scholarly journals Selective Extraction of Piceatannol from Passiflora edulis By-Products: Application of HSPs Strategy and Inhibition of Neurodegenerative Enzymes

2021 ◽  
Vol 22 (12) ◽  
pp. 6248
Author(s):  
Luana dos Santos ◽  
Jose Mendiola ◽  
Andrea Sánchez-Camargo ◽  
Gerardo Álvarez-Rivera ◽  
Juliane Viganó ◽  
...  
Keyword(s):  
Selective Extraction ◽  
Relative Energy ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Passiflora Edulis ◽  
Energy Distance ◽  
Environmentally Safe ◽  
Conventional Extraction ◽  
By Products ◽  
Hansen Solubility

Passiflora edulis by-products (PFBP) are a rich source of polyphenols, of which piceatannol has gained special attention recently. However, there are few studies involving environmentally safe methods for obtaining extracts rich in piceatannol. This work aimed to concentrate piceatannol from defatted PFBP (d-PFBP) by means of pressurized liquid extraction (PLE) and conventional extraction, using the bio-based solvents selected with the Hansen solubility parameters approach. The relative energy distance (Ra) between solvent and solute was: Benzyl Alcohol (BnOH) < Ethyl Acetate (EtOAc) < Ethanol (EtOH) < EtOH:H2O. Nonetheless, EtOH presented the best selectivity for piceatannol. Multi-cycle PLE at 110 °C was able to concentrate piceatannol 2.4 times more than conventional extraction. PLE exhibited a dependence on kinetic parameters and temperature, which could be associated with hydrogen bonding forces and the dielectric constant of the solvents. The acetylcholinesterase (AChE) and lipoxygenase (LOX) IC50 were 29.420 μg/mL and 27.682 μg/mL, respectively. The results reinforce the demand for processes to concentrate natural extracts from food by-products.

Application of Hansen solubility approach for the subcritical and supercritical selective extraction of phlorotannins from Cystoseira abies-marina

RSC Advances ◽  
2016 ◽  
Vol 6 (97) ◽  
pp. 94884-94895 ◽  
Author(s):  
A. P. Sánchez-Camargo ◽  
L. Montero ◽  
A. Cifuentes ◽  
M. Herrero ◽  
E. Ibáñez
Keyword(s):  
Theoretical Approach ◽  
Selective Extraction ◽  
Bioactive Molecules ◽  
Solubility Parameters ◽  
Green Solvent ◽  
Hansen Solubility Parameters ◽  
Brown Macroalgae ◽  
First Time ◽  
Hansen Solubility

A new theoretical approach based on Hansen solubility parameters has been employed for the first time to select the best green solvent to extract complex bioactive molecules such as phlorotannins from brown macroalgae Cystoseira abies-marina.

scholarly journals Effect of Varying Solvents on Structural Properties of Annealed PVDF-Trfe Thin Films

2019 ◽  
Vol 7 (4.14) ◽  
pp. 440
Author(s):  
A. N. Arshad ◽  
M. N. Sarip ◽  
M. N. Sarip ◽  
E. Z. Engku Zaharah ◽  
M. D. Rozana
Keyword(s):  
Energy Difference ◽  
Relative Energy ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Polar Solvents ◽  
Xrd Pattern ◽  
Β Phase ◽  
Relative Increment ◽  
High Degree ◽  
Hansen Solubility

PVDF-TrFE (70:30 mol%) powders were dissolved individually in three polar solvents of Diethyl Carbonate (DEC), Methyl Ethyl Ketone (MEK) and N-, N-, Dimethylformamide (DMF). The solution was spin coated and formed PVDF-TrFE films of 250 nm thickness; UN DEC, UN MEK and UN DMF films.  PVDF-TrFE powders were found to readily dissolve in DMF solvent as indicated by Hansen solubility parameters (δt). Hansen parameter showed small difference in reading (δt = 1.7) for PVDF-TrFE and DMF, and low relative energy difference (RED) value. All films were annealed at 120°C (AN DEC, AN MEK, AN DMF). The AN DMF film showed high presence of polar β-phase crystals as evident from the ATR-FTIR spectrum. This is given by the significant peaks at 848, 1190, and 1290 cm-1. The trend is consistent with XRD pattern, where relative increment of cps value (53%) at 19.2° (2θ) is observed. This further supports the high degree of β-phase crystals observed in AN DMF film.  

