scholarly journals Removal of Reactive Green 12 Dye and COD from Simulated Wastewater Using Different Coagulants

Author(s):  
Tamara Kawther Hussein ◽  
Nidaa Adil Jasim

The ability of using each of the following: aluminum sulphate (Al2(SO4)3.16H2O), ferric chloride (FeCl3), and ferrous sulphate (FeSO4) as chemical coagulants was investigated for removing of reactive green 12 (RG 12) dye and chemical oxygen demand (COD) from simulated wastewater. Best pH , coagulants dosages, and initial concentrations were obtained by jar test. The maximum efficiency for removing RG-12 and COD recorded by ferric chloride were 98% and 88 %,  by alum were 95% and 88%, and by ferrous sulphate were 70% and 50%. All these results obtained at the best pH 6, dosage 100 mg/l and initial concentrations for RG-12 and COD 50 mg/l and 600 mg/l respectively. The maximum volume of sludge was for alum coagulant 14 ml/l, 12 ml/l for ferric chloride and 0.5 ml/l for ferrous sulphate. The study improved that it is possible to use each of aluminum sulphate, ferric chloride and ferrous sulphate as an economical coagulant to treat the wastewater which it is polluted with RG 12 dye and COD.

1978 ◽  
Vol 5 (1) ◽  
pp. 83-97 ◽  
Author(s):  
Robert D. Cameron

The use of cheap, locally available peat as a treatment method for landfill leachate was investigated by passing leachate through plexiglass columns filled with an amorphous-granular peat. Preliminary adjustment of pH showed that reducing pH to 4.8 dramatically reduced adsorption. Increasing the pH to 8.4, metal removal was increased owing to filtration of precipitated metals. The best adsorption of metals occurred at the 'natural' pH of 7.1. Manganese was found to be the limiting pollutant. At the 0.05 mg/ℓ maximum acceptable manganese concentration 94% of the total metals were removed, requiring 159 kg of peat per 1000 ℓ of leachate.Resting the peat for 1 month did significantly increase removal capacity.Desorption of some contaminants occurred when water was percolated through the peat. The desorption test effluent was not toxic to fish although iron, lead and COD (chemical oxygen demand) exceeded acceptable values.Chemical pretreatment using lime and ferric chloride achieved significant iron, manganese and calcium removals. Chemical pretreatment followed by peat adsorption offered no advantage other than reducing toxicity to fish.Peat treatment alone was effective in reducing concentrations to a level that was non-toxic to fish.


2008 ◽  
Vol 4 (1) ◽  
pp. 318-322 ◽  
Author(s):  
Lugard Ukiwe ◽  
I.C. Iwu ◽  
Chijioke Okere M

An investigation into the ability of four inorganic coagulants namely; alum (Al2(SO4)3.18H2O), ammonium aluminum sulphate (NH4Al(SO4)2.12H2O), ferrous sulphate (FeSO4) and ammonium ferrous sulphate (NH4)2Fe(SO4)2.6H2O) in clarifying wastewater was examined. Results obtained from conventional standard ‘jar-test’ experiments indicated that alum was the most effective coagulant since it reduced turbidity of the wastewater to 0.64 NTU at a contact time of 300 min. Ferrous sulphate was the least effective coagulant, reducing turbidity of the wastewater to 3.45 NTU only at 240 min contact time, but when the contact time of the experiment was increased from 240 to 300 min, re-coloration of the solution was observed indicating re-stabilization of suspended particles. These findings tend to support the claim that alum is a choice coagulant for wastewater clarification.   


