scholarly journals Applicability of Near Infrared Reflectance Spectroscopy to Predict Amylose Contents of Single-Grain Maize

Agronomy ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 2463
Author(s):  
Qing Dong ◽  
Qianqian Xu ◽  
Jiandong Wu ◽  
Beijiu Cheng ◽  
Haiyang Jiang
Keyword(s):  
Root Mean Square Error ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Near Infrared ◽  
Reflectance Spectroscopy ◽  
Coefficient Of Determination ◽  
Mean Square ◽  
Near Infrared Reflectance ◽  
Single Grain ◽  
Single Seeds

Near infrared reflectance spectroscopy (NIRS) and reference data were used to determine the amylose contents of single maize seeds to enable rapid, effective selection of individual seeds with desired traits. To predict the amylose contents of a single seed, a total of 1069 (865 as calibration set, 204 as validation set) single seeds representing 120 maize varieties were analyzed using chemical methods and performed calibration and external validation of the 150 single seeds set in parallel. Compared to various spectral pretreatments, the regression of partial least squares (PLS) with mathematical treatment of Harmonization showed the final optimization. The single-seed amylose contents showed the root mean square error of calibration (RMSEC) of 2.899, coefficient of determination for calibration (R2) of 0.902, and root mean square error of validation (RMSEV) of 2.948. In external validations, the coefficient of determination in cross-validation (r2), root mean square error of the prediction (RMSEP) and ratio of the standard deviation to SEP (RPD) were 0.892, 2.975 and 3.086 in the range of 20–30%, respectively. Therefore, NIRS will be helpful to breeders for determining the amylose contents of single-grain maize.

Quantitative Analysis of Forsythiae fructus by Near Infrared Spectroscopy

2013 ◽  
Vol 807-809 ◽  
pp. 1967-1971
Author(s):  
Yan Bai ◽  
Xiao Yan Duan ◽  
Hai Yan Gong ◽  
Cai Xia Xie ◽  
Zhi Hong Chen ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Root Mean Square Error ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Cross Validation ◽  
Ethanol Extract ◽  
Mean Square ◽  
Validation Set

In this paper, the content of forsythoside A and ethanol-extract were rapidly determinated by near-infrared reflectance spectroscopy (NIRS). 85 samples of Forsythiae Fructus harvested in Luoyang from July to September in 2012 were divided into a calibration set (75 samples) and a validation set (10 samples). In combination with the partical least square (PLS), the quantitative calibration models of forsythoside A and ethanol-extract were established. The correlation coefficient of cross-validation (R2) was 0.98247 and 0.97214 for forsythoside A and ethanol-extract, the root-mean-square error of calibration (RMSEC) was 0.184 and 0.570, the root-mean-square error of cross-validation (RMSECV) was 0.81736 and 0.36656. The validation set were used to evaluate the performance of the models, the root-mean-square error of prediction (RMSEP) was 0.221 and 0.518. The results indicated that it was feasible to determine the content of forsythoside A and ethanol-extract in Forsythiae Fructus by near-infrared spectroscopy.

scholarly journals Authentication of Patin Fish Oil (Pangasius micronemus) using FTIR Spectroscopy Combined with Chemometrics

2020 ◽  
pp. 23
Author(s):  
Anggita Rosiana Putri ◽  
Abdul Rohman ◽  
Sugeng Riyanto ◽  
Widiastuti Setyaningsih
Keyword(s):  
Root Mean Square Error ◽  
Fish Oil ◽  
Ftir Spectroscopy ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Partial Least Square ◽  
Least Square ◽  
Partial Least Square Regression ◽  
Coefficient Of Determination ◽  
Mean Square

