scholarly journals Gold and Ceria as Catalysts for VOC Abatement: A Review

Catalysts ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 789
Author(s):  
Jana Gaálová ◽  
Pavel Topka

Due to its excellent oxygen storage capacity, ceria is a well-known oxidation catalyst. However, its performance in the oxidation of volatile organic compounds can be improved by the introduction of gold. Depending on the type of VOC to be oxidized, the surface of gold nanoparticles and the gold/ceria interface may contribute to enhanced activity and/or selectivity. Choosing a proper preparation method is crucial to obtain optimal gold particle size. Deposition–precipitation was found to be more suitable than coprecipitation or impregnation. For industrial applications, monolithic catalysts are needed to minimize the pressure drop in the reactor and reduce mass and heat transfer limitations. In addition to the approach used with powder catalysts, the method employed to introduce gold in/on the washcoat has to be considered.

2007 ◽  
Vol 7 (11) ◽  
pp. 4013-4016 ◽  
Author(s):  
SeungSoo Lim ◽  
DongJu Moon ◽  
JongHo Kim ◽  
YoungChul Kim ◽  
NamCook Park ◽  
...  

Autothermal reforming of propane for hydrogen over Ni catalysts supported on a variety of perovskites was performed in an atmospheric flow reactor. Perovskite is known for its higher thermal stability and oxygen storage capacity, but catalytic activity of itself is low. A sites of the ABO3 structured perovskites were occupied by La while B sites by one of Fe, Co, Ni, and Al by citrate method. The composition of the reactant mixture was H2O/C/O2 = 8.96/1.0/1.1. The changes in the states of the catalysts after reaction were analyzed by XRD, TPD, and TGA. Ni/LaAlO3 catalyst maintained the perovskite structure after reaction. It showed higher hydrogen yield and thermal stability compared to those of the catalysts with Fe, Co, or Ni in B sites. Catalysts prepared by deposition-precipitation (DP) method showed higher activity than those prepared by impregnation method, presumably due to the smaller sizes of the NiO crystal particles.


2016 ◽  
Vol 40 (12) ◽  
pp. 10108-10115 ◽  
Author(s):  
Genyuan Zhao ◽  
Jing Li ◽  
Wenshuang Zhu ◽  
Xueqin Ma ◽  
Yonghua Guo ◽  
...  

Herein, we demonstrate the influence of zirconium species on promoting the oxygen storage capacity and three-way catalytic properties of zirconium-manganese oxide catalysts.


2021 ◽  
Author(s):  
Liam Mc Grane ◽  
Roy Douglas ◽  
Kurtis Irwin ◽  
Andrew Woods ◽  
Jonathan Stewart ◽  
...  

1985 ◽  
Vol 17 (1) ◽  
pp. 75-86 ◽  
Author(s):  
E.C. Su ◽  
C.N. Montreuil ◽  
W.G. Rothschild

2016 ◽  
Vol 52 (68) ◽  
pp. 10369-10372 ◽  
Author(s):  
Lu Liu ◽  
Daniel D. Taylor ◽  
Efrain E. Rodriguez ◽  
Michael R. Zachariah

The selection of highly efficient oxygen carriers (OCs) is a key step necessary for the practical development of chemical looping combustion (CLC).


Nano Letters ◽  
2011 ◽  
Vol 11 (2) ◽  
pp. 361-364 ◽  
Author(s):  
Jing Zhang ◽  
Hitoshi Kumagai ◽  
Kae Yamamura ◽  
Satoshi Ohara ◽  
Seiichi Takami ◽  
...  

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