scholarly journals Is Sugarcane a Convenient Feedstock to Provide Ethanol to Oxygenate Gasolines in Mexico? A Process Simulation and Techno-Economic-Based Analysis

2021 ◽  
Vol 8 ◽  
Author(s):  
Jorge Aburto ◽  
Elías Martínez-Hernández
Keyword(s):  
Production Capacity ◽  
Economic Assessment ◽  
Methyl Tert Butyl Ether ◽  
Selling Price ◽  
Sugar Production ◽  
Butyl Ether ◽  
Southern Mexico ◽  
Market Prices ◽  
Gasoline Demand ◽  
Minimum Ethanol Selling Price

Sugarcane is a major crop produced in many tropical countries including Mexico and has been the basis of a well-established agroindustry. However, the variation in market prices and health concerns over the consumption of sugar are challenging the economics and sustainability of sugarcane growers and mills. This paper presents a techno-economic assessment of using existing production capacity of sugarcane in Mexico and the correspondent Mexican sugarcane mills for producing ethanol as gasoline oxygenate, in comparison to the export of excess sugar production. Using the most recent statistics, we found out that the bioethanol potential is of 849,260,499 L/year which can cover for 100% of the premium and magna gasoline demand in metropolitan area (MA) and 48% of premium gasoline in rest of the country areas (RoCAs) at 5.8% w/v blending (2.7% O2 w/v). This can be done by diverting the 20% sugar production excess to ethanol with the benefit of a higher gross netback of 308.3 USD/ton of sugarcane in comparison to 222.5 USD/ton of sugarcane when it is exported. Furthermore, a minimum ethanol-selling price (MESP) of 0.5211 USD/L was estimated, showing that ethanol might be competitive against methyl tert-butyl ether (0.50 USD/L FOB Gulf price) as gasoline oxygenate agent. Decarbonizing gasoline in Mexico through the use of ethanol might allow the abatement of 5,766.8 kg CO2/day when 20% sugar is used. Concerning the underconstruction Dos Bocas refinery in Tabasco State, southern Mexico, ethanol blend at 5.8% in gasolines might but also contribute to the abatement of 6.1% of CO2 emissions and the required sugarcane was estimated at 1 million tons per year. All these indicate that sugarcane has a great potential as a feedstock to produce first-generation ethanol as a gasoline oxygenate agent in Mexico.

scholarly journals Net Energy Analysis and Techno-Economic Assessment of Co-Production of Bioethanol and Biogas from Cellulosic Biomass

Fermentation ◽  
2021 ◽  
Vol 7 (4) ◽  
pp. 229
Author(s):  
Teeraya Jarunglumlert ◽  
Chattip Prommuak
Keyword(s):  
Cellulosic Ethanol ◽  
Energy Analysis ◽  
Market Price ◽  
Economic Assessment ◽  
Cellulosic Biomass ◽  
Energy Output ◽  
Selling Price ◽  
Net Energy ◽  
Minimum Ethanol Selling Price ◽  
Economic Studies

Co-production is a process based on the biorefinery concept that maximizes the benefit of biomass by reusing residue from the production of one product to produce others. In this regard, biogas is one of the most researched second products for the production of ethanol from cellulosic biomass. However, operating this scheme requires additional investment in biogas processing equipment. This review compiles data from research studies on the co-production of bioethanol and biogas from lignocellulosic biomass to determine which is more worthwhile: leaving the residue or investing more to benefit from the second product. According to previous research, ethanol stillage can be converted to biogas via anaerobic digestion, increasing energy output by 2–3 fold. Techno-economic studies demonstrated that the co-production process reduces the minimum ethanol selling price to a level close to the market price of ethanol, implying the possibility of industrializing cellulosic ethanol production through this scheme.

scholarly journals From sugars to FDCA: a techno-economic assessment using a design concept based on solvent selection and carbon dioxide emissions

2021 ◽  
Author(s):  
Amir Al Ghatta ◽  
James D. E. T. Wilton-Ely ◽  
Jason P. Hallett
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Emissions ◽  
Process Development ◽  
Economic Assessment ◽  
Design Concept ◽  
Selling Price ◽  
Solvent Selection ◽  
Current Process ◽  
Process Simulations ◽  
Solvent Systems

Process simulations allow the evaluation of the emissions and selling price for the production of the key monomer FDCA based on different feedstocks and solvent systems, alongside considerations of safety and current process development.

scholarly journals Biodegradation of Methyl tert-Butyl Ether and Other Fuel Oxygenates by a New Strain, Mycobacterium austroafricanum IFP 2012

