scholarly journals Effects of hydrogen blending on hydraulic and thermal characteristics of natural gas pipeline and pipe network

Author(s):  
Heng Zhang ◽  
Jingfa Li ◽  
Yue Su ◽  
Peng Wang ◽  
Bo Yu

Blending a fraction of hydrogen into the natural gas pipeline or urban pipe network is an efficient approach for hydrogen delivery. In this paper, the mathematical model of Hydrogen-Blended Natural Gas (HBNG) transportation is established, and the influences of hydrogen blending on hydraulic and thermal characteristics of natural gas pipeline and pipe network are numerically investigated. The impact of hydrogen blending ratio on the performance of centrifugal compressor and the operating point for joint operation of pipeline and compressor is discussed. Results illustrate that compared with natural gas without hydrogen, the hydrogen blending can reduce the pipeline friction resistance and increase the volume flow rate. However, due to the lower volumetric calorific value of HBNG, the energy flow rate actually decreases under the same transportation condition. Meanwhile, the temperature drop along the pipeline slows down due to the blended hydrogen. The performance degradation of centrifugal compressor occurs with the increasing hydrogen blending ratio, and the operating point for joint operation of pipeline and centrifugal compressor moves to the direction of higher volume flow rate and lower pressure. This study is expected to shed a light on the hydrogen delivery by natural gas pipelines and pipe networks.

Gases ◽  
2021 ◽  
Vol 1 (4) ◽  
pp. 156-179
Author(s):  
Abubakar Jibrin Abbas ◽  
Hossein Hassani ◽  
Martin Burby ◽  
Idoko Job John

As an alternative to the construction of new infrastructure, repurposing existing natural gas pipelines for hydrogen transportation has been identified as a low-cost strategy for substituting natural gas with hydrogen in the wake of the energy transition. In line with that, a 342 km, 36″ natural gas pipeline was used in this study to simulate some technical implications of delivering the same amount of energy with different blends of natural gas and hydrogen, and with 100% hydrogen. Preliminary findings from the study confirmed that a three-fold increase in volumetric flow rate would be required of hydrogen to deliver an equivalent amount of energy as natural gas. The effects of flowing hydrogen at this rate in an existing natural gas pipeline on two flow parameters (the compressibility factor and the velocity gradient) which are crucial to the safety of the pipeline were investigated. The compressibility factor behaviour revealed the presence of a wide range of values as the proportions of hydrogen and natural gas in the blends changed, signifying disparate flow behaviours and consequent varying flow challenges. The velocity profiles showed that hydrogen can be transported in natural gas pipelines via blending with natural gas by up to 40% of hydrogen in the blend without exceeding the erosional velocity limits of the pipeline. However, when the proportion of hydrogen reached 60%, the erosional velocity limit was reached at 290 km, so that beyond this distance, the pipeline would be subject to internal erosion. The use of compressor stations was shown to be effective in remedying this challenge. This study provides more insights into the volumetric and safety considerations of adopting existing natural gas pipelines for the transportation of hydrogen and blends of hydrogen and natural gas.


