scholarly journals Fabrication of PEO-PMMA-LiClO4-Based Solid Polymer Electrolytes Containing Silica Aerogel Particles for All-Solid-State Lithium Batteries

Energies ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 2559 ◽  
Author(s):  
Ye Lim ◽  
Hyun-Ah Jung ◽  
Haejin Hwang
Keyword(s):  
Polymer Electrolyte ◽  
Polymer Electrolytes ◽  
Silica Aerogel ◽  
Solid Polymer Electrolyte ◽  
Ethylene Carbonate ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Lithium Ion Conductivity

To improve the ionic conductivity and thermal stability of a polyethylene oxide (PEO)-ethylene carbonate (EC)-LiClO4-based solid polymer electrolyte for lithium-ion batteries, polymethyl methacrylate (PMMA) and silica aerogel were incorporated into the PEO matrix. The effects of the PEO:PMMA molar ratio and the amount of silica aerogel on the structure of the PEO-PMMA-LiClO4 solid polymer electrolyte were studied by X-ray diffraction, Fourier-transform infrared spectroscopy and alternating current (AC) impedance measurements. The solid polymer electrolyte with PEO:PMMA = 8:1 and 8 wt% silica aerogel exhibited the highest lithium-ion conductivity (1.35 × 10−4 S∙cm−1 at 30 °C) and good mechanical stability. The enhanced amorphous character and high degree of dissociation of the LiClO4 salt were responsible for the high lithium-ion conductivity observed. Silica aerogels with a high specific surface area and mesoporosity could thus play an important role in the development of solid polymer electrolytes with improved structure and stability.

Creating ionic channels in single-ion conducting solid polymer electrolyte by manipulating phase separation structure

2018 ◽  
Vol 6 (48) ◽  
pp. 24848-24859 ◽  
Author(s):  
Zhen Li ◽  
Qiming Yao ◽  
Qi Zhang ◽  
Yangqiang Zhao ◽  
Dangxun Gao ◽  
...  
Keyword(s):  
Phase Separation ◽  
Polymer Electrolyte ◽  
Solid Polymer Electrolyte ◽  
Lithium Ion ◽  
Ionic Channels ◽  
Hyperbranched Polymers ◽  
Ion Conductivity ◽  
Solid Polymer ◽  
Lithium Ion Conductivity ◽  
Ion Conducting

An approach to construct ionic channels in SICSPEs by blending pre-assembled ionic nanowires and hyperbranched polymers for high lithium-ion conductivity.

Highly efficient solid polymer electrolytes using ion containing polymer microgels

2015 ◽  
Vol 6 (7) ◽  
pp. 1052-1055 ◽  
Author(s):  
Suting Yan ◽  
Jianda Xie ◽  
Qingshi Wu ◽  
Shiming Zhou ◽  
Anqi Qu ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Polymer Electrolyte ◽  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolyte ◽  
Solid Polymer Electrolytes ◽  
High Ionic Conductivity ◽  
Solid Polymer ◽  
Highly Efficient ◽  
Potential Use

A solid polymer electrolyte fabricated using ion containing microgels manifests high ionic conductivity for potential use in lithium batteries.

Hexagonal boron nitride induces anion trapping in a polyethylene oxide based solid polymer electrolyte for lithium dendrite inhibition

2020 ◽  
Vol 8 (19) ◽  
pp. 9579-9589 ◽  
Author(s):  
Yuhan Li ◽  
Libo Zhang ◽  
Zongjie Sun ◽  
Guoxin Gao ◽  
Shiyao Lu ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Polymer Electrolyte ◽  
Polyethylene Oxide ◽  
Solid Polymer Electrolyte ◽  
Hexagonal Boron Nitride ◽  
Lithium Ion ◽  
Solid Polymer ◽  
Lithium Ion Conductivity ◽  
Lithium Dendrite ◽  
Composite Solid

Lithium ion conductivity and mechanical strength of a PEO based composite solid polymer electrolyte are improved by adding h-BN.

scholarly journals High sodium ionic conductivity in PEO/PVP solid polymer electrolytes with InAs nanowire fillers

2021 ◽  
Author(s):  
Chandni Devi ◽  
Jnaneswari Gellanki ◽  
Håkan Pettersson ◽  
Sandeep Kumar
Keyword(s):  
Energy Storage ◽  
Ionic Conductivity ◽  
Polymer Electrolyte ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolyte ◽  
Low Cost ◽  
Solid Polymer Electrolytes ◽  
Sodium Ion ◽  
Solid Polymer ◽  
Significant Advance

