scholarly journals Penentuan Kondisi Optimasi Transpor Ion Cu (Ii) Melalui Teknik Membran Cair Fasa Ruah Secara Simultan Dengan Oksin Sebagai Pembawa

2015 ◽  
Vol 4 (2) ◽  
pp. 48
Author(s):  
Refinel ◽  
Admin Alif ◽  
Rizki Octarini
Keyword(s):  
Optimum Condition ◽  
Kinetic Analysis ◽  
Liquid Membrane ◽  
Ion Concentration ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane ◽  
H2so4 Concentration ◽  
Membrane Technique ◽  
Carrier Transportation

 ABSTRACT Determination of optimum condition and kinetic analysis Cu (II) iontransport by simultaneous bulk liquid membrane has been studied. Optimum condition for resource phase with Cu (II) ion concentration as 3,147 x 10-4 M obtained at pH 3 receiving phase with H2SO4 concentration 0,15 M and transport time as long as 3 hours through chloroform membrane using oxine 17,5 x 10-4 M as carrier. Transportation rate of Cu (II) ion decided by comparasion changer-over rest concentration in resource phase Rs and transpoted to receiving phase Rp and then monitored by Atomic Adsorbtion Spectrophotometre (AAS). Kinetic of transport Cu (II) ion process by simultaneous bulk liquid membrane technique fulfil irreversible consecutive first order reaction with transport Cu (II) ion gave (k1) value as 0,0442 minute-1 and ( k1 ) 0,0372 minute-1 . Simultaneous bulk liquid membrane method can be the alternative method in the determination of optimum condition and kinetic analysis of metal ions transport. Key words: Cu (II) ion, kinetic, optimum, transport, liquid membrane, simultaneous    

scholarly journals TRANSPORT BEHAVIOR OF Cr(III), Cd(II), Pb(II), AND Ag(I) IONS THROUGH BULK LIQUID MEMBRANE CONTAINING p-tert-BUTYLCALIX[4]ARENE–TETRADIETHYLACETAMIDE AS ION CARRIER

2010 ◽  
Vol 8 (3) ◽  
pp. 300-306 ◽  
Author(s):  
Maming Maming ◽  
Jumina Jumina ◽  
Dwi Siswanta ◽  
Hardjono Sastrohamidjojo ◽  
Keisuke Ohto
Keyword(s):  
Optimum Condition ◽  
Liquid Membrane ◽  
Bulk Liquid ◽  
High Concentration ◽  
Bulk Liquid Membrane ◽  
Transport Efficiency ◽  
Transport Behavior ◽  
Source Phase ◽  
Ion Carrier

The study on the transport behavior of Cr(III), Cd(II), Pb(II), and Ag(I) through bulk liquid membrane using p-tert-butylcalix[4]arene-tetradiethylacetamide as ions carrier has been conducted. The aims of this work are to determine the optimum condition, efficiency, and transport selectivity of the carriers for those ions. Both optimum condition and transport efficiency were obtained by determination of the concentration of transported ions with variation of the source phase pH, ion carrier concentration, the nature of decomplexant agent in the receiving phase, and transport time. The transport selectivity of the ion carrier was obtained from the ions competition transport experiments. The amount of Cr(III), Pb(II), Cd(II), and Ag(I) transported across liquid membrane were 11.6, 25.5, 39.5, and 42.1% respectively. The ion carrier is selective for Cd(II), Pb(II), Ag(I), and strongly depends on the nature of decomplexant agent as well as transport mechanism. The remarkable selectivity was shown by the ion carrier to Ag(I) when the transport process was carry out under high concentration of acid in the source phase.   Keywords: transport, p-tert-butylcalix[4]arene-tetradiethylacetamide, efficiency, selectivity, bulk liquid membrane, heavy metals

scholarly journals TRANSPORT OF Cr(III), Cd(II), Pb(II), AND Ag(I) IONS THROUGH BULK LIQUID MEMBRANE CONTAINING p-tert-BUTYLCALIX[4]ARENE –TETRAETHYLESTER AS ION CARRIER

2010 ◽  
Vol 8 (1) ◽  
pp. 72-77 ◽  
Author(s):  
Maming Maming ◽  
Jumina Jumina ◽  
Dwi Siswanta ◽  
Firdaus Firdaus ◽  
Hardjono Sastrohamidjojo
Keyword(s):  
Heavy Metals ◽  
Optimum Condition ◽  
Liquid Membrane ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane ◽  
Transport Time ◽  
Ions Transport ◽  
Source Phase ◽  
Ion Carrier

