scholarly journals ISSN : 1978-628X KINETIKA TRANSPOR FENOL DENGAN ADITIF SURFAKTAN DALAM TEKNIK MEMBRAN CAIR FASA RUAH

2012 ◽  
Vol 5 (2) ◽  
pp. 150
Author(s):  
Refinel ◽  
Djufri Mustafa Mustafa ◽  
Welly Safitri ◽  
Yulia Yesti ◽  
Rudhy Anggi
Keyword(s):  
Oleic Acid ◽  
Liquid Membrane ◽  
Sodium Dodecyl ◽  
Tween 80 ◽  
Bulk Liquid ◽  
Membrane Phase ◽  
Bulk Liquid Membrane ◽  
Membrane Technique ◽  
Source Phase ◽  
Span 60

Study of transport of phenol using the surfactant SDS (Sodium Dodecyl Sulfate), Tween-80 as additive in the source phase and oleic acid, Span-60 additive in the membrane phase with bulk liquid membrane techniques has been performed. Transportation system was in one way using solution of phenol 2.13 x 10 -4 M as the source phase, 30 mL of chloroform as membrane phase, a solution of 12 mL of 0.1 M NaOH as the receiving phase and stirring speed of 340 rpm. The concentration of phenol that transported into receiving phase and remaining in the source is determined by measuring phenol method using 4-aminoantipirin and monitored with a spectrophotometer. The result showed the percentage of transport of phenol into the receiving phase is 93.07% within 120 minutes without any additive surfactant, while for additive oleic acid and Span-60 the percentage of transport phenol is 97.28% and 88.84% within 90 minutes. Phenol transport system analyzed by means of a kinetic model involving consecutive irreversible first order reaction with the constants extraction of phenol from the source to the membrane (k1) of 0.0346 minute-1, 0.0304 min-1, and from the membrane phase into the receiving phase (k2) of 0.0264 min-1, 0.0309 min-1 each for additive oleic acid and Span-60 in the membrane phase. Surfactant SDS and Tween-80 additive in the source phase is not effective to decreased the transport time of the phenol in the phase bulk liquid membrane technique.

scholarly journals OPTIMALISASI TRANSPORT SELEKTIF ION Ni(II) TERHADAP Cd(II) DENGAN ZAT PEMBAWA OKSIN MELALUI TEKNIK MEMBRAN CAIR FASA RUAH SECARA SIMULTAN

2015 ◽  
Vol 2 (2) ◽  
pp. 181
Author(s):  
Vera Tri Ningsih ◽  
Admin Alif ◽  
Hermansyah Aziz
Keyword(s):  
Rate Constant ◽  
Liquid Membrane ◽  
Transport Rate ◽  
Bulk Liquid ◽  
Membrane Phase ◽  
Bulk Liquid Membrane ◽  
Solution Ph ◽  
Membrane Technique ◽  
Source Phase ◽  
Phase Transport

  ABSTRACT The selective transport of Ni(II) to Cd(II) through simultaneously liquid membrane technique has been investigated. The cell membrane was made by mixturing Ni(II) and Cd(II) ions at concentration as 3.41x10-4 M and 1.78x10-4 M respectively as source phase, oxine in chloroform as membrane phase and Na2EDTA solution as receiving phase. Concentration of recidual Ni(II) and Cd(II) ions in source phase transported to receiving phase was measured by Atomic Absortion Spectrofotometry (AAS). The results showed the at optimum condition of Ni(II) and Cd(II) transport occurred at source phase of pH 7, oxine concentration 0.001 M in chloroform and 0.04 M Na2EDTA solution pH 7. In this condition, Ni(II) and Cd(II) transport selectivity was found 80.89%. From the experiment, it was found that the transport rate constant from source phase to membrane phase (k1) for Ni(II) (0.7544 per hour) smaller than Cd(II) (1.3800 per hour ), on the other hand the transport rate constant from membrane phase to receiving phase (k2) Ni(II) (2.7580 per hour) greater than Cd(II) (1.3790 per hour). The phase-to-phase transport of Ni(II) and Cd(II) was consecutive first order reaction.  Keywords : bulk liquid membrane, oxine, technique    

scholarly journals PENAMBAHAN ASAM OLEAT TERHADAP Sistem transpor Cu(II) dengan zat pembawa oksin melalui teknik membran cair fasa ruah

