Production of Tagatose from Galactose in a Batch-type Reactor Using a Phosphate Buffer under Subcritical Water Conditions

2020 ◽  
Vol 26 (6) ◽  
pp. 695-699
Author(s):  
Shuji Adachi ◽  
Yayoi Miyagawa ◽  
Takashi Kobayashi
2010 ◽  
Vol 160 (1) ◽  
pp. 259-266 ◽  
Author(s):  
Omid Pourali ◽  
Feridoun Salak Asghari ◽  
Hiroyuki Yoshida

Catalysts ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 1270
Author(s):  
Yuanyuan Zhao ◽  
Kansei Konishi ◽  
Eiji Minami ◽  
Shiro Saka ◽  
Haruo Kawamoto

Ru-Sn/TiO2 is an effective catalyst for hydrogenation of aqueous acetic acid to ethanol. In this paper, a similar hydrogenation process was investigated in a flow-type rather than a batch-type reactor. The optimum temperature was 170 °C for the batch-type reactor because of gas production at higher temperatures; however, for the flow-type reactor, the ethanol yield increased with reaction temperature up to 280 °C and then decreased sharply above 300 °C, owing to an increase in the acetic acid recovery rate. The selectivity for ethanol formation was improved over the batch process, and an ethanol yield of 98 mol % was achieved for a 6.7 min reaction (cf. 12 h for batch) (liquid hourly space velocity: 1.23 h−1). Oxidation of ethanol to acetic acid (i.e., the reverse reaction) adversely affected the hydrogenation. On the basis of these results, hydrogenation mechanisms that include competing side reactions are discussed in relation to the reactor type. These results will help the development of more efficient catalytic procedures. This method was also effectively applied to hydrogenation of lactic acid to propane-1,2-diol.


1986 ◽  
Vol 8 (3) ◽  
pp. 106-121 ◽  
Author(s):  
Daniel F. Chodosh ◽  
Kenneth Kamholz ◽  
Sidney H. Levinson ◽  
Robert Rhinesmith

2014 ◽  
Vol 170 ◽  
pp. 454-461 ◽  
Author(s):  
Sundaravadivelnathan Ponnusamy ◽  
Harvind Kumar Reddy ◽  
Tapaswy Muppaneni ◽  
Cara Meghan Downes ◽  
Shuguang Deng

2016 ◽  
Vol 4 (46) ◽  
pp. 10903-10913 ◽  
Author(s):  
Cecilia Granados-Miralles ◽  
Matilde Saura-Múzquiz ◽  
Espen D. Bøjesen ◽  
Kirsten M. Ø. Jensen ◽  
Henrik L. Andersen ◽  
...  

Hydrothermal synthesis of SrFe12O19 is followed in situ using PXRD, and successfully reproduced ex situ using a custom-designed batch-type reactor.


2009 ◽  
Vol 87 (6) ◽  
pp. 867-873 ◽  
Author(s):  
R. Alenezi ◽  
G.A. Leeke ◽  
R.C.D. Santos ◽  
A.R. Khan

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