THE REGULARITY OF HEAVY METALS DISTRIBUTION AND BEHAVIOR IN THE BOTTOM SEDIMENTS ON THE PROFILE “NORTHERN DVINA RIVER – WHITE SEA”

Author(s):  
Alina Zimovets ◽  
Alina Zimovets ◽  
Yury Fedorov ◽  
Yury Fedorov ◽  
Asya Ovsepyan ◽  
...  

A study was conducted to investigate the level of heavy metals in bottom sediments of the Northern Dvina mouth area and the White Sea in various seasons since 2004. Of greatest interest for the study was presented as such heavy metals as Hg, Pb, Cd, Cu, Ni, Zn, Cr, which belong to the priority group of toxic elements. The heavy metals concentrations were determined with atomic absorption spectrometer. Also the grain-size composition, concentrations of organic carbon and values of hydrogen ion exponent (pH) and redox potential (Eh) in bottom sediments were determined. It was found that the levels of heavy metals in sediments significantly changed in the lateral radial direction. There is a tendency to increased concentrations of some heavy metals downstream of the river. The high concentrations of heavy metals were found within the influence of cities and towns. So the extremely high mercury concentrations were found in the sediments of small and shallow channels crossing the Arkhangelsk city. The study of heavy metal concentrations in the bottom sediments along the profile “the Northern Dvina - Dvina Bay - White sea” showed that the marginal filter contributes to the coprecipitation with suspended metals of anthropogenic genesis. These processes greatly reduce the contamination risk of the White Sea. Thus, the impact of the river on the ecosystem of the White Sea outside the marginal filter is significantly less.

Author(s):  
Alina Zimovets ◽  
Alina Zimovets ◽  
Yury Fedorov ◽  
Yury Fedorov ◽  
Asya Ovsepyan ◽  
...  

A study was conducted to investigate the level of heavy metals in bottom sediments of the Northern Dvina mouth area and the White Sea in various seasons since 2004. Of greatest interest for the study was presented as such heavy metals as Hg, Pb, Cd, Cu, Ni, Zn, Cr, which belong to the priority group of toxic elements. The heavy metals concentrations were determined with atomic absorption spectrometer. Also the grain-size composition, concentrations of organic carbon and values of hydrogen ion exponent (pH) and redox potential (Eh) in bottom sediments were determined. It was found that the levels of heavy metals in sediments significantly changed in the lateral radial direction. There is a tendency to increased concentrations of some heavy metals downstream of the river. The high concentrations of heavy metals were found within the influence of cities and towns. So the extremely high mercury concentrations were found in the sediments of small and shallow channels crossing the Arkhangelsk city. The study of heavy metal concentrations in the bottom sediments along the profile “the Northern Dvina - Dvina Bay - White sea” showed that the marginal filter contributes to the coprecipitation with suspended metals of anthropogenic genesis. These processes greatly reduce the contamination risk of the White Sea. Thus, the impact of the river on the ecosystem of the White Sea outside the marginal filter is significantly less.


Author(s):  
Liudmila L. Demina ◽  
Dmitry F. Budko ◽  
Alexander N. Novigatsky ◽  
Tatiana N. Alexсeeva ◽  
Anastasia I. Kochenkova

2021 ◽  
Vol 11 (14) ◽  
pp. 6592
Author(s):  
Ana Moldovan ◽  
Maria-Alexandra Hoaghia ◽  
Anamaria Iulia Török ◽  
Marius Roman ◽  
Ionut Cornel Mirea ◽  
...  

This study aims to investigate the quality and vulnerability of surface water (Aries River catchment) in order to identify the impact of past mining activities. For this purpose, the pollution and water quality indices, Piper and Durov plots, as well vulnerability modeling maps were used. The obtained results indicate that the water samples were contaminated with As, Fe, Mn, Pb and have relatively high concentrations of SO42−, HCO3−, TDS, Ca, K, Mg and high values for the electrical conductivity. Possible sources of the high content of chemicals could be the natural processes or the inputs of the mine drainage. Generally, according to the pollution indices, which were correlated to high concentrations of heavy metals, especially with Pb, Fe and Mn, the water samples were characterized by heavy metals pollution. The water quality index classified the studied water samples into five different classes of quality, namely: unsuitable for drinking, poor, medium, good and excellent quality. Similarly, medium, high and very high vulnerability classes were observed. The Durov and Piper plots classified the waters into Mg-HCO3− and Ca-Cl− types. The past and present mining activities clearly change the water chemistry and alter the quality of the Aries River, with the water requiring specific treatments before use.


