scholarly journals Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst

2021 ◽  
Vol 9 ◽  
Author(s):  
Shunli Shi ◽  
Ying Yu ◽  
Bingzhen Zhang ◽  
Yicheng Zhong ◽  
Lei Wang ◽  
...  
Keyword(s):  
Benzyl Alcohol ◽  
Heterogeneous Catalysts ◽  
Catalytic Performance ◽  
Catalytic Synthesis ◽  
Solvent Free ◽  
Turnover Frequency ◽  
One Pot ◽  
Free Condition ◽  
Solvent Free Condition ◽  
Air Atmosphere

The development of efficient heterogeneous catalysts for one-pot tandem/cascade synthesis of imines remains meaningful and challenging. Herein, we constructed an Au/MOF catalyst featured hollow and double MOF shell nanostructure. Owing to its structural merits and acid-basic nature, the as-synthesized Void|(Au)ZIF-8|ZIF-8 catalyst exhibited an enhanced synergistically catalytic performance for tandem catalytic synthesis of imines from benzyl alcohol and aniline under air atmosphere and solvent-free condition. Its 170.16 h−1 of turnover frequency (TOF) was 2.5 times higher than that of the reported catalyst with the highest TOF value.

Sulfated polyborate: a new and eco-friendly catalyst for one-pot multi-component synthesis of 3,4-dihydropyrimidin-2(1H)-ones/thiones via Biginelli reaction

2016 ◽  
Vol 40 (12) ◽  
pp. 10412-10417 ◽  
Author(s):  
Chetan K. Khatri ◽  
Deelip S. Rekunge ◽  
Ganesh U. Chaturbhuj
Keyword(s):  
Biginelli Reaction ◽  
Solvent Free ◽  
Synthetic Methodology ◽  
One Pot ◽  
Free Condition ◽  
Sulfated Polyborate ◽  
Highly Efficient ◽  
Excellent Yield ◽  
Solvent Free Condition

A highly efficient and improved synthetic methodology for the preparation of 3,4-dihydropyrimidin-2(1H)-one derivatives in good to excellent yield via Biginelli reaction of β-ketoesters/β-diketone, urea/thiourea and various aldehydes using new, efficient and recyclable sulfated polyborate catalyst under the solvent-free condition is reported.

One-pot three-component synthesis of bis(indolyl)methanes under solvent-free condition using heteropoly-11-tungsto-1-vanadophosphoric acid supported on natural clay as catalyst

2017 ◽  
Vol 47 (9) ◽  
pp. 913-927 ◽  
Author(s):  
Karuppaiah Selvakumar ◽  
Thangamariyappan Shanmugaprabha ◽  
Ramamoorthy Annapoorani ◽  
Ponnusamy Sami
Keyword(s):  
Solvent Free ◽  
Natural Clay ◽  
One Pot ◽  
Free Condition ◽  
Solvent Free Condition

scholarly journals A Facile One-Pot Solvent-Free Synthesis of 1,2-Dihydro-1-arylnaphtho[1,2-e][1,3]oxazine-3-ones Catalyzed by Wet Cyanuric Chloride

2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
Firouzeh Nemati ◽  
Azam Beyzai
Keyword(s):  
Organic Solvent ◽  
Simple Procedure ◽  
Reaction Times ◽  
Solvent Free ◽  
Cyanuric Chloride ◽  
One Pot ◽  
Free Condition ◽  
Solvent Free Condition ◽  
High Yields ◽  
Solvent Free Synthesis

A novel one-pot synthesis of 1,2-dihydro-1-arylnaphtho[1,2-e][1,3]oxazine-3-ones by condensation of a variety of aldehydes withβ-naphthol and urea or thiourea in the presence of wet cyanuric chloride under solvent-free condition has been described. High yields, simple procedure, easy workup, short reaction times, and avoiding the use of organic solvent are the advantages of this green methodology.

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