2013 ◽  
Vol 8 (1) ◽  
pp. 318-322
Author(s):  
Lugard Ukiwe ◽  
I.C. Iwu ◽  
Chijioke Okere M

An investigation into the ability of four inorganic coagulants namely; alum (Al2(SO4)3.18H2O), ammonium aluminum sulphate (NH4Al(SO4)2.12H2O), ferrous sulphate (FeSO4) and ammonium ferrous sulphate (NH4)2Fe(SO4)2.6H2O) in clarifying wastewater was examined. Results obtained from conventional standard ‘jar-test’ experiments indicated that alum was the most effective coagulant since it reduced turbidity of the wastewater to 0.64 NTU at a contact time of 300 min. Ferrous sulphate was the least effective coagulant, reducing turbidity of the wastewater to 3.45 NTU only at 240 min contact time, but when the contact time of the experiment was increased from 240 to 300 min, re-coloration of the solution was observed indicating re-stabilization of suspended particles. These findings tend to support the claim that alum is a choice coagulant for wastewater clarification.   


2013 ◽  
Vol 12 (2) ◽  
pp. 318-322
Author(s):  
Lugard Ukiwe ◽  
I.C. Iwu ◽  
Chijioke Okere M

An investigation into the ability of four inorganic coagulants namely; alum (Al2(SO4)3.18H2O), ammonium aluminum sulphate (NH4Al(SO4)2.12H2O), ferrous sulphate (FeSO4) and ammonium ferrous sulphate (NH4)2Fe(SO4)2.6H2O) in clarifying wastewater was examined. Results obtained from conventional standard ‘jar-test’ experiments indicated that alum was the most effective coagulant since it reduced turbidity of the wastewater to 0.64 NTU at a contact time of 300 min. Ferrous sulphate was the least effective coagulant, reducing turbidity of the wastewater to 3.45 NTU only at 240 min contact time, but when the contact time of the experiment was increased from 240 to 300 min, re-coloration of the solution was observed indicating re-stabilization of suspended particles. These findings tend to support the claim that alum is a choice coagulant for wastewater clarification.   


2016 ◽  
Vol 12 (8) ◽  
pp. 318-322
Author(s):  
Lugard Ukiwe ◽  
I.C. Iwu ◽  
Chijioke Okere M

An investigation into the ability of four inorganic coagulants namely; alum (Al2(SO4)3.18H2O), ammonium aluminum sulphate (NH4Al(SO4)2.12H2O), ferrous sulphate (FeSO4) and ammonium ferrous sulphate (NH4)2Fe(SO4)2.6H2O) in clarifying wastewater was examined. Results obtained from conventional standard ‘jar-test’ experiments indicated that alum was the most effective coagulant since it reduced turbidity of the wastewater to 0.64 NTU at a contact time of 300 min. Ferrous sulphate was the least effective coagulant, reducing turbidity of the wastewater to 3.45 NTU only at 240 min contact time, but when the contact time of the experiment was increased from 240 to 300 min, re-coloration of the solution was observed indicating re-stabilization of suspended particles. These findings tend to support the claim that alum is a choice coagulant for wastewater clarification.   


2021 ◽  
Author(s):  
Ayad Hmood

Wastewater containing Zn+₂and Ni+₂is normally treated by chemical precipitation, coagulation, flocculation followed by clarification.The metal precipitation is influenced by chemical (wastewater pH, coagulant type and dose) and physical (rapid mixing speed and time) parameters. The process usually consists of the rapid dispersal of a coagulant into the wastewater followed by an intense agitation commonly defined as rapid mixing. This study focused on the most important parameters of rapid mixing design: mixing intensity and duration. Simulated aqueous solutions containing 50 ppm Zn+₂and 50 ppm Ni+₂were treated with aluminum sulphate, ferrous sulphate and ferric chloride coagulants at different doses and different rapid mixing times and speeds. Experimental results obtained indicate that ferric chloride at 30 mg/l dose was superior over aluminum sulphate and ferrous sulphate at the same dose in Zn+₂and Ni+₂removals. Rapid mixing time had a strong influence on the metal removal. An optimal combination of rapid mixing parameters was determined as: 60 s at 100 rpm for Zn+₂and 30 s at 80 rpm for Ni+₂removals. Scanning electron microscopy images for Zn+₂and Ni+₂flocs at optimum parameters of rapid mixing show that ferric chloride addition compacts the surface texture of the metals flocs. Flocs formed by Zn+₂are denser and larger than flocs formed by Ni+₂.


