils using classical chemical methods is too complicated and time consuming and therefore limits the use of this parameter in large scale surveys. Near infrared spectroscopy (NIRS) is a very rapid, non-destructive analytical technique that can be used to determine many constituents of soil organic matter. Representative sets of 84 different soil samples from arable land and grasslands and 75 forest soils were used to develop reliable NIRS calibration models for glomalin. One calibration model was developed for samples with a low content of glomalin (arable land and grasslands), the second for soils with a high content of glomalin (forest soils), and the third calibration model for all combined soil samples. Calibrations were validated and optimized by leave-one-sample-out-cross-validation (LOSOCV) and by the external validation using eight soil samples (arable land and grassland), and six soil samples (forest soils) not included in the calibration models. Two different calibration models were recommended. One model for arable and grassland soils and the second for forest soils. No statistically significant differences were found between the reference and the NIRS method for both calibration models. The parameters of the NIRS calibration model (RMSECV = 0,70 and R = 0,90 for soils from arable land and grasslands and RMSECV = 3,8 and R = 0,94 for forest soils) proved that glomalin can be determined directly in air-dried soils by NIRS with adequate trueness and precision.


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