Author(s):  
Igor Petryshyn ◽  
◽  
Olexandr Bas ◽  
◽  

The paper focuses on the need to determine the natural gas heat combustion in order to transition to gas metering in units of energy. The technical organization of gas transportation in the main and distribution pipelines on the territory of Ukraine is shown. A detailed analysis of regulatory and legal support, which regulates the definition and accounting of quantitative and qualitative characteristics of natural gas at gas metering units. The draft Rules for determining the natural gas volume are considered in detail. Specified variants of determining the weighted average value of combustion heat in the case of complex gas supply systems with the use of flow measuring means of gas combustion heat. The necessity and urgency of determining the natural gas heat combustion on measuring systems, which are equipped with duplicate metering units without the installation flow means measuring the heat combustion. Emphasis is placed on the fact that a large number of measuring systems are built on the method of variable pressure drop with the use of standard orifice devices. It is pointed out that this method, according to its physical principle, measures the mass gas flow rate. It is also stipulated that ultrasonic gas meters are often used to complete duplicate metering units. The advantages of ultrasonic meters are given. Attention is drawn to the availability of technical metrological support in Ukraine on the basis calibration prover, which includes two secondary standards gas volume and volume flow rate units. Methods and technical means for determining the natural gas heat combustion are analyzed. The calculation of the gas heat combustion and the Wobbe number based on the density values is shown. It is noted that the value of the gas mass flow rate is related to the value of the gas volume flow rate precisely the value of density. The nonlinear dependence of the gas mass heat combustion for the density, which is associated with a disproportionate change in the percentage of carbon atoms to hydrogen atoms, is shown. The structural scheme of the measuring system with the duplicating metering unit for gas density definition and gas heat combustion calculation is developed. The density calculation and natural gas heat combustion depending on the molar fraction of nitrogen and carbon dioxide in the gas from the minimum to the maximum value is carried out. The linear dependence of the change in the gas heat combustion for the molar fraction of nitrogen is established, on the basis of which the method of controlling the gas heat combustion for measuring systems with a duplicate metering unit is proposed. It is shown that the developed procedure for determining the natural gas heat combustion based on the value of density, which is obtained from the calculation of gas mass flow rate and gas volume flow rate consumption on measuring systems with duplicate metering units exactly satisfies class B and C according to DSTU OIML R 140.


Author(s):  
Joe A. Mascorro ◽  
Gerald S. Kirby

Embedding media based upon an epoxy resin of choice and the acid anhydrides dodecenyl succinic anhydride (DDSA), nadic methyl anhydride (NMA), and catalyzed by the tertiary amine 2,4,6-Tri(dimethylaminomethyl) phenol (DMP-30) are widely used in biological electron microscopy. These media possess a viscosity character that can impair tissue infiltration, particularly if original Epon 812 is utilized as the base resin. Other resins that are considerably less viscous than Epon 812 now are available as replacements. Likewise, nonenyl succinic anhydride (NSA) and dimethylaminoethanol (DMAE) are more fluid than their counterparts DDSA and DMP- 30 commonly used in earlier formulations. This work utilizes novel epoxy and anhydride combinations in order to produce embedding media with desirable flow rate and viscosity parameters that, in turn, would allow the medium to optimally infiltrate tissues. Specifically, embeding media based on EmBed 812 or LX 112 with NSA (in place of DDSA) and DMAE (replacing DMP-30), with NMA remaining constant, are formulated and offered as alternatives for routine biological work.Individual epoxy resins (Table I) or complete embedding media (Tables II-III) were tested for flow rate and viscosity. The novel media were further examined for their ability to infilftrate tissues, polymerize, sectioning and staining character, as well as strength and stability to the electron beam and column vacuum. For physical comparisons, a volume (9 ml) of either resin or media was aspirated into a capillary viscocimeter oriented vertically. The material was then allowed to flow out freely under the influence of gravity and the flow time necessary for the volume to exit was recored (Col B,C; Tables). In addition, the volume flow rate (ml flowing/second; Col D, Tables) was measured. Viscosity (n) could then be determined by using the Hagen-Poiseville relation for laminar flow, n = c.p/Q, where c = a geometric constant from an instrument calibration with water, p = mass density, and Q = volume flow rate. Mass weight and density of the materials were determined as well (Col F,G; Tables). Infiltration schedules utilized were short (1/2 hr 1:1, 3 hrs full resin), intermediate (1/2 hr 1:1, 6 hrs full resin) , or long (1/2 hr 1:1, 6 hrs full resin) in total time. Polymerization schedules ranging from 15 hrs (overnight) through 24, 36, or 48 hrs were tested. Sections demonstrating gold interference colors were collected on unsupported 200- 300 mesh grids and stained sequentially with uranyl acetate and lead citrate.


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