Authentication of Patin fish oil (MIP) is essential to prevent adulteration practice, to ensure quality, nutritional value, and product safety. The purpose of this study is to apply the FTIR spectroscopy combined with chemometrics for MIP authentication. The chemometrics method consists of principal component regression (PCR) and partial least square regression (PLSR). PCR and PLSR were used for multivariate calibration, while for grouping the samples using discriminant analysis (DA) method. In this study, corn oil (MJ) was used as an adulterate. Twenty-one mixed samples of MIP and MJ were prepared with the adulterate concentration range of 0-50%. The best authentication model was obtained using the PLSR technique using the first derivative of FTIR spectra at a wavelength of 650-3432 cm-1. The coefficient of determination (R2) for calibration and validation was obtained 0.9995 and 1.0000, respectively. The value of root mean square error of calibration (RMSEC) and root mean square error of prediction (RMSEP) were 0.397 and 0.189. This study found that the DA method can group the samples with an accuracy of 99.92%.

Estimating Center of Mass Kinematics During Perturbed Human Standing Using Accelerometers

2021 ◽  
pp. 1-10
Author(s):  
Sandra K. Hnat ◽  
Musa L. Audu ◽  
Ronald J. Triolo ◽  
Roger D. Quinn
Keyword(s):  
Root Mean Square Error ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Mean Squared Error ◽  
Balance Control ◽  
Center Of Mass ◽  
Coefficient Of Determination ◽  
Mean Square ◽  
Cord Injury ◽  
Movement Type

Estimating center of mass (COM) through sensor measurements is done to maintain walking and standing stability with exoskeletons. The authors present a method for estimating COM kinematics through an artificial neural network, which was trained by minimizing the mean squared error between COM displacements measured by a gold-standard motion capture system and recorded acceleration signals from body-mounted accelerometers. A total of 5 able-bodied participants were destabilized during standing through: (1) unexpected perturbations caused by 4 linear actuators pulling on the waist and (2) volitionally moving weighted jars on a shelf. Each movement type was averaged across all participants. The algorithm’s performance was quantified by the root mean square error and coefficient of determination (R2) calculated from both the entire trial and during each perturbation type. Throughout the trials and movement types, the average coefficient of determination was 0.83, with 89% of the movements with R2 > .70, while the average root mean square error ranged between 7.3% and 22.0%, corresponding to 0.5- and 0.94-cm error in both the coronal and sagittal planes. COM can be estimated in real time for balance control of exoskeletons for individuals with a spinal cord injury, and the procedure can be generalized for other gait studies.

scholarly journals Estimating Maximum Daily Precipitation in the Upper Vistula Basin, Poland

Atmosphere ◽  
2019 ◽  
Vol 10 (2) ◽  
pp. 43 ◽  
Author(s):  
Dariusz Młyński ◽  
Andrzej Wałęga ◽  
Andrea Petroselli ◽  
Flavia Tauro ◽  
Marta Cebulska
Keyword(s):  
Root Mean Square Error ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Goodness Of Fit ◽  
Daily Precipitation ◽  
Probability Distributions ◽  
Random Variables ◽  
Coefficient Of Determination ◽  
Mean Square ◽  
Probability Of Exceedance

The aim of this study was to determine the best probability distributions for calculating the maximum annual daily precipitation with the specific probability of exceedance (Pmaxp%). The novelty of this study lies in using the peak-weighted root mean square error (PWRMSE), the root mean square error (RMSE), and the coefficient of determination (R2) for assessing the fit of empirical and theoretical distributions. The input data included maximum daily precipitation records collected in the years 1971–2014 at 51 rainfall stations from the Upper Vistula Basin, Southern Poland. The value of Pmaxp% was determined based on the following probability distributions of random variables: Pearson’s type III (PIII), Weibull’s (W), log-normal, generalized extreme value (GEV), and Gumbel’s (G). Our outcomes showed a lack of significant trends in the observation series of the investigated random variables for a majority of the rainfall stations in the Upper Vistula Basin. We found that the peak-weighted root mean square error (PWRMSE) method, a commonly used metric for quality assessment of rainfall-runoff models, is useful for identifying the statistical distributions of the best fit. In fact, our findings demonstrated the consistency of this approach with the RMSE goodness-of-fit metrics. We also identified the GEV distribution as recommended for calculating the maximum daily precipitation with the specific probability of exceedance in the catchments of the Upper Vistula Basin.

