scholarly journals Metrology in chemistry: some questions and answers

2020 ◽  
Vol 14 (2) ◽  
pp. 83-87
Author(s):  
Ivo Leito ◽  
Irja Helm

This article presents some typical questions from practitioners, trying to implement metrological concepts in their everyday chemical analysis work, and answers to them by the authors, in the context of the authors’ pragmatic view on applying the metrological principles to chemical analysis. Several of the presented questions are staples at training seminars and during on-line courses. The answers to the questions reflect the authors’ opinions and are not always fully in line with the generally accepted positions.

1995 ◽  
Vol 16 (2) ◽  
pp. 75-82 ◽  
Author(s):  
B. Bescós ◽  
J. Castaño ◽  
A. González Ureña

This paper reports on the simultaneous detection of Mg, Mn, Fe and Pb in Al samples using laser-induced breakdown spectroscopy and optical multichannel analysis of the photoablated microplasma. Using calibrated samples, well characterized linear working curves were determined for these minor components over the 0.01–1% concentration range. In addition optimum experimental conditions were found that allow the analysis to be carded out in a fast and non-invasive manner. The potential application of the method to on-line industrial analysis is also suggested.


1997 ◽  
Vol 346 (3) ◽  
pp. 341-349 ◽  
Author(s):  
Eithne Dempsey ◽  
Dermot Diamond ◽  
Malcolm R Smyth ◽  
Gerald Urban ◽  
Gerhard Jobst ◽  
...  

1997 ◽  
Vol 28 ◽  
pp. S445-S446 ◽  
Author(s):  
P. Mikuska ◽  
A. Khlystov ◽  
H.M. ten Brink ◽  
G.P. Wyers ◽  
J. Slanina
Keyword(s):  

1992 ◽  
Author(s):  
Michel F. Sultan ◽  
Michael J. O'Rourke
Keyword(s):  

2014 ◽  
Vol 7 (9) ◽  
pp. 10109-10130 ◽  
Author(s):  
P. Eichler ◽  
M. Müller ◽  
B. D'Anna ◽  
A. Wisthaler

Abstract. We herein present the concept of a novel modular inlet system that allows using gas-phase analyzers for on-line chemical characterization of semi-volatile submicron particles. The "chemical analysis of aerosol on-line" (CHARON) inlet consists of a gas-phase denuder for stripping off gas-phase analytes, an aerodynamic lens for particle enrichment in the sampling flow and a thermo-desorption unit for particle volatilization prior to chemical analysis. We coupled the CHARON inlet to a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS) which quantitatively detects most organic analytes and ammonia. The combined set-up measures submicron organic and ammonium nitrate/sulfate particles online. Two proof-of-principle studies were carried out for demonstrating the analytical power of the new set-up in analyzing primarily emitted and secondarily generated particles. Oxygenated organics and their partitioning between the gas and the particulate phase were observed from the reaction of limonene with ozone. Abundant quasi-molecular ions of organic particulate constituents were observed when submicron particles were sampled from diluted mainstream cigarette smoke.


2010 ◽  
Vol 397 (7) ◽  
pp. 2939-2947 ◽  
Author(s):  
Anna M. Clark ◽  
Kyle M. Sousa ◽  
Claire N. Chisolm ◽  
Ormond A. MacDougald ◽  
Robert T. Kennedy

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