Chemically Fueled Block Copolymer Self-Assembly into Transient Nanoreactors
Keyword(s):
The Self
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In chemically fueled supramolecular materials, molecular self-assembly is coupled to a fuel-driven chemical reaction cycle. The fuel-dependence makes the material dynamic and endows it with exciting properties like adaptivity and autonomy. In contrast to the large work on the self-assembly of small molecules, we herein designed a diblock copolymer, which self assembles into transient micelles when coupled to a fuel-driven chemical reaction cycle. Moreover, we used these transient block copolymer micelles to locally increase the concentration of hydrophobic reagents and thereby function as a transient nanoreactor.
2021 ◽
2017 ◽
Vol 36
(3)
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pp. 266-272
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2014 ◽
Vol 20
(8)
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pp. 957-965
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2006 ◽
Vol 128
(8)
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pp. 2745-2750
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2010 ◽
Vol 114
(28)
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pp. 9128-9134
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