scholarly journals Using Multi-Temporal MODIS NDVI Data to Monitor Tea Status and Forecast Yield: A Case Study at Tanuyen, Laichau, Vietnam

2020 ◽  
Vol 12 (11) ◽  
pp. 1814
Author(s):  
Phamchimai Phan ◽  
Nengcheng Chen ◽  
Lei Xu ◽  
Zeqiang Chen
Keyword(s):  
Remote Sensing ◽  
Root Mean Square Error ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Vegetation Index ◽  
Coefficient Of Determination ◽  
Percentage Error ◽  
Support Vector ◽  
Mean Square ◽  
Multi Temporal

Tea is a cash crop that improves the quality of life for people in the Tanuyen District of Laichau Province, Vietnam. Tea yield, however, has stagnated in recent years, due to changes in temperature, precipitation, the age of the tea bushes, and diseases. Developing an approach for monitoring tea bushes by remote sensing and Geographic Information Systems (GIS) might be a way to alleviate this problem. Using multi-temporal remote sensing data, the paper details an investigation of the changes in tea health and yield forecasting through the normalized difference vegetation index (NDVI). In this study, we used NDVI as a support tool to demonstrate the temporal and spatial changes in NDVI through the extract tea NDVI value and calculate the mean NDVI value. The results of the study showed that the minimum NDVI value was 0.42 during January 2013 and February 2015 and 2016. The maximum NDVI value was in August 2015 and June 2017. We indicate that the linear relationship between NDVI value and mean temperature was strong with R 2 = 0.79 Our results confirm that the combination of meteorological data and NDVI data can achieve a high performance of yield prediction. Three models to predict tea yield were conducted: support vector machine (SVM), random forest (RF), and the traditional linear regression model (TLRM). For period 2009 to 2018, the prediction tea yield by the RF model was the best with a R 2 = 0.73 , by SVM it was 0.66, and 0.57 with the TLRM. Three evaluation indicators were used to consider accuracy: the coefficient of determination ( R 2 ), root-mean-square error (RMSE), and percentage error of tea yield (PETY). The highest accuracy for the three models was in 2015 with a R 2 ≥ 0.87, RMSE < 50 kg/ha, and PETY less 3% error. In the other years, the prediction accuracy was higher in the SVM and RF models. Meanwhile, the RF algorithm was better than PETY (≤10%) and the root mean square error for this algorithm was significantly less (≤80 kg/ha). RMSE and PETY showed relatively good values in the TLRM model with a RMSE from 80 to 100 kg/ha and a PETY from 8 to 15%.

Determination of Magnesium Oxide Content in Mineral Medicine Talcum Using Near-Infrared Spectroscopy Integrated with Support Vector Machine

2017 ◽  
Vol 71 (11) ◽  
pp. 2427-2436 ◽  
Author(s):  
Mi Lei ◽  
Long Chen ◽  
Bisheng Huang ◽  
Keli Chen
Keyword(s):  
Root Mean Square Error ◽  
Least Squares ◽  
Partial Least Squares ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Near Infrared ◽  
Nir Spectroscopy ◽  
Support Vector ◽  
Mean Square ◽  
Characteristic Spectrum