Geosciences ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 332
Author(s):  
Nadezhda Khaustova ◽  
Yulia Tikhomirova ◽  
Svetlana Korost ◽  
Elena Poludetkina ◽  
Andrey Voropaev ◽  
...  

To evaluate the effect of redox conditions at the sedimentation stage on uranium content and U/TOC ratio in marine source rocks, we analyzed the accumulation of uranium in modern marine bottom sediments formed in different redox conditions. The behavior of uranium from bottom sediments formed in oxidizing and sub-oxidizing settings has been studied on the sediments of the Upper Pleistocene–Holocene age accumulated in the coastal area of the White Sea (Kandalaksha Gulf). We studied the content of uranium, Eh, pH, TOC, C, H, N, and S element and isotope compositions and other parameters in two sampled columns of bottom sediments at a depth of 0–2.5 m. The composition of sediments was typical for the shelf zone where marine genesis mixes with the continental run-off. The upper layer of sediments (0–50 cm) were characterized by oxidizing conditions (Eh ~ 400 mV); with the increase in depth, redox conditions changed from oxidizing to reducing (0 ÷ 200 mV). The uranium concentration in the upper layer was 1–1.5 ppm, U/TOC ratio varied in the range of 0.8–1.1 ppmU/%TOC. The uranium content and U/TOC ratio increased up to the values of 2.6 ppm and 1.4 ppmU/%TOC at a depth of 0.5−2.5 m, respectively, but the general content of uranium in the studied environment was close to the values characterizing continental run-off. The results obtained for the White Sea sediments were compared with the sediment of the Black Sea, formed in the anoxic conditions of hydrogen sulfide contamination. In these conditions, the uranium content varied from 10 to 20 ppm. The obtained data were interpreted using thermodynamic modeling of the uranium forms in the seawater at different pH and Eh. This study demonstrated that the change of redox conditions from oxidizing to reducing leads to increased uranium content due to a decrease in uranium’s solubility in water. These results show that oxidation–reduction potential could be one of the most important factors controlling uranium content in black shales formed in the marine environment.


2006 ◽  
Vol 54 (6-7) ◽  
pp. 307-314 ◽  
Author(s):  
B. Béchet ◽  
B. Durin ◽  
M. Legret ◽  
P. Le Cloirec

The thickness of non-saturated zone and physico-chemical conditions are important parameters to assess the impact of infiltration ponds on water resources with respect to heavy metals transfer. As changes in physico-chemical parameters of solutions have a strong impact on the mobility of colloidal phases in sediments and soils, the colloidal facilitated transfer of heavy metals has to be investigated. Therefore, this study focuses on the characterization of runoff, surface and interstitial waters in a retention/infiltration pond collecting runoff waters of a bridge near Nantes. Physico-chemical parameters and chemical analyses were performed on the waters during about one year. The separation of dissolved and colloidal fractions was carried out by filtration and ultrafiltration for one sample of surface and interstitial waters. Until now, the runoff waters were only filtered at 0.45 μm. The comparison of physico-chemical data shows that the minor variations of runoff water parameters are mitigated in basin and in soils but strong variations impact the composition of interstitial waters. High concentrations of zinc, copper and still of lead are measured in runoff. Lead and cadmium seem to be associated to colloidal and particulate fractions while zinc, copper, nickel and chromium are distributed in all fractions.


2006 ◽  
Vol 406 (1) ◽  
pp. 136-140 ◽  
Author(s):  
G. A. Leonova ◽  
V. A. Bobrov ◽  
V. P. Shevchenko ◽  
A. A. Prudkovskii

Baltica ◽  
2019 ◽  
Vol 32 (1) ◽  
pp. 51-62
Author(s):  
Alexander Krek ◽  
Aleksandr Danchenkov ◽  
Marina Ulyanova ◽  
Darya Ryabchuk

The scope of the study was to assess the impact of potential sources of Cu, Zn, Co, Ni, and Cr on bottom sediments of the Russian sector of the south-eastern Baltic Sea. A total of 68 samples were taken and analyzed for grain-size (laser diffraction and sieve method) and heavy metal concentration (atomic absorption spectroscopy method). To avoid the influence of the sorption capacity of the fine-grained sediments to accumulate the pollutants, the normalization of the heavy metal concentration to Fe was applied. The environmental indices (contamination factor and modified degree of contamination) were calculated. The research has shown the contribution of oil platform, pipelines, ports and wastewater treatment facilities on the geochemical composition of bottom sediments. The authors have identified the level of heavy metals contamination of the middle parts of the Curonian and Vistula spits as a result of alongshore transport of pollutants.


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