2015 ◽  
Vol 2 (1) ◽  
pp. 45
Author(s):  
Olly Norita Tetra ◽  
Zaharasmi ◽  
Refinel
Keyword(s):  
Aqueous Solutions ◽  
Liquid Membrane ◽  
Bulk Liquid ◽  
Optimum Conditions ◽  
Membrane Phase ◽  
Bulk Liquid Membrane ◽  
Phase 0 ◽  
Interface System ◽  
Source Phase ◽  
Feed Phase

 ABSTRACT The removal of Cu(II) from aqueous solutions had been employed throught bulk liquid membrane techniques with arrange the optimization conditions of transport Cu(II) interface system. The optimum conditions of transport were found to be 3.1510-4 M of Cu(II) at pH 3  in the source phase,  17.510-4 M oxine dissolved into chloroform as membrane phase, 0,15 M H2SO4 as acceptor in  receiving phase, stirring rate was 340 rpm and  it was found that the transport of Cu(II) to receiving phase reached 97.41% during 6 hours. The effect of addition  oleat acid 1.57  10-3 M as surfactant  in membrane phase resulted a rapidly time of  transport Cu(II) to be 3 hours, wherein Cu(II) transported  into  the receive phase reached 97.83%  and remained  in feed phase 0%. Keywords: bulk liquid membrane, oxine, oleat acid, Cu(II) )transport

scholarly journals TRANSPOR ION TEMBAGA (II) MELALUI TEKNIK MEMBRAN CAIR FASA RUAH

2015 ◽  
Vol 1 (1) ◽  
pp. 25
Author(s):  
Olly Norita Tetra ◽  
Admin Alif ◽  
Hermansyah A ◽  
Emriadi
Keyword(s):  
Acid Concentration ◽  
Liquid Membrane ◽  
Ph Gradient ◽  
Bulk Liquid ◽  
Optimum Conditions ◽  
Membrane Phase ◽  
Bulk Liquid Membrane ◽  
Source Phase

 ABSTRACT Bulk liquid membrane methode have been used to study transport  of  Cu(II) ion containing oxine as carrier. It was found that total Cu(II) ion 20 ppm was transported from source phase to receiving phase after 360 min reached 97.3 % in optimum conditions source phase pH is 3, oxine concentration as carier in membrane phase is 17.5 x 10-4 M, membrane volume is 20 mL, sulfur acid concentration in receiving phase 0.15 M and time of balance is 15 minute. Thus a pH gradient is utilized to drive the Cu(II) transport.

scholarly journals OPTIMALISASI TRANSPOR Zn(II) DENGAN ZAT PEMBAWA DITIZON MELALUI TEKNIK MEMBRAN CAIR FASA RUAH

2015 ◽  
Vol 3 (2) ◽  
pp. 151
Author(s):  
Olly Norita Tetra ◽  
Zaharasmi K ◽  
Zaharasmi K ◽  
Refinel ◽  
Refinel ◽  
...  
Keyword(s):  
Liquid Membrane ◽  
Research Result ◽  
Bulk Liquid ◽  
Operation Technique ◽  
Optimum Conditions ◽  
Membrane Phase ◽  
Bulk Liquid Membrane ◽  
Transport Time ◽  
Source Phase ◽  
Membrane Ion Transport

 ABSTRACT Zn(II) transport from the source phase into the source phase had been researched by using dithizone as carrier through bulk liquid membrane. Ion transport are started by adding 6 mL source phase that consist of Zn(II), 12 mL receiver phase that consist of Na2EDTA and 20 mL membrane phase that consist of dithizone as carrier. The experiment operation technique was assisted by magnetic stirrer mixing at 340 rpm speed within 15 minutes equilibrium time. The measurement was done to both of source phase and receiver phase by using Atomic Absorption Spectrophotometer (213.9 nm) until Zn(II) was transported to receiver phase and residue in source phase was gathered. The research result that optimum conditions to transport 3.06 x 10-4 M Zn(II) was at pH 8.5 of source phase, 1.75 x 10-5 M dithizone concentrate at membrane phase, 0.06 M EDTA concentrate at pH 6 in receiver phase and 3 hours transport time with Zn(II) percentage which was transported to receiver phase 93% and residue in source phase do not detect. Keywords: transport Zn(II), bulk liquid membrane, dithizone

scholarly journals KINETIKA TRANSPOR Cu(II) OLEH ZAT PEMBAWA OKSIN DENGAN DAN TANPA ASAM OLEAT MELALUI MEMBRAN CAIR FASA RUAH