In this research paper, a fast, quantitative, analytical model for magnesium oxide (MgO) content in medicinal mineral talcum was explored based on near-infrared (NIR) spectroscopy. MgO content in each sample was determined by ethylenediaminetetraacetic acid (EDTA) titration and taken as reference value of NIR spectroscopy, and then a variety of processing methods of spectra data were compared to establish a good NIR spectroscopy model. To start, 50 batches of talcum samples were categorized into training set and test set using the Kennard–Stone (K-S) algorithm. In a partial least squares regression (PLSR) model, both leave-one-out cross-validation (LOOCV) and training set validation (TSV) were used to screen spectrum preprocessing methods from multiplicative scatter correction (MSC), and finally the standard normal variate transformation (SNV) was chosen as the optimal pretreatment method. The modeling spectrum bands and ranks were optimized using PLSR method, and the characteristic spectrum ranges were determined as 11995–10664, 7991–6661, and 4326–3999 cm−1, with four optimal ranks. In the support vector machine (SVM) model, the radical basis function (RBF) kernel function was used. Moreover, the full spectrum data of samples pretreated with SNV, the characteristic spectrum data screened using synergy interval partial least squares (SiPLS), and the scoring data of the first four ranks obtained by a partial least squares (PLS) dimension reduction of characteristic spectrum were taken as input variables of SVM, and the MgO content reference values of various sample were taken as output values. In addition, the SVM model internal parameters were optimized using the grid optimization method (GRID), particle swarm optimization (PSO), and genetic algorithm (GA) so that the optimal C and g-values were determined and the validation model was established. By comprehensively comparing the validation effects of different models, it can be concluded that the scoring data of the first four ranks obtained by PLS dimension reduction of characteristic spectrum were taken as input variables of SVM, and the PLS-SVM regression model established using GRID was the optimal NIR spectroscopy quantitative model of talc. This PLS-SVM regression model (rank = 4) measured that the MgO content of talcum was in the range of 17.42–33.22%, with root mean square error of cross validation (RMSECV) of 2.2127%, root mean square error of calibration (RMSEC) of 0.6057%, and root mean square error of prediction (RMSEP) of 1.2901%. This model showed high accuracy and strong prediction capacity, which can be used for rapid prediction of MgO content in talcum.

Determination of Loganin in Qiju Dihuang Pills by Near-Infrared Spectroscopy Technique

2013 ◽  
Vol 807-809 ◽  
pp. 1978-1983 ◽  
Author(s):  
Cai Xia Xie ◽  
Hai Yan Gong ◽  
Jian Ying Liu ◽  
Jing Wei Lei ◽  
Xiao Yan Duan ◽  
...  
Keyword(s):  
Root Mean Square Error ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Diffuse Reflectance ◽  
Near Infrared ◽  
Diffuse Reflectance Spectroscopy ◽  
Partial Least Square ◽  
Calibration Model ◽  
Mean Square

To establish a rapid analytical method for Loganin in Qiju Dihuang Pills (condensed) by Near-infrared Diffuse Reflectance Technique. Collecting NIR spectra by NIR Diffuse Reflectance Spectroscopy, the partial least square calibration model was built. The correlation coefficients (R2) and the root-mean-square error of cross-validation (RMSECV) were 0.99764 and 0.09340, respectively. In the external validation,coefficients of determination (r2) between NIRS and HPLC values was 0.97348,the root-mean-square error of prediction (RMSEP) was 0.08491. The results showed that the method was rapid, accurate, and could be applied to the fast determination of Loganin in Qiju Dihuang Pills (condensed).

Rapid Determination of Docosahexaenoic Acid in Powdered Oil by Near-Infrared Spectroscopy

2010 ◽  
Vol 16 (2) ◽  
pp. 187-193 ◽  
Author(s):  
Yang Meiyan ◽  
Li Jing ◽  
Nie Shaoping ◽  
Hu Jielun ◽  
Yu Qiang ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Docosahexaenoic Acid ◽  
Root Mean Square Error ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Cross Validation ◽  
Mean Square ◽  
Validation Set

