scholarly journals Poly(ethylene oxide)-Based Composite Electrolytes Filled with Periodic Mesoporous Silica for Solid State Ionics

2005 ◽  
Vol 1 ◽  
pp. 14-19 ◽  
Author(s):  
Yoichi Tominaga ◽  
Masahiro Morita ◽  
Shigeo Asai ◽  
Masao Sumita
2021 ◽  
Vol 9 (15) ◽  
pp. 5396-5404
Author(s):  
Xiang Zhang ◽  
Tengfei Zhang ◽  
Yifei Shao ◽  
Hailin Cao ◽  
Zhenhua Liu ◽  
...  

2018 ◽  
Vol 285 ◽  
pp. 355-364 ◽  
Author(s):  
Shruti Suriyakumar ◽  
Sivalingam Gopi ◽  
Murugavel Kathiresan ◽  
Suriyasarathi Bose ◽  
E. Bhoje Gowd ◽  
...  

2003 ◽  
Vol 68 (10) ◽  
pp. 2019-2031 ◽  
Author(s):  
Markéta Zukalová ◽  
Jiří Rathouský ◽  
Arnošt Zukal

A new procedure has been developed, which is based on homogeneous precipitation of organized mesoporous silica from an aqueous solution of sodium metasilicate and a nonionic poly(ethylene oxide) surfactant serving as a structure-directing agent. The decrease in pH, which induces the polycondensation of silica, is achieved by hydrolysis of ethyl acetate. Owing to the complexation of Na+ cations by poly(ethylene oxide) segments, assembling of the mesostructure appears to occur under electrostatic control by the S0Na+I- pathway, where S0 and I- are surfactant and inorganic species, respectively. As the complexation of Na+ cations causes extended conformation of poly(ethylene oxide) segments, the pore size and pore volume of organized mesoporous silica increase in comparison with materials prepared under neutral or acidic conditions. The assembling of particles can be fully separated from their solidification, which results in the formation of highly regular spherical particles of mesoporous silica.


2018 ◽  
Vol 141 (3) ◽  
pp. 1227-1234 ◽  
Author(s):  
Gen Zhang ◽  
You-lee Hong ◽  
Yusuke Nishiyama ◽  
Songyan Bai ◽  
Susumu Kitagawa ◽  
...  

Polymer ◽  
2005 ◽  
Vol 46 (25) ◽  
pp. 11737-11743 ◽  
Author(s):  
D.J. Harris ◽  
T.J. Bonagamba ◽  
M. Hong ◽  
K. Schmidt-Rohr

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