WARTA AKAB ◽  
2021 ◽  
Vol 45 (2) ◽  
Author(s):  
Ahmad Zakaria ◽  
Sopian Sauri ◽  
Dian Mira Fadela ◽  
Puspita Sri Ayu Wardhani

Industri pangan menghasilkan air limbah berbahan organik dan padatan tersuspensi maupun terlarut yang tinggi. Salah satu proses pengolahan air limbah yaitu dengan proses koagulasi-flokulasi yang bertujuan untuk menghilangkan padatan tersuspensi dan zat organik yang dapat menyebabkan kekeruhan serta bau dengan penambahan koagulan. Penambahan koagulan pada instalasi pengolahan air limbah (IPAL) tidak dilakukan secara kuantitatif, sehingga perlu dilakukan percobaan dengan metode jar test. Tujuan percobaan untuk mengetahui pH dan dosis optimum serta efisiensi koagulan poly aluminium chloride (PAC) untuk menurunkan kadar chemical oxygen demand (COD), total suspended solid (TSS), dan total dissolved solid (TDS). Hasil uji parameter COD, TSS, dan TDS dibandingkan dengan Surat Keputusan Gubernur Tingkat 1 Jawa Barat (SK Gub TK 1 Jabar) No. 6 Tahun 1999 tentang Baku Mutu Limbah Cair Bagi Kegiatan Industri di Jawa Barat. Berdasarkan hasil percobaan diperoleh kondisi optimum koagulan PAC pada pH air limbah 6–7 dengan dosis koagulan optimum pada (80–90) mg/L. Hasil pengujian parameter TS, TDS, TSS, kekeruhan dan COD berturut-turut memberikan nilai efisiensi sebesar (52,6-57,8)%, (53,9-55,5)%, (52,4-58,1)%, (97,8-99,1)%, dan (71,6–77,1)%. Percobaan yang dilakukan membuktikan bahwa koagulan PAC mampu menurunkan kadar pada parameter uji dengan nilai efisiensi yang cukup besar.


2021 ◽  
Author(s):  
Ayad Hmood

Wastewater containing Zn+₂and Ni+₂is normally treated by chemical precipitation, coagulation, flocculation followed by clarification.The metal precipitation is influenced by chemical (wastewater pH, coagulant type and dose) and physical (rapid mixing speed and time) parameters. The process usually consists of the rapid dispersal of a coagulant into the wastewater followed by an intense agitation commonly defined as rapid mixing. This study focused on the most important parameters of rapid mixing design: mixing intensity and duration. Simulated aqueous solutions containing 50 ppm Zn+₂and 50 ppm Ni+₂were treated with aluminum sulphate, ferrous sulphate and ferric chloride coagulants at different doses and different rapid mixing times and speeds. Experimental results obtained indicate that ferric chloride at 30 mg/l dose was superior over aluminum sulphate and ferrous sulphate at the same dose in Zn+₂and Ni+₂removals. Rapid mixing time had a strong influence on the metal removal. An optimal combination of rapid mixing parameters was determined as: 60 s at 100 rpm for Zn+₂and 30 s at 80 rpm for Ni+₂removals. Scanning electron microscopy images for Zn+₂and Ni+₂flocs at optimum parameters of rapid mixing show that ferric chloride addition compacts the surface texture of the metals flocs. Flocs formed by Zn+₂are denser and larger than flocs formed by Ni+₂.


