scholarly journals Effect of liming on the mobilization of soil phosphorus

1965 ◽  
Vol 37 (4) ◽  
pp. 243-254
Author(s):  
Armi Kaila

The effect of liming on the soil phosphorus fractions was studied under the laboratory conditions. 28 samples of mineral soils (pH in 0.01 M CaCl2 suspension 4.0 to 6.0) were incubated with 1 per cent CaCO3 or without lime for six months at about 18—20°C. In an other experiment, six samples (pH from 3.3 to 4.3) were incubated with 0, 0.5, 1, or 2 per cent CaCO3 also for six months. At the end of the incubation period the soil pH in the limed samples of the first experiment ranged from pH 5.9 to pH 7.5, in the second experiment the highest application kept the soil pH at 6.5 to 7.0. In the air-dried samples the content of organic phosphorus and the fractions of inorganic phosphorus were determined, and the increases or decreases due to the incubation and liming were calculated. Incubation without lime brought about decrease in the organic phosphorus content of several samples, and the presence of lime tended to intensify this effect, although only in a few cases the decrease due to liming was statistically significant. Liming also tended to increase the accumulation of NH4F-soluble inorganic phosphorus. The acid-soluble fraction was often increased in the limed samples but not in the unlimed ones. The alkali-soluble fraction was decreased in most soils in the limed samples, while it increased in some of the unlimed ones. In the second experiment the incubation caused marked decrease in the alkali-soluble phosphorus without a corresponding increase in the other phosphorus fractions determined in the subsoil samples. It was concluded that in these experiments the relatively heavy liming in the first place affected the distribution of inorganic phosphorus increasing the NH4F-soluble and acid-soluble forms at the expense of the alkali-soluble fraction. The effect on the mineralization of organic phosphorus seemed to be in most soils of minor importance.

1961 ◽  
Vol 33 (1) ◽  
pp. 185-193 ◽  
Author(s):  
Armi Kaila

Samples from two field trials were incubated at 20°C for seven months with or without an addition of 1 per cent CaCO3. Both the samples of loam soil and silt soil originated from the surface inch of plots treated with no phosphate, superphosphate or hyperphosphate, resp. It was found that liming did not in any case increase the amount of organic phosphorus mineralized during the incubation. Its effect was observed in the distribution of this phosphorus in the various fractions of inorganic phosphorus. In the distinctly acid samples which were incubated without lime the mineralized phosphorus seemed to accumulate as the ammonium fluoride-soluble and alkali-soluble forms, while in the neutral samples incubated with lime an increase only in the former fraction was detected. When the samples from the hyperphosphate plots were incubated without lime, apparently some apatite of the fertilizer was dissolved and sorbed as the ammonium fluoride soluble or alkali-soluble forms. No decrease in the acid-soluble fraction of these samples incubated with lime did occur.


1967 ◽  
Vol 39 (1) ◽  
pp. 5-13 ◽  
Author(s):  
Armi Kaila

The effect of liming on the distribution of superphosphate phosphorus in various fractions of soil phosphorus was studied. Samples of four mineral soils (pH 3.9 to 5.1) were incubated at room temperature for eight months with 0, 0.5, or 1.0 per cent CaCO3, and with 0.40 per cent superphosphate or without any phosphate application. Liming increased the soil pH-values to pH 6.1—7.3. Samples were analyzed for inorganic phosphorus by the fractionation method of CHANG and JACKSON. Results obtained after an incubation period of four months showed that, both in the fertilized and unfertilized samples, liming had increased the fluoride soluble, acid soluble and easily soluble fractions, but it had decreased the alkali soluble phosphorus. These effects were generally the more distinct, the higher the application of CaCO3 had been. During the prolonged incubation, the alkali soluble fraction tended to increase at the expense of the fluoride soluble phosphorus. The differences in the phosphorus content of various fractions in the respective fertilized and unfertilized samples showed that the »superphosphate phosphorus» was mainly recovered as the fluoride soluble and alkali soluble forms, the relative amount of the latter being the lower the heavier the liming had been. Yet, even at about pH 7, from one fifth to one fourth of the applied phosphorus appeared to be sorbed by iron compounds and ocurred in the alkali soluble fraction. The sum of the proportions of easily soluble and fluoride soluble phosphorus increased with liming. The small parts of fertilizer phosphorus recovered in the acid soluble form did not depend on the rate of liming. Thus, even at pH 7, no significant turning of superphosphate phosphorus in difficultly soluble apatite like secondary calcium phosphates could be detected. The effect of liming on the availability of the fertilizer phosphorus and on the phosphate retention pattern of the soil, was discussed.


