Interaction of Salt Melts of Magnesium Production with Atmospheric Air

2019 ◽  
Vol 60 (3) ◽  
pp. 215-224
Author(s):  
I. M. Komelin ◽  
A. P. Lysenko
2005 ◽  
Vol 488-489 ◽  
pp. 89-94 ◽  
Author(s):  
I.V. Zabyelin ◽  
Igor M. Komelin ◽  
Ivan A. Barannik ◽  
I.L. Sikorskaya

This paper covers information on salt melts, used in crucibleless electrical furnaces as a heating element, which interact with atmospheric air to form solid and gaseous products and mostly determine the furnace design, governing furnace maintenance conditions and its service life.


Author(s):  
I. M. Komelin ◽  
A. P. Lysenko ◽  
D. S. Kondrat'eva

Corrosion tests of SCh15 cast iron, Steel 3 and Steel 3 with aluminized coating in some compositions of 10%MgCl2-KCl-NaCl and 10%MgCl2-KCl-Naa-Caa2 salt melts with 10 %, 25 % and 40 % CaCl2 concentrations, and also in 10MgCl2-45%KCl-20%NaCl-25%NaBr melt, and in the gas phase above these melts at 700 °C. A gravimetric method was used to determine corrosion rates of metal samples. Chemical analysis of absorption solutions was used to determine concentrations of halide and hydrogen halide impurities in air blown through the reactor with melts and samples. It was shown that carbon steel aluminizing can reduce the corrosion rate in the gas phase over the salt melt by a factor of 5 to 70. The formation mechanism of gases aggressive in relation to carbon steel and cast iron in atmospheric air in contact with salt chloride melt was considered. Accelerated hydrogen chloride and chlorine formation during the salt melt interaction with atmospheric air under the influence of iron corrosion products was found.


Author(s):  
B. S. Soroka

The article considers the role and place of water and water vapor in combustion processes with the purpose of reduction the effluents of nitrogen oxides and carbon oxide. We have carried out the complex of theoretical and computational researches on reduction of harmful nitrogen and carbon oxides by gas fuel combustion in dependence on humidity of atmospheric air by two approaches: CFD modeling with attraction of DRM 19 chemical kinetics mechanism of combustion for 19 components along with Bowman’s mechanism used as “postprocessor” to determine the [NO] concentration; different thermodynamic models of predicting the nitrogen oxides NO formation. The numerical simulation of the transport processes for momentum, mass and heat being solved simultaneously in the united equations’ system with the chemical kinetics equations in frame of GRI methane combustion mechanism and NO formation calculated afterwards as “postprocessor” allow calculating the absolute actual [CO] and [NO] concentrations in dependence on combustion operative conditions and on design of furnace facilities. Prediction in frame of thermodynamic equilibrium state for combustion products ensures only evaluation of the relative value of [NO] concentration by wet combustion the gas with humid air regarding that in case of dry air – oxidant. We have developed the methodology and have revealed the results of numerical simulation of impact of the relative humidity of atmospheric air on harmful gases formation. Range of relative air humidity under calculations of atmospheric air under impact on [NO] and [CO] concentrations at the furnace chamber exit makes φ = 0 – 100%. The results of CFD modeling have been verified both by author’s experimental data and due comparing with the trends stated in world literature. We have carried out the complex of the experimental investigations regarding atmospheric air humidification impact on flame structure and environmental characteristics at natural gas combustion with premixed flame formation in open air. The article also proposes the methodology for evaluation of the nitrogen oxides formation in dependence on moisture content of burning mixture. The results of measurements have been used for verification the calculation data. Coincidence of relative change the NO (NOx) yield due humidification the combustion air revealed by means of CFD prediction has confirmed the qualitative and the quantitative correspondence of physical and chemical kinetics mechanisms and the CFD modeling procedures with the processes to be studied. A sharp, more than an order of reduction in NO emissions and simultaneously approximately a two-fold decrease in the CO concentration during combustion of the methane-air mixture under conditions of humidification of the combustion air to a saturation state at a temperature of 325 K.


2019 ◽  
Vol 14 (3) ◽  
pp. 226
Author(s):  
Khanit Matra ◽  
Yottana Tanakaran ◽  
Teerawat Temponsub ◽  
Suphanat Nimbua ◽  
Phanuwat Thab-in ◽  
...  

1993 ◽  
Author(s):  
JAY GRINSTEAD ◽  
GABRIEL LAUFER ◽  
JAMES MCDANIEL, JR.

Author(s):  
S. M. FROLOV ◽  
◽  
S. V. Platonov ◽  
K. A. AVDEEV ◽  
V. S. AKSENOV ◽  
...  

To reduce the hydrodynamic drag force to the movement of the boat, an artificial gas cavity is organized under its bottom. Such a cavity partially insulates the bottom from direct contact with water and provides “gas lubrication” by means of forced supply of atmospheric air or exhaust gases from the main propulsion system. A proper longitudinal and transverse shaping of the gas cavity can significantly (by 20%-30%) reduce the hydrodynamic drag of the boat at low (less than 3%) consumption of the propulsion system power for gas supply.


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