2002 ◽  
Vol 68 (6) ◽  
pp. 2754-2762 ◽  
Author(s):  
Alan François ◽  
Hugues Mathis ◽  
Davy Godefroy ◽  
Pascal Piveteau ◽  
Françoise Fayolle ◽  
...  
Keyword(s):  
Polyacrylamide Gel Electrophoresis ◽  
Sodium Dodecyl ◽  
Dry Weight ◽  
Butyl Alcohol ◽  
Amyl Alcohol ◽  
Methyl Tert Butyl Ether ◽  
Methylotrophic Bacterium ◽  
Specific Rate ◽  
Butyl Ether ◽  
Mycobacterium Austroafricanum

ABSTRACT A strain that efficiently degraded methyl tert-butyl ether (MTBE) was obtained by initial selection on the recalcitrant compound tert-butyl alcohol (TBA). This strain, a gram-positive methylotrophic bacterium identified as Mycobacterium austroafricanum IFP 2012, was also able to degrade tert-amyl methyl ether and tert-amyl alcohol. Ethyl tert-butyl ether was weakly degraded. tert-Butyl formate and 2-hydroxy isobutyrate (HIBA), two intermediates in the MTBE catabolism pathway, were detected during growth on MTBE. A positive effect of Co2+ during growth of M. austroafricanum IFP 2012 on HIBA was demonstrated. The specific rate of MTBE degradation was 0.6 mmol/h/g (dry weight) of cells, and the biomass yield on MTBE was 0.44 g (dry weight) per g of MTBE. MTBE, TBA, and HIBA degradation activities were induced by MTBE and TBA, and TBA was a good inducer. Involvement of at least one monooxygenase during degradation of MTBE and TBA was shown by (i) the requirement for oxygen, (ii) the production of propylene epoxide from propylene by MTBE- or TBA- grown cells, and (iii) the inhibition of MTBE or TBA degradation and of propylene epoxide production by acetylene. No cytochrome P-450 was detected in MTBE- or TBA-grown cells. Similar protein profiles were obtained after sodium dodecyl sulfate-polyacrylamide gel electrophoresis of crude extracts from MTBE- and TBA-grown cells. Among the polypeptides induced by these substrates, two polypeptides (66 and 27 kDa) exhibited strong similarities with known oxidoreductases.

Phthalate degradation by glow discharge plasma enhanced with pyrite in aqueous solution

2016 ◽  
Vol 74 (6) ◽  
pp. 1365-1375 ◽  
Author(s):  
Chensi Shen ◽  
Shaoshuai Wu ◽  
Hui Chen ◽  
Sadia Rashid ◽  
Yuezhong Wen
Keyword(s):  
Aqueous Solution ◽  
Energy Efficiency ◽  
Glow Discharge ◽  
Discharge Plasma ◽  
Ph Value ◽  
Glow Discharge Plasma ◽  
Methyl Tert Butyl Ether ◽  
Butyl Ether ◽  
Polymeric Compound ◽  
X Ray

In order to prevent health risk from potential exposures to phthalates, a glow discharge plasma (GDP) process was applied for phthalate degradation in aqueous solution. The results revealed that the phthalate derivatives 4-hydroxyphthalic acid, 4-methylphthalic acid and 4-tert-butylphthalic anhydride could be degraded efficiently in GDP process (498 V, 0.2 A) with high removal efficiencies of over 99% in 60 minutes. Additionally, pyrite as a promising heterogeneous iron source in the Fenton reaction was found to be favorable for GDP process. The phthalate degradation reaction could be significantly enhanced by the continuous formation of •OH and the inhibition of the quenching reaction in the pyrite Fenton system due to the constant dissolution of Fe(II) from pyrite surface. Meanwhile, the initial pH value showed little impact on the degradation of phthalates and the energy efficiency of GDP system for phthalate degradation ranged between 0.280 × 10−9 and 1.210 × 10−9 mol/J, which is similar to the GDP system with phenol, bisphenol A and methyl tert-butyl ether as the substrates. Further, the X-ray diffraction and scanning electron microscopy with energy dispersive X-ray spectroscopy analyses indicated that the pyrite was relatively stable in GDP system and there was no obvious polymeric compound formed on the catalyst surface. Overall, this GDP process offers high removal efficiency, simple technology, considerable energy efficiency and the applicability to salt-containing phthalate wastewater.

Direct dissolution of gallstones with methyl tert-butyl ether (MTBE) via endoscopic transpapillary catheterization in the gallbladder (ETCG)

1994 ◽  
Vol 29 (4) ◽  
pp. 486-494 ◽  
Author(s):  
Naohito Uchida ◽  
Toshiaki Nakatsu ◽  
Shuko Hirabayashi ◽  
Atsushi Minami ◽  
Hiroki Fukuma ◽  
...  
Keyword(s):  
Methyl Tert Butyl Ether ◽  
Butyl Ether ◽  
Tert Butyl ◽  
Direct Dissolution ◽  
Dissolution Of Gallstones
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