scholarly journals Lithium-Ion Battery Modeling Including Degradation Based on Single-Particle Approximations

Batteries ◽  
2020 ◽  
Vol 6 (3) ◽  
pp. 37 ◽  
Author(s):  
Mostafa Al-Gabalawy ◽  
Nesreen S. Hosny ◽  
Shimaa A. Hussien

This paper introduces a physical–chemical model that governs the lithium ion (Li-ion) battery performance. It starts from the model of battery life and moves forward with simplifications based on the single-particle model (SPM), until arriving at a more simplified and computationally fast model. On the other hand, the implementation of this model is developed through MATLAB. The goal is to characterize an Li-ion cell and obtain its charging and discharging curves with different current rates and different cycle depths, as well as its transitory response. In addition, the results provided are represented and compared, and different methods of estimating the state of the batteries are applied. They include the dynamics of the electrolyte and the effects of aging caused by a high number of charging and discharging cycles of the batteries. A complete comparison with the three-parameter method (TPM) is represented in order to demonstrate the superiority of the applied methodology.

Batteries ◽  
2021 ◽  
Vol 7 (3) ◽  
pp. 51
Author(s):  
Manh-Kien Tran ◽  
Andre DaCosta ◽  
Anosh Mevawalla ◽  
Satyam Panchal ◽  
Michael Fowler

Lithium-ion (Li-ion) batteries are an important component of energy storage systems used in various applications such as electric vehicles and portable electronics. There are many chemistries of Li-ion battery, but LFP, NMC, LMO, and NCA are four commonly used types. In order for the battery applications to operate safely and effectively, battery modeling is very important. The equivalent circuit model (ECM) is a battery model often used in the battery management system (BMS) to monitor and control Li-ion batteries. In this study, experiments were performed to investigate the performance of three different ECMs (1RC, 2RC, and 1RC with hysteresis) on four Li-ion battery chemistries (LFP, NMC, LMO, and NCA). The results indicated that all three models are usable for the four types of Li-ion chemistries, with low errors. It was also found that the ECMs tend to perform better in dynamic current profiles compared to non-dynamic ones. Overall, the best-performed model for LFP and NCA was the 1RC with hysteresis ECM, while the most suited model for NMC and LMO was the 1RC ECM. The results from this study showed that different ECMs would be suited for different Li-ion battery chemistries, which should be an important factor to be considered in real-world battery and BMS applications.


Nanoscale ◽  
2021 ◽  
Author(s):  
Kun Wang ◽  
Yongyuan Hu ◽  
Jian Pei ◽  
Fengyang Jing ◽  
Zhongzheng Qin ◽  
...  

High capacity Co2VO4 becomes a potential anode material for lithium ion batteries (LIBs) benefiting from its lower output voltage during cycling than other cobalt vanadates. However, the application of this...


Electronics ◽  
2021 ◽  
Vol 10 (4) ◽  
pp. 487
Author(s):  
Tae-Kue Kim ◽  
Sung-Chun Moon

The growth of the lithium-ion battery market is accelerating. Although they are widely used in various fields, ranging from mobile devices to large-capacity energy storage devices, stability has always been a problem, which is a critical disadvantage of lithium-ion batteries. If the battery is unstable, which usually occurs at the end of its life, problems such as overheating and overcurrent during charge-discharge increase. In this paper, we propose a method to accurately predict battery life in order to secure battery stability. Unlike the existing methods, we propose a method of assessing the life of a battery by estimating the irreversible energy from the basic law of entropy using voltage, current, and time in a realistic dimension. The life estimation accuracy using the proposed method was at least 91.6%, and the accuracy was higher than 94% when considering the actual used range. The experimental results proved that the proposed method is a practical and effective method for estimating the life of lithium-ion batteries.


2015 ◽  
Vol 3 (30) ◽  
pp. 15403-15407 ◽  
Author(s):  
Xizheng Liu ◽  
De Li ◽  
Songyan Bai ◽  
Haoshen Zhou

Magnetic Fe3O4 particles are used as the binder in a Li-ion battery. This new battery gives a long cycle life and can work well even after intensive vibration. The electrode is fabricated in a liquid-free process and can be easily recycled after battery disposal. It decrease the total cost and pollutant emission over the whole battery life.


Author(s):  
Satadru Dey ◽  
Beshah Ayalew

This paper proposes and demonstrates an estimation scheme for Li-ion concentrations in both electrodes of a Li-ion battery cell. The well-known observability deficiencies in the two-electrode electrochemical models of Li-ion battery cells are first overcome by extending them with a thermal evolution model. Essentially, coupling of electrochemical–thermal dynamics emerging from the fact that the lithium concentrations contribute to the entropic heat generation is utilized to overcome the observability issue. Then, an estimation scheme comprised of a cascade of a sliding-mode observer and an unscented Kalman filter (UKF) is constructed that exploits the resulting structure of the coupled model. The approach gives new real-time estimation capabilities for two often-sought pieces of information about a battery cell: (1) estimation of cell-capacity and (2) tracking the capacity loss due to degradation mechanisms such as lithium plating. These capabilities are possible since the two-electrode model needs not be reduced further to a single-electrode model by adding Li conservation assumptions, which do not hold with long-term operation. Simulation studies are included for the validation of the proposed scheme. Effect of measurement noise and parametric uncertainties is also included in the simulation results to evaluate the performance of the proposed scheme.


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