2020 ◽  
Vol 143 ◽  
pp. 02024
Author(s):  
Wang Xi ◽  
Lu Shuchang ◽  
Pei Zhiqiang ◽  
Hou Kun ◽  
Ya Zongjie ◽  
...  

In this experiment, the effects of different types of conditioners and their application on the absorption and transformation of phosphorus in high phosphorus soils in facilities were investigated to improve the environmental problems of protected farmland caused by phosphorus accumulation. Waxy corn was used as a test crop, and five conditioners such as humic acid, biochar, bentonite, alum, and dephosphorized gypsum were used as test materials for potting experiments. The experiment set 10 treatments, namely T1(Blank control), T2(Humic acid), T3(Biochar), T4(Bentonite), T5(Alum), T6 (Dephosphorized gypsum), T7(Biochar-bentonite-alum), T8(Humic acid-biochar-alum),T9(Humic acidbiochar- bentonite-alum),T10(Humic acid-bentonite-biochar-alum-dephosphorized gypsum). Based on the analysis of the results of the three crops, except that the first crop was not significant, the biomass and phosphorus absorption of waxy corn of T2 was the highest in the second crop, and T10 was the most effective treatment in the third crop. The soil available phosphorus content of T8 was the lowest in the second crop and that of T10 was the lowest in the third crop, which were 12.01% and 12.75% lower than the control. The soil water-soluble phosphorus content of T4 was the lowest in the second crop, which was 41.84% lower than the control, and that of T8 was the lowest in the third crop, which was 26.62% lower than the control. According to the results of the three crops, the ratio of the total phosphorus content of the inorganic phosphorus in the third crop of each treatment was increasing compared with the first crop. The soil phosphorus was transformed from organic phosphorus to inorganic phosphorus. The ratio of total phosphorus content of organic phosphorus of T6, T9, T10 was larger than other treatments, which slowed down the conversion of phosphorus to available form. The ratio of Ca8-P in the inorganic phosphorus was the highest, reaching about 50% to 60%. From the results and analysis, T2 and T10 were beneficial to the absorption of soil phosphorus by waxy corn, T8 and T10 were beneficial to slow down the conversion of phosphorus to the effective state, reduce the potential risk of phosphorus environment, improve the phosphorus accumulation environmental issues in greenhouse farmland.


1963 ◽  
Vol 43 (1) ◽  
pp. 97-106 ◽  
Author(s):  
R. L. Halstead ◽  
J. M. Lapensee ◽  
K. C. Ivarson

In a laboratory experiment, liming resulted in an average decline of 3.6 per cent in the total organic phosphorus content of incubated surface samples of seven acid soils from eastern Canada. Increases of 2.6 and 5.1 per cent in 1N H2SO4- and 4N HCl-soluble inorganic phosphorus, respectively, and a decrease of 46.4 per cent in NaHCO3-soluble organic phosphorus (pH 8.5) provided further evidence of mineralization of organic phosphorus following liming. There was some evidence, however, that the differences in NaHCO3-soluble organic phosphorus following liming were due only in part to mineralization, since Ca(OH)2 added to a soil just prior to extraction with NaHCO3 had a repressive effect on the solubility of the organic phosphorus compounds.Some mineralization of organic phosphorus occurred when unlimed samples were incubated in the laboratory for 9 months.Marked increases in microbiological activity, as indicated by increased numbers of microorganisms, and increased CO2 and NO3-nitrogen production, were associated with lower values for extractable organic phosphorus following liming. Partial sterilization of samples with toluene lowered biological activity in the unlimed and limed samples. Toluene was found, however, to have a positive effect on release of phosphorus from organic form.


1938 ◽  
Vol 28 (2) ◽  
pp. 234-246 ◽  
Author(s):  
L. A. Dean

1. Extractions of soils with sodium hydroxide, followed by an acid, have been used in an attempt to fractionate the soil phosphorus.2. Colorimetric methods for the estimation of the organic and inorganic phosphorus in alkali soil extracts have been suggested.3. The amount of soil phosphorus soluble in sodium hydroxide is affected by the active soil calcium. It is suggested that sodium-saturated soils be used when studying the alkali-soluble phosphorus.4. The acid-soluble phosphorus remaining in soil after extraction with sodium hydroxide was determined. This fraction appears by analogy to be similar to the apatites.5. The largest fraction of the total soil phosphorus was not dissolved by the sodium hydroxide and acid extractions. This fraction was not increased by the long-continued use of phosphatic fertilizers at Rothamsted and Woburn.6. Relatively large amounts of organic phosphorus were found in soils and the amounts were closely related to the carbon contents.