The study on transport of Cr(III), Cd(II), Pb(II), and Ag(I) through bulk liquid membrane using p-tert-butylcalix[4]arene-tetraethylester as ions carrier has been conducted. The aims of this work are to determine the optimum condition, efficiency, and selectivity of transport of the carriers for those ions. Both optimum condition and efficiency of transport were obtained by determination of the concentration of transported ions with variation of source phase pH, ion carrier concentration, the nature of stripping agent in the target phase, and transport time. The ion transport selectivity of ion carrier was obtained from the ions transport competition experiments using equimolar mixtures. The amount of Cr(III), Pb(II), Cd(II), and Ag(I  that was transported across liquid membrane was about 0, 10, 10 and 50 % respectively after 24 hours, except for Pb(II) (32 hours). The ion carrier is selective for Ag(I) where separation factor to Cd(II) was 16.0, that to Pb(II) was 42.8, and that to Cr(III) was infinite.   Keywords: transport,  calix[4]arene, efficiency, selectivity, bulk liquid membrane, heavy metals

scholarly journals Synthesis of A Novel Carrier Compound Thiazoethyl Methyl Eugenoxyacetate from Eugenol and Its Use in the Bulk Liquid Membrane Technique

2018 ◽  
Vol 18 (1) ◽  
pp. 121 ◽  
Author(s):  
Muhammad Cholid Djunaidi ◽  
Pratama Jujur Wibawa ◽  
Ratna Hari Murti
Keyword(s):  
Metal Ions ◽  
Retention Time ◽  
Liquid Membrane ◽  
Vibration Mode ◽  
Ester Group ◽  
Ftir Spectrum ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane ◽  
Selective Transport ◽  
Membrane Technique

Research into the synthesis and use of a novel carrier compound, thiazoethyl methyl eugenoxyacetic acid (TMEAA) for selective transport of Cu(II), Cd(II) and Cr(III) metal ions in the bulk liquid membrane (BLM) technique was conducted. TMEAA was synthesized from eugenol. Eugenol was acidified into eugenoxyacetic acid and subsequently esterified using 4-methyl-5-thiazoethanol. Analysis of the result was performed using GC-MS and FTIR. The TMEAA obtained was liquid, viscous, blackish-brown and fragrant, with a yield of 88%. This compound was soluble in benzene and chloroform but insoluble in methanol. The GC-MS analysis result showed the presence of a single peak, with a retention time of 26.5 min and an area of 100%, while the disappearance of vibration mode at 1727 cm-1 was attributed to acid absorption and the FTIR spectrum indicated that formation of an ester group had occurred. TMEAA was used as a carrier compound in the BLM technique to transport Cu(II), Cd(II) and Cr(III), using chloroform as a solvent. The results showed that TMEAA was more selective for Cu(II) and Cd(II) than Cr(III). Moreover, the research proved that N and S groups of TMEAA were selective for Cu (II) and Cd (II).

Extraction Process of L-Theanine across Aiquat 336-Kerosene Bulk Liquid Membrane

2012 ◽  
Vol 485 ◽  
pp. 52-55
Author(s):  
Du Shu Huang ◽  
Zhao Long Huang ◽  
Na Wu ◽  
Jing Wang ◽  
Chun Xu ◽  
...  
Keyword(s):  
Carrier Concentration ◽  
Liquid Membrane ◽  
Extraction Process ◽  
Ion Concentration ◽  
Bulk Liquid ◽  
Separation Performance ◽  
Aliquat 336 ◽  
Bulk Liquid Membrane ◽  
Initial Concentration

L-theanine was extracted by bulk liquid membrane containing Aliquat 336 as a carrier and kerosene as solvent. The effects of theanine initial concentration, carrier concentration and ion concentration in the extracting phase on separation performance were discussed and appropriate extractive conditions were established.

scholarly journals Kinetika dan mekanisme sistem transpor Cd(II) antar fasa melalui teknik membran cair fasa ruah dengan oksin sebagai zat pembawa

2015 ◽  
Vol 1 (1) ◽  
pp. 97
Author(s):  
Zaharasmi Kahar ◽  
Djufri Mustafa ◽  
Wiwit
Keyword(s):  
Transport System ◽  
Liquid Membrane ◽  
Chloroform Solution ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane ◽  
First Order ◽  
Mobile Carrier ◽  
Membrane Technique ◽  
Model Curve ◽  
Good Agreement

 ABSTRACT The transport and separation of Cd(II) through  bulk liquid membrane technique had been investigated and optimised. Cd(II) was transported  through a liquid membrane  of  chloroform solution containing oxine as mobile carrier and  received by EDTA in stripping phase. In compliance with optimum condition, the flux of Cd(II) crossing the membrane was studied, and applied further into a model of the transport system and kinetics mechanism. Concentration of Cd(II) in feed  and stripping phases were experimentally determined, and monitored by the atomic absorption spectrophotometer at lmaks 228.8 nm.  The model curve of time dependence of Cd(II) reduced concentrations in the feed, membrane and  stripping phases show good agreement and characterized as a transport system for Cd(II) interphase involved two consecutive irreversible first order reactions. The rate constant of transport at temperature 28°C are k1 0.0416 minutes-1, k2 0.0354  minutes-1 and  activation energy  32.96 kJ mol-1

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