2015 ◽  
Vol 2 (2) ◽  
pp. 127
Author(s):  
Refinel ◽  
Emdeniz
Keyword(s):  
Activation Energy ◽  
Liquid Membrane ◽  
Copper Ions ◽  
Transport Rate ◽  
Bulk Liquid ◽  
Exit Rate ◽  
Membrane Phase ◽  
Bulk Liquid Membrane ◽  
Source Phase ◽  
Phase Transport

 Vol. 2, No. 2ABSTRACT Transport of Cu(II) ions with and without oleat acid additive through bulk liquid membrane has been fullfill the kinetic lows of consecutive irreversible first reaction by oxine as carrier in chloroform membrane. Additions of oleat acid 1.57510–3 M could increase Cu(II) transport affectivity on interface of membrane-source phase and receiving-membrane phase. Transport rate constanta value of Cu(II) ions entrance (k1) 0.0454/minute and the membrane exit rate (k2) 0.0364/minute at 301 K with activation energy 51.471 kJ/mol and without oleat acid rate constanta (k1) 0.0236/minute, (k2) 0.0193/minute with activation energy 55.2499 kJ/mol at the same condition. Keywords : bulk liquid membrane, oxine, oleat acid, copper ions    

scholarly journals Liquid-liquid extraction and facilitated membrane transport of Pb2+ using a lipophilic acridono-crown ether as carrier

2020 ◽  
Vol 99 (1-2) ◽  
pp. 117-129
Author(s):  
Ádám Golcs ◽  
László Bezúr ◽  
Péter Huszthy ◽  
Tünde Tóth
Keyword(s):  
Membrane Transport ◽  
Metal Ion ◽  
Liquid Membrane ◽  
Competitive Inhibition ◽  
Liquid Extraction ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane ◽  
Liquid Liquid Extraction ◽  
Component Systems ◽  
Source Phase

AbstractStudies on liquid-liquid extraction and bulk liquid membrane (BLM) technique-based metal ion separation by a previously published Pb2+-selective acridono-18-crown-6 ether selector molecule were performed. The effects of the stirring speed, the quality of apolar organic membrane, the counterions of Pb2+, the pH of the aqueous phase, the concentration of the source phase, the concentration of the carrier in the BLM and the temperature on the Pb2+-separation were investigated. Moreover, the effects of the competitive inhibition due to the presence of Ag+, Ca2+, Co2+, Cu2+, K+, Mg2+, Na+ and Zn2+ as competing ions in a multicomponent aqueous source phase of different ion-concentrations were also studied. After a proper dilution of the multicomponent aqueous source phase, excellent Pb2+-selectivity was achieved without a significant reduction in the efficiency compared to the liquid membrane transport of single-component systems. Based on the BLM-cell studies the applied selector molecule proved to be suitable for the development of liquid membrane-based Pb2+-selective separation methods, which can be greatly aided by the analysis of the effects on the separation and by the optimization of the parameters of the process discussed here.

scholarly journals TRANSPORT BEHAVIOR OF Cr(III), Cd(II), Pb(II), AND Ag(I) IONS THROUGH BULK LIQUID MEMBRANE CONTAINING p-tert-BUTYLCALIX[4]ARENE–TETRADIETHYLACETAMIDE AS ION CARRIER

2010 ◽  
Vol 8 (3) ◽  
pp. 300-306 ◽  
Author(s):  
Maming Maming ◽  
Jumina Jumina ◽  
Dwi Siswanta ◽  
Hardjono Sastrohamidjojo ◽  
Keisuke Ohto
Keyword(s):  
Optimum Condition ◽  
Liquid Membrane ◽  
Bulk Liquid ◽  
High Concentration ◽  
Bulk Liquid Membrane ◽  
Transport Efficiency ◽  
Transport Behavior ◽  
Source Phase ◽  
Ion Carrier

The study on the transport behavior of Cr(III), Cd(II), Pb(II), and Ag(I) through bulk liquid membrane using p-tert-butylcalix[4]arene-tetradiethylacetamide as ions carrier has been conducted. The aims of this work are to determine the optimum condition, efficiency, and transport selectivity of the carriers for those ions. Both optimum condition and transport efficiency were obtained by determination of the concentration of transported ions with variation of the source phase pH, ion carrier concentration, the nature of decomplexant agent in the receiving phase, and transport time. The transport selectivity of the ion carrier was obtained from the ions competition transport experiments. The amount of Cr(III), Pb(II), Cd(II), and Ag(I) transported across liquid membrane were 11.6, 25.5, 39.5, and 42.1% respectively. The ion carrier is selective for Cd(II), Pb(II), Ag(I), and strongly depends on the nature of decomplexant agent as well as transport mechanism. The remarkable selectivity was shown by the ion carrier to Ag(I) when the transport process was carry out under high concentration of acid in the source phase.   Keywords: transport, p-tert-butylcalix[4]arene-tetradiethylacetamide, efficiency, selectivity, bulk liquid membrane, heavy metals

scholarly journals Removal of Acetaminophen Residues from Wastewater by Bulk Liquid Membrane Process