Soil Research ◽  
1992 ◽  
Vol 30 (3) ◽  
pp. 383 ◽  
Author(s):  
KW Perrott ◽  
SU Sarathchandra ◽  
BW Dow

A two year investigation of soil phosphorus and the soil organic cycle was carried out on a typical hill country site in the North Island, New Zealand. This included investigation of changes in soil phosphorus, as well as seasonal and fertilizer (superphosphate) effects on soil microbial phosphorus and sulfur, sodium bicarbonate extractable phosphorus and calcium chloride extractable sulfur. No net utilization of soil organic phosphorus occurred when application of phosphate fertilizer was withheld. On the contrary, accumulation of organic phosphorus was found in both fertilized and unfertilized plots. Immobilization of inorganic phosphorus into organic forms appeared to be a significant factor in fertilizer phosphorus requirements at this site. It was also a significant cause of the decline in the soil phosphorus status when no fertilizer was applied. Despite declining pasture production, there were no effects of withholding superphosphate on the soil biological cycle as measured by soil microbial phosphorus and sulfur, total organic phosphorus and sodium bicarbonate extractable organic phosphorus. However, seasonal variations occurred indicating storage and release of phosphorus by the soil organic matter and microbial biomass. Release of phosphorus occurred during periods of rapid pasture growth and could account for phosphorus uptake by the pasture at those times.


1966 ◽  
Vol 17 (3) ◽  
pp. 303 ◽  
Author(s):  
AJ Rixon

Changes in phosphorus applied as superphosphate to irrigated pastures on a red-brown earth were studied for a 4 year period commencing 1 year after the establishment of the pastures. The pastures consisted of Wimmera ryegrass (Lolium rigidum Gaud.), perennial ryegrass (L. perenne L.), subterranean clover (Trifolium subterraneum L.), and white clover (T. repens L.). Measurements of phosphorus fractions were made on the 0–3 in. soil horizon over this period and, for the final 2 years, on the organic matter layer (mat) which was present on the soil surface under all pastures. The mat was shown to be an important accumulation site for organic phosphorus, as well as for inorganic phosphorus which accumulates from interception of broadcast applications of superphosphate. Of the 155 lb phosphorus per acre added as fertilizer, 82–100% was accounted for principally as increases in the acetic acid-soluble fraction or as organic phosphorus. There were no significant changes in the inorganic phosphorus fraction soluble in sodium hydroxide. It was concluded that the amount of phosphorus converted to the organic form will determine the level for maintenance applications of phosphorus on the irrigated pastures.


1964 ◽  
Vol 62 (3) ◽  
pp. 341-351 ◽  
Author(s):  
J. L. L'Estrange ◽  
R. F. E. Axford

Short-term grazing trials with daily blood sampling were carried out on Welsh mountain ewes in early lactation.1. A small decrease in serum magnesium levels and a very marked decrease in serum inorganic phosphorus levels, were observed in two groups of four ewes, when one group was transferred from an old pasture to a fertilized (high nitrogen and potash) fresh spring ley, and the others to a similar fresh ley but untreated. There was little effect from the fertilizer treatment on the magnesium, calcium, potassium, sodium or phosphorus content of the herbage.


2012 ◽  
Vol 518-523 ◽  
pp. 4801-4805
Author(s):  
Li Xin Chen ◽  
Wen Biao Duan

Variation in total phosphorus (TP), available phosphorus (AP), the forms of organic phosphorus (OP) and inorganic phosphorus (IP) in rhizosphere soil (RS) and non-rhizosphere soil (NRS) at different development stages in larch (Larix olgensis) plantations was quantitively studied through field investigation, chemical analysis and statistical test. The results indicated that: AP, O-P (occluded phosphate), TP, OP in RS exhibited a significantly or apparently decreased tendency over stand age, but IP, Ca-P (phosphate combined with calcium) and Fe-P (phosphate combined with Ferrum) in RS presented a significantly or apparently increased trend when stand age increased; Ca-P in NRS increased when stand age became larger; Fe-P in half-mature stand (HMS), AP and Fe-P in near mature stand (NMS), AP and Ca-P in mature stand (MS) in NRS was higher than in RS


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