Determination of Hansen solubility parameters for sugarcane oil. Use of ethanol in sugarcane wax refining

2021 ◽  
Vol 72 (2) ◽  
pp. e408
Author(s):  
E. Hernández
Keyword(s):  
Castor Oil ◽  
Energy Difference ◽  
Relative Energy ◽  
Refining Process ◽  
High Rate ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Consumption Rates ◽  
Hansen Solubility

Currently, the refining of sugarcane wax is carried out with 95% v/v ethanol as solvent. This process has a high rate of ethanol consumption thus, the main objective of this work was to corroborate the feasibility of 95% v/v ethanol as a solvent in the refining of sugarcane wax. The suitability of its performance over other organic solvents was evaluated through the relative energy difference (RED) determined from Hansen solubility parameters (HSPs) of sugarcane oil, which were calculated using HSPiP software. HSPs turned out to be δD = 16.24 MPa½, δP = 3.21 MPa½ and δH = 10.34 MPa½, similar to those reported for pine resin and castor oil. The best solvent was 1-decanol. 95% v/v ethanol turned out to be a bad solvent. Absolute ethanol had a RED value of 0.993, which made it a better candidate since it could reduce consumption rates, and constituted an eco-friendly solvent produced in Cuba for the refining process.

Measurement of Hansen Solubility Parameters of Third-Degree Burn Eschar

Burns ◽  
2021 ◽  
Author(s):  
Maryam Hosseini ◽  
Michael S. Roberts ◽  
Reza Aboofazeli ◽  
Hamid R. Moghimi
Keyword(s):  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Degree Burn ◽  
Hansen Solubility

scholarly journals Solubilization of Trans-Resveratrol in Some Mono-Solvents and Various Propylene Glycol + Water Mixtures

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3091
Author(s):  
Mohammed Ghazwani ◽  
Prawez Alam ◽  
Mohammed H. Alqarni ◽  
Hasan S. Yusufoglu ◽  
Faiyaz Shakeel
Keyword(s):  
Propylene Glycol ◽  
Mole Fraction ◽  
Bioactive Compound ◽  
Theoretical Models ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
Neat Water ◽  
Dissolution Properties ◽  
Hansen Solubility

This research deals with the determination of solubility, Hansen solubility parameters, dissolution properties, enthalpy–entropy compensation, and computational modeling of a naturally-derived bioactive compound trans-resveratrol (TRV) in water, methanol, ethanol, n-propanol, n-butanol, propylene glycol (PG), and various PG + water mixtures. The solubility of TRV in six different mono-solvents and various PG + water mixtures was determined at 298.2–318.2 K and 0.1 MPa. The measured experimental solubility values of TRV were regressed using six different computational/theoretical models, including van’t Hoff, Apelblat, Buchowski–Ksiazczak λh, Yalkowsly–Roseman, Jouyban–Acree, and van’t Hoff–Jouyban–Acree models, with average uncertainties of less than 3.0%. The maxima of TRV solubility in mole fraction was obtained in neat PG (2.62 × 10−2) at 318.2 K. However, the minima of TRV solubility in the mole fraction was recorded in neat water (3.12 × 10−6) at 298.2 K. Thermodynamic calculation of TRV dissolution properties suggested an endothermic and entropy-driven dissolution of TRV in all studied mono-solvents and various PG + water mixtures. Solvation behavior evaluation indicated an enthalpy-driven mechanism as the main mechanism for TRV solvation. Based on these data and observations, PG has been chosen as the best mono-solvent for TRV solubilization.

Application of the Hansen Solubility Parameters Theory to Carbon Nanotubes

2008 ◽  
Vol 8 (11) ◽  
pp. 6082-6092 ◽  
Author(s):  
S. Detriche ◽  
G. Zorzini ◽  
J.-F. Colomer ◽  
A. Fonseca ◽  
J. B. Nagy
Keyword(s):  
Carbon Nanotubes ◽  
Present Approach ◽  
New Method ◽  
Solubility Parameters ◽  
Hansen Solubility Parameters ◽  
High Solubility ◽  
New Approach ◽  
Hansen Solubility

Carbon nanotubes (CNT) are very promising nano-objects due to their exceptional properties. However, their tendency to form bundles as well as their insolubility in common solvents makes them difficult to handle. The main way to solve the problem is chemical or physical CNTs functionalisations, with all the problems inherent to the methods. In this contribution, we present a new approach that allows predicting the solubility of carbon nanotubes in many solvents but also predicting the most appropriate solvents to use for given samples of CNTs. Solubilisation and dispersion being directly connected, the present approach of solubilisation proves also to be efficient in dispersing the CNTs bundles. This contribution is a first step toward the control of carbon nanotube's dispersion in polymers and their homogenous functionalisation. Moreover, we also report here a new method, based on solvents, to separate carbon nanotubes by size, the use of mixture of non-solvents in order to obtain good solvents and the use of mixture of good solvents to obtain higher solubility. The use of mixture of good solvents allowed us to obtain high solubility, up to three times higher then that reported in literature. We have also measured and analysed the solubility of some functionalised carbon nanotubes.

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