2020 ◽  
Vol 21 (4) ◽  
pp. 1-9
Author(s):  
Sawsan Abd Muslim Mohammed Albasri ◽  
Husna Salim Wahab
Keyword(s):  
Activation Energy ◽  
Carrier Concentration ◽  
Extraction Efficiency ◽  
Liquid Membrane ◽  
Volume Ratio ◽  
Bulk Liquid ◽  
Membrane Phase ◽  
Bulk Liquid Membrane ◽  
Nacl Concentration ◽  
Feed Phase

   The removal of Anit-Inflammatory drugs, namely; Acetaminophen (ACTP), from wastewater by bulk liquid membrane (BLM) process using Aliquat 336 (QCl) as a carrier was investigated. The effects of several parameters on the extraction efficiency were studied in this research, such as the initial feed phase concentration (10-50) ppm of ACTP, stripping phase (NaCl) concentration (0.3,0.5,0.7 M), temperature (30-50oC), the volume ratio of feed phase to membrane phase (200-400ml/80ml), agitation speed of the feed phase (75-125 rpm), membrane stirring speed (0, 100, 150 rpm), carrier concentration (1, 5, 9 wt%), the pH of feed (2, 4, 6, 8, 10), and solvent type (CCl4 and n-Heptane). The study shows that high extraction efficiency for ACTP of about 97% was achieved by a bulk liquid membrane at 50 ppm initial concentration of feed; stirring speed of feed phase 130 rpm; stirring speed of membrane phase 100rpm; 0.5 M NaCl concentration; carrier concentration 1wt%; volume ratio of 200ml feed:80ml membrane; feed pH of ACTP is 6,  and 50˚C. The transport kinetics was evaluated using a kinetic model with two consecutive first-order irreversible reactions. The kinetics of (ACTP) transport by bulk liquid membrane was investigated at the best experimental conditions. The activation energy values of the extraction and stripping processes were 1.733 and 1.826 kJ.mol−1. The activation energy confirms that the transport process from solutions is controlled by diffusion.

scholarly journals Synthesis of A Novel Carrier Compound Thiazoethyl Methyl Eugenoxyacetate from Eugenol and Its Use in the Bulk Liquid Membrane Technique

2018 ◽  
Vol 18 (1) ◽  
pp. 121 ◽  
Author(s):  
Muhammad Cholid Djunaidi ◽  
Pratama Jujur Wibawa ◽  
Ratna Hari Murti
Keyword(s):  
Metal Ions ◽  
Retention Time ◽  
Liquid Membrane ◽  
Vibration Mode ◽  
Ester Group ◽  
Ftir Spectrum ◽  
Bulk Liquid ◽  
Bulk Liquid Membrane ◽  
Selective Transport ◽  
Membrane Technique

Research into the synthesis and use of a novel carrier compound, thiazoethyl methyl eugenoxyacetic acid (TMEAA) for selective transport of Cu(II), Cd(II) and Cr(III) metal ions in the bulk liquid membrane (BLM) technique was conducted. TMEAA was synthesized from eugenol. Eugenol was acidified into eugenoxyacetic acid and subsequently esterified using 4-methyl-5-thiazoethanol. Analysis of the result was performed using GC-MS and FTIR. The TMEAA obtained was liquid, viscous, blackish-brown and fragrant, with a yield of 88%. This compound was soluble in benzene and chloroform but insoluble in methanol. The GC-MS analysis result showed the presence of a single peak, with a retention time of 26.5 min and an area of 100%, while the disappearance of vibration mode at 1727 cm-1 was attributed to acid absorption and the FTIR spectrum indicated that formation of an ester group had occurred. TMEAA was used as a carrier compound in the BLM technique to transport Cu(II), Cd(II) and Cr(III), using chloroform as a solvent. The results showed that TMEAA was more selective for Cu(II) and Cd(II) than Cr(III). Moreover, the research proved that N and S groups of TMEAA were selective for Cu (II) and Cd (II).

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