Near-infrared spectroscopy (NIRS) was used as a rapid and nondestructive method to determine the content of docosahexaenoic acid (DHA) in powdered oil samples. A total of 82 samples were scanned in the diffuse reflectance mode by Nicolet 5700 FTIR spectrometer and the reference values for DHA was measured by gas chromatography. Calibration equations were developed using partial least-squares regression (PLS) with internal cross-validation. Samples were split in two sets, one set used as calibration (n = 66) whereas the remaining samples (n=16) were used as validation set. Two mathematical treatments (first and second derivative), none (log(1/R)) and standard normal variate as scatter corrections and Savitzky—Golay smoothing were explored. To decide upon the number of PLS factors included in the PLS model, the model with the lowest root mean square error of cross-validation (RMSECV=0.44) for the validation set is chosen. The correlation coefficient (r) between the predicted and the reference results which used as an evaluation parameter for the models is 0.968. The root mean square error of prediction of the final model is 0.59. The results reported in this article demonstrate that FT-NIR measurements can serve as a rapid method to determine DHA in powdered oil.

scholarly journals Detection of deltamethrin in cabbages using visible shortwave near-infrared spectroscopy

Food Research ◽  
2021 ◽  
Vol 5 (3) ◽  
pp. 273-280
Author(s):  
C.D.M. Ishkandar ◽  
N.M. Nawi ◽  
R. Janius ◽  
N. Mazlan ◽  
T.T. Lin
Keyword(s):  
Infrared Spectroscopy ◽  
Root Mean Square Error ◽  
Spectral Data ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Near Infrared Spectroscopy ◽  
Near Infrared ◽  
Partial Least Square ◽  
Calibration Model ◽  
Mean Square

Pesticides have long been used in the cabbage industry to control pest infestation. This study investigated the potential application of low-cost and portable visible shortwave near-infrared spectroscopy for the detection of deltamethrin residue in cabbages. A total of sixty organic cabbage samples were used. The sample was divided into four batches, three batches were sprayed with deltamethrin pesticide whereas the remaining batch was not sprayed (control sample). The first three batches of the cabbages were sprayed with the pesticide at three different concentrations, namely low, medium and high with the values of 0.08, 0.11 and 0.14% volume/volume (v/v), respectively. Spectral data of the cabbage samples were collected using visible shortwave near-infrared (VSNIR) spectrometer with wavelengths range between 200 and 1100 nm. Gas chromatography-electron capture detector (GC-ECD) was used to determine the concentration of deltamethrin residues in the cabbages. Partial least square (PLS) regression method was adopted to investigate the relationship between the spectral data and deltamethrin concentration values. The calibration model produced the values of coefficient of determination (R2 ) and the root mean square error of calibration (RMSEC) of 0.98 and 0.02, respectively. For the prediction model, the values of R2 and the root mean square error of prediction (RMSEP) were 0.94 and 0.04, respectively. These results demonstrated that the proposed spectroscopic measurement is a promising technique for the detection of pesticide at different concentrations in cabbage samples.

DRYING KINETICS AND MOISTURE DIFFUSIVITY OF FOUR VARIETIES OF BAMBARA BEANS

2021 ◽  
Vol 6 (1) ◽  
pp. 30-33
Author(s):  
E.O. Awotona ◽  
A.O. Alade ◽  
S.A. Adebanjo ◽  
O. Duduyemi ◽  
T.J. Afolabi
Keyword(s):  
Root Mean Square Error ◽  
Mean Square Error ◽  
Root Mean Square ◽  
Goodness Of Fit ◽  
Moisture Diffusivity ◽  
Coefficient Of Determination ◽  
Mean Square ◽  
Fit Statistics ◽  
Drying Behavior ◽  
Maximum Coefficient

Drying of bambara beans was studied at 40oC at every 30 minutes in a Laboratory oven. Effective moisture diffusivity ranges between 5.886 x 10-10 m2/s – 4.354 x 10-10 m2/s respectively. The statistical criteria used in evaluation of the model were maximum coefficient of determination R2 and minimum root mean square error [RMSE]. Determination for goodness of fit statistics for drying of the beans was carried out. Midilli model was used to predict the drying curve. The Midili model was found to produce accurate predictions for all the four varieties of bambara beans and the model was shown to be an excellent model for predicting drying behavior of TVSU-47 and the R2 value was 0.9971 and the value of root mean square error was 0.0149 respectively.

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