Abstract Solid-state sodium ion batteries are frequently referred to as the most promising technology for future energy storage applications. However, developing a solid electrolyte with high ionic conductivity and a wide electrochemical stability window, remains a major challenge. Although solid-polymer electrolytes have attracted great interest due to their low cost, low density and very good processability, they generally have significantly lower ionic conductivity and poor mechanical strength. Here, we report on the development of a low-cost solid polymer electrolyte comprised of poly(ethylene oxide), poly(vinylpyrrolidone) and sodium hexafluorophosphate, mixed with indium arsenide nanowires. We show that the addition of 1.0 percent by weight of nanowires increases the sodium ion conductivity in the polymer to 1.50 × 10-4 Scm−1 at 40° C. This is the highest reported conductivity for any solid polymer electrolyte to date. In order to explain this remarkable characteristic, we propose a new transport model where sodium ions hop between close-spaced defect sites present on the surface of the nanowires, forming an effective complex conductive percolation network. Our work represents a significant advance in the development of novel solid polymer electrolytes with embedded ultrafast 1D percolation networks for next generations of low-cost, high-performance batteries with excellent energy storage capabilities.

Tailored high cycling performance in a solid polymer electrolyte with perovskite-type Li0.33La0.557TiO3 nanofibers for all-solid-state lithium ion batteries

2019 ◽  
Vol 48 (10) ◽  
pp. 3263-3269 ◽  
Author(s):  
Kang-Qiang He ◽  
Jun-Wei Zha ◽  
Peng Du ◽  
Samson Ho-Sum Cheng ◽  
Chen Liu ◽  
...  
Keyword(s):  
Solid State ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolyte ◽  
Lithium Ion ◽  
Cycling Performance ◽  
Electrochemical Stability ◽  
Safety Performance ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Perovskite Type

Solid polymer electrolytes (SPEs) have drawn considerable attention owing to their reliable safety performance, electrochemical stability and exceptional flexibility.

Studies on thin films of PVC-PMMA blend polymer electrolytes

2013 ◽  
Vol 33 (7) ◽  
pp. 633-638 ◽  
Author(s):  
Mohammad Saleem Khan ◽  
Rahmat Gul ◽  
Mian Sayed Wahid
Keyword(s):  
Thin Films ◽  
Thermal Stability ◽  
Ionic Conductivity ◽  
Polymer Electrolyte ◽  
Polymer Electrolytes ◽  
Ethylene Carbonate ◽  
Salt Content ◽  
Solid Polymer Electrolytes ◽  
Solid Polymer ◽  
Degree Of Crystallinity

Abstract Thin films of poly (vinyl chloride) (PVC)/poly (methyl methacrylate) (PMMA) blend polymers complexed with different concentrations of LiClO4 salt, containing ethylene carbonate (EC) as the plasticizer, were fabricated by the solution cast procedure. Ionic conductivity, thermal stability and X-ray diffraction (XRD) studies were undertaken. AC impedance measurements were done in the temperature range of 20–70°C. The highest ionic conductivity at room temperature was found to be 2.23×10-5 S cm-1 for the sample containing 15 wt% of LiClO4 salt. The XRD technique was used to investigate the structure and complex formation of solid polymer electrolytes. There was a decrease in degree of crystallinity. The amorphous nature of complexed solid polymer blend electrolyte films increased, due to the addition of LiClO4 salt. Thermogravimetric analysis (TGA) and differential thermal analysis (DTA) revealed the effect of salt on the thermal stability of the polymer electrolytes. It was found that these polymer electrolyte systems show stability up to about 280°C. It was also found that, with increased LiClO4 salt content in complexed polymer electrolyte systems, the degradation temperature decreased.

scholarly journals High ion-conducting solid polymer electrolytes based on blending hybrids derived from monoamine and diamine polyethers for lithium solid-state batteries

RSC Advances ◽  
2017 ◽  
Vol 7 (33) ◽  
pp. 20373-20383 ◽  
Author(s):  
Ta-Ming Liu ◽  
Diganta Saikia ◽  
Sze-Yuan Ho ◽  
Ming-Chou Chen ◽  
Hsien-Ming Kao
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Polymer Electrolyte ◽  
Polymer Electrolytes ◽  
Solid Polymer Electrolyte ◽  
Solid Polymer Electrolytes ◽  
High Ionic Conductivity ◽  
Solid Polymer ◽  
Solid State Batteries ◽  
Ion Conducting

The blended hybrid solid polymer electrolyte possessed a high ionic conductivity value of 1.2 × 10−4 S cm−1 at 30 °C.

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