scholarly journals Heavy Metal, Rare Earth Element and Pb Isotope Dynamics in Mussels During a Depuration Experiment in the Gulf of Aqaba, Northern Red Sea

2021 ◽  
Vol 8 ◽  
Author(s):  
Tal Benaltabet ◽  
Eldad Gutner-Hoch ◽  
Adi Torfstein

Mussels are considered highly efficient marine biomonitors, tracing anthropogenic and natural variations in heavy metals and various organic compounds. While heavy metals depuration processes in biomonitors are of growing interest, less knowledge is available regarding their Pb isotopes and rare earth elements (REEs) accumulation-release dynamics, and their response to short-term anthropogenic and terrigenous perturbations. Here, we report the results of a relocation experiment where a group of mussels (Brachidontes pharaonis) were extracted from a contaminated lagoon in the Gulf of Aqaba, northern Red Sea, and placed in water tanks that were flushed continuously with fresh, uncontaminated seawater. Specimens were removed periodically from the water table over a period of 13 weeks and trace and REEs and Pb isotopic compositions were determined separately for mussel’s shells and soft tissues. The results display a clear decrease over time in the concentrations of various heavy metals and REEs in the soft tissue, in concert with a similar shift in the Pb isotopic compositions toward seawater values. By contrast, the elemental and Pb isotopic composition of the shell presents little change over time. Coupling between the Pb isotopic composition of corresponding soft tissue and shell samples allows back-calculation of the timing and magnitude of abrupt pollution events and presents a novel approach for monitoring short-term pollution events. Nevertheless, given the coastal setting of the studied samples, it is important to consider the effects of terrigenous material on the results. Accordingly, Al-normalized element concentrations, Pb isotopes and calculated Ce anomalies, are used to identify two distinct terrigenous end members controlling the contaminated lagoon and the pristine site. The study demonstrates the potential of using mussels as robust biomonitors of natural and anthropogenic environmental perturbations through the combination between elemental concentrations and the isotopic composition of Pb.

Author(s):  
Halil Kaya ◽  
Gaurango Banerjee

The paper examines the Sarbanes-Oxley (2002) Acts immediate impact on board composition and characteristics as well as possible reversals in its impact over time. Effects on directors age and tenure are analyzed over the 2001-06 sample period. Female participation in corporate boards is also studied in the pre-SOX and post-SOX periods. The dual roles of directors in being a member of the board as well as serving as either CEO, CFO, Chairman, Co-Chair, Founder, or Lead Director of their respective companies is also examined. We observe a short-term impact of SOX on board compositions due to changes seen in board characteristics between 2001 (pre-SOX), and 2003-05 short-term period (post-SOX). Also, we observe a reversal of board characteristics in 2006 to pre-SOX levels implying that the effects of SOX on board composition were short-lived, and needs to be monitored over time to ensure adherence to corporate accountability guidelines over the long-term.


2021 ◽  
pp. 089020702110173
Author(s):  
Nadin Beckmann ◽  
Damian P Birney ◽  
Amirali Minbashian ◽  
Jens F Beckmann

The study aimed to investigate the status of within-person state variability in neuroticism and conscientiousness as individual differences constructs by exploring their (a) temporal stability, (b) cross-context consistency, (c) empirical links to selected antecedents, and (d) empirical links to longer term trait variability. Employing a sample of professionals ( N = 346) from Australian organisations, personality state data together with situation appraisals were collected using experience sampling methodology in field and repeatedly in lab-like settings. Data on personality traits, cognitive ability, and motivational mindsets were collected at baseline and after two years. Contingent (situation contingencies) and non-contingent (relative SD) state variability indices were relatively stable over time and across contexts. Only a small number of predictive effects of state variability were observed, and these differed across contexts. Cognitive ability appeared to be associated with state variability under lab-like conditions. There was limited evidence of links between short-term state and long-term trait variability, except for a small effect for neuroticism. Some evidence of positive manifold was found for non-contingent variability. Systematic efforts are required to further elucidate the complex pattern of results regarding the antecedents, correlates and outcomes of individual differences in state variability.


Author(s):  
Allen D. Uhler ◽  
Jeffery H. Hardenstine ◽  
Deborah A. Edwards ◽  
Guilherme R. Lotufo

AbstractPolychlorinated biphenyls (PCBs) were added to certain marine vessel bottom paints as a plasticizer to improve the adhesion and durability of the paint. The most common PCB formulation used to amend such paints was Aroclor 1254. Fugitive Aroclor-containing paint chips generated from vessel maintenance and repair operations represent a potential source of PCB contamination to sediments. Limited published studies indicate that Aroclor-containing paint is largely inert and exhibits low PCB leaching into water; however, the rate and degree of leaching of PCBs from paint chips have not been directly studied. This laboratory-based study evaluated the rate and extent of leaching of PCBs from paint chips into freshwater. The results of this investigation demonstrate that the rate of PCB dissolution from paint chips decreased rapidly and exponentially over time. Based on this study, it is estimated that the rate of leaching of PCBs from paint chips would cease after approximately 3 years of exposure to water. When all leachable PCBs were exhausted, it is estimated that less than 1% of the mass of PCBs in the paint chips was amenable to dissolution. The results of this experiment suggest that Aroclor-containing paint chips found in sediments are likely short-term sources of dissolved-phase PCB to pore or surface waters and that the majority of the PCBs in paint chips remain in the paint matrix and unavailable for partitioning into water. Graphic Abstract


2012 ◽  
Vol 7 (2) ◽  
pp. 236-257 ◽  
Author(s):  
Jaap Spreeuw ◽  
Iqbal Owadally

AbstractWe analyze the mortality of couples by fitting a multiple state model to a large insurance data set. We find evidence that mortality rates increase after the death of a partner and, in addition, that this phenomenon diminishes over time. This is popularly known as a “broken-heart” effect and we find that it affects widowers more than widows. Remaining lifetimes of joint lives therefore exhibit short-term dependence. We carry out numerical work involving the pricing and valuation of typical contingent assurance contracts and of a joint life and survivor annuity. If insurers ignore dependence, or mis-specify it as long-term dependence, then significant mis-pricing and inappropriate provisioning can result. Detailed numerical results are presented.


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