scholarly journals Passivation Strategies through Surface Reconstruction toward Highly Efficient and Stable Perovskite Solar Cells on n-i-p Architecture

Energies ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4836
Author(s):  
Jiajia Suo ◽  
Bowen Yang ◽  
Anders Hagfeldt

Perovskite solar cells have achieved remarkable enhancement in their performance in recent years. However, to get an entrance to the photovoltaic market, great effort is still necessary to further improve their efficiency as well as their long-term stability under various conditions. Among various types of approaches (including compositional engineering, dopant engineering, self-assembled monolayers (SAMs), et al.), interfacial engineering through passivation treatment has been considered as one of the most effective strategies to reduce the non-radiative recombination within the PSCs. Thus, this short review summaries recent efforts on chemical interfacial passivation strategies from a different perspective owing to their common phenomena of reconstructing the perovskite surface via the formation of three-dimensional perovskite, low-dimensional perovskite and synergistic effect provided by a mixed-salt passivation system, respectively.

Nanophotonics ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Tianqi Niu ◽  
Qifan Xue ◽  
Hin-Lap Yip

Abstract Low-dimensional metal halide perovskites have emerged as promising alternatives to the traditional three-dimensional (3D) components, due to their greater structural tunability and environmental stability. Dion-Jacobson (DJ) phase two-dimensional (2D) perovskites, which are formed by incorporating bulky organic diammonium cations into inorganic frameworks that comprises a symmetrically layered array, have recently attracted increasing research interest. The structure-property characteristics of DJ phase perovskites endow them with a unique combination of photovoltaic efficiency and stability, which has led to their impressive employment in perovskite solar cells (PSCs). Here, we review the achievements that have been made to date in the exploitation of DJ phase perovskites in photovoltaic applications. We summarize the various ligand designs, optimization strategies and applications of DJ phase PSCs, and examine the current understanding of the mechanisms underlying their functional behavior. Finally, we discuss the remaining bottlenecks and future outlook for these promising materials, and possible development directions of further commercial processes.


Energies ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 2 ◽  
Author(s):  
Cuili Gai ◽  
Jigang Wang ◽  
Yongsheng Wang ◽  
Junming Li

Halide perovskite solar cells (PSCs) are considered as one of the most promising candidates for the next generation solar cells as their power conversion efficiency (PCE) has rapidly increased up to 25.2%. However, the most efficient halide perovskite materials all contain toxic lead. Replacing the lead cation with environmentally friendly tin (Sn) is proposed as an important alternative. Today, the inferior performance of Sn-based PSCs mainly due to two challenging issues, namely the facile oxidation of Sn2+ to Sn4+ and the low formation energies of Sn vacancies. Two-dimensional (2D) halide perovskite, in which the large sized organic cations confine the corner sharing BX6 octahedra, exhibits higher formation energy than that of three-dimensional (3D) structure halide perovskite. The approach of mixing a small amount of 2D into 3D Sn-based perovskites was demonstrated as an efficient method to produce high performance perovskite films. In this review, we first provide an overview of key points for making high performance PSCs. Then we give an introduction to the physical parameters of 3D ASnX3 (MA+, FA+, and Cs+) perovskite and a photovoltaic device based on them, followed by an overview of 2D/3D halide perovskites based on ASnX3 (MA+ and FA+) and their optoelectronic applications. The current challenges and a future outlook of Sn-based PSCs are discussed in the end. This review will give readers a better understanding of the 2D/3D Sn-based PSCs.


Author(s):  
Zhihai Liu ◽  
Lei Wang ◽  
Chongyang Xu ◽  
Xiaoyin Xie

Recently, Ruddlesden–Popper two-dimensional (2D) perovskite solar cells (PSCs) have been intensively studied, owing to their high power conversion efficiency (PCE) and excellent long-term stability. In this work, we fabricated electron-transport-layer-free...


Solar Energy ◽  
2021 ◽  
Vol 218 ◽  
pp. 28-34
Author(s):  
Mahmoud Samadpour ◽  
Mahsa Heydari ◽  
Mahdi Mohammadi ◽  
Parisa Parand ◽  
Nima Taghavinia

Author(s):  
Eun-Cheol Lee ◽  
Zhihai Liu

Recently, Ruddlesden–Popper two-dimensional (2D) perovskite solar cells (PSCs) have been intensively studied, owing to their high power conversion efficiency (PCE) and excellent long-term stability. In this work, we improved the...


2021 ◽  
pp. 131754
Author(s):  
Lyubov A. Frolova ◽  
Lavrenty G. Gutsev ◽  
Bala R. Ramachandran ◽  
Nadezhda N. Dremova ◽  
Sergey M. Aldoshin ◽  
...  

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