Author(s):  
Gilberto Jesús Colina Andrade ◽  
Sedolfo Carrasquero ◽  
Amelia Segovia ◽  
Gabriela Zambrano ◽  
Altamira Díaz

  Los efluentes industriales ocasionan graves impactos ambientales, su adecuado tratamiento y su posterior reutilización contribuye a un consumo sostenible del agua. En esta investigación se evaluó la efectividad de la bentonita (BT) como clarificante y se comparó con los coagulantes químicos tradicionales: sulfato de aluminio (SA) y cloruro férrico (CF) durante el tratamiento de los efluentes de un complejo industrial alimentario. Este estudio se llevó a cabo utilizando aguas residuales provenientes de industrias manufactureras de harina de trigo y pastas localizada en San Francisco, Venezuela. La caracterización del efluente se realizó mediante la medición de los parámetros: demanda bioquímica de oxígeno, demanda química de oxígeno, alcalinidad total, sólidos totales, sólidos suspendidos totales, sólidos sedimentables, color real, pH y turbidez. Los tratamientos se ejecutaron a través de corridas exploratorias con dosis que oscilaron entre 0 y 400 mg/L. El experimento se condujo con un diseño que toma muestras al azar y aplica tres tratamientos (SA, CF y BT), usando el equipo de la prueba de jarra, para reproducir las condiciones de una planta de tratamiento. Las dosis óptimas que permitieron obtener porcentajes de remoción de 98, 90 y 98% para el color y 92, 93 y 97% para la turbidez, fueron 260, 200 y 40 mg/L para el SA, CF y BT, respectivamente. Existieron diferencias significativas entre los tratamientos realizados, siendo la bentonita dosificada en húmedo la que arrojó las mayores remociones y generó un efluente que cumplió con la normativa venezolana vigente para descargas en cuerpos de agua.   Palabra clave: tratamiento fisicoquímico, aguas residuales industriales, bentonita, cloruro férrico, sulfato de aluminio.   Abstract Industrial effluents cause serious environmental impacts, proper treatment and subsequent reuse for multiple uses contributes to sustainable water consumption, which is why it is necessary to apply treatments to improve the conditions of the effluent. The effectiveness of bentonite (BT) as a clarifying agent was evaluated and compared with chemical coagulants: aluminum sulfate (AS) and ferric chloride (FC) by a physicochemical treatment of coagulation-flocculation in effluents of a food industrial complex. This study was carried out using wastewater from a manufacturing industrial complex of wheat flour and pastas. Wastewater characterization was performed by measuring the parameters: biochemical oxygen demand (BOD5,20), chemical oxygen demand (COD), total alkalinity, total solids (TS), total suspended solids (TSS), settleable solids (SS), true colour, pH and turbidity. The treatments were carried out by conducting exploratory runs with doses of coagulants ranging between 0 and 300 mg/L. The experiment was conducted by using a completely randomized design with a total of three treatments (SA, CF y BT) and the jar test equipment, which reproduces the treatment plant conditions. Optimal doses obtained for the clarifying agents were 260, 200, and 40 mg/L, for a removal of 98, 90, and 98% for colour and 92, 93, and 97% for turbidity, respectively. There were significant differences between the treatments performed, being the wet bentonite the one that produced the highest elimination percentages. The effluent quality obtained from the treatments fulfilled the Venezuelan standards for discharge in water bodies.   Keywords: physicochemical treatment, coagulation, industrial wastewater, effluent, bentonite, ferric chloride, aluminum sulfate.  


2013 ◽  
Vol 2013 ◽  
pp. 1-7 ◽  
Author(s):  
Habsah Alwi ◽  
Juferi Idris ◽  
Mohibah Musa ◽  
Ku Halim Ku Hamid

The effectiveness of banana stem juice as a natural coagulant for treatment of spent coolant wastewater was investigated . Three main parameters were studied, namely, chemical oxygen demand (COD), suspended solids (SSs), and turbidity of effluent. Coagulation experiments using jar test were performed with a flocculation system where the effects of spent coolant wastewater pH as well as banana stem juice dosage on coagulation effectiveness were examined. The highest recorded COD, SS, and turbidity removal percentages by banana stem juice were 80.1%, 88.6%, and 98.5%, respectively, observed for effluent at pH 7 using 90 mL dosage. The inulin concentration in the banana stem was examined to be 1.22016 mg/mL. It could be concluded that banana stem juice showed tremendous potential as a natural coagulant for water treatment purposes and could be applied in the pretreatment stage of Malaysian spent coolant wastewater prior to secondary treatment.


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