scholarly journals Temperature-Dependent Luminescence of Red-Emitting Ba2Y5B5O17: Eu3+ Phosphors with Efficiencies Close to Unity for Near-UV LEDs

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 763 ◽  
Author(s):  
Egle Ezerskyte ◽  
Julija Grigorjevaite ◽  
Agne Minderyte ◽  
Sebastien Saitzek ◽  
Arturas Katelnikovas

Solid state white light sources based on a near-UV LED chip are gaining more and more attention. This is due to the increasing efficiency of near-UV-emitting LED chips and wider phosphors selection if compared to devices based on blue LED chips. Here, a brief overview is given of the concepts of generating white light employing near-UV LED and some optical properties of the available phosphors are discussed. Finally, the synthesis and optical properties of very efficient red-emitting Ba2Y5B5O17:Eu3+ phosphor powder and ceramics is reported and discussed in terms of possible application as a red component in near-UV LED-based white light sources.

CrystEngComm ◽  
2019 ◽  
Vol 21 (43) ◽  
pp. 6566-6573
Author(s):  
Dongyi Shen ◽  
Yiran Shao ◽  
Yingchun Zhu

The bandgap energy of Si3N4:Al is precisely and gradually tailored from 2.58 to 2.85 eV by increasing the Al concentration. Si3N4:Al:Eu phosphors exhibiting a yellow-orange emission are promising for solid-state warm white lighting under blue chip excitation.


2015 ◽  
Vol 3 (27) ◽  
pp. 7096-7104 ◽  
Author(s):  
Kai Li ◽  
Mengmeng Shang ◽  
Yang Zhang ◽  
Jian Fan ◽  
Hongzhou Lian ◽  
...  

A series of Ca9Bi(PO4)7:Ce3+,Tb3+,Mn2+phosphors synthesizedviathe high-temperature solid-state reaction method can emit intense tunable color from purple-blue to red including white under UV excitation, which shows their potential application in UV-pumped white-light-emitting diodes.


Nanomaterials ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 153 ◽  
Author(s):  
Mahdi Kiani Khouzani ◽  
Abbas Bahrami ◽  
Maryam Yazdan Mehr ◽  
Willem Dirk van Driel ◽  
Guoqi Zhang

This paper aims to investigate the synthesis, structure, and optical properties of SiO2@YAG:Ce core–shell optical nanoparticles for solid state lighting applications. YAG:Ce phosphor is a key part in white light emitting diodes (LEDs), with its main functionality being the generation of yellow light. Generated yellow light from phosphor will be combined with blue light, emitted from chip, resulting in the generation of white light. Generated light in LEDs will often be scattered by SiO2 nanoparticles. SiO2 nanoparticles are often distributed within the optical window, aiming for a more homogeneous light output. The main idea in this research is to combine these functionalities in one core–shell particle, with its core being SiO2 and its shell being phosphor. In this study core–shell nanoparticles with different Ce3+ concentrations were synthesized by a sol–gel method. Synthesized nanoparticles were characterized by X-ray diffraction (XRD), small angle X-ray scattering (SAXS) analysis, high resolution transmission electron macroscopy (HRTEM), Fourier transform infrared (FTIR), and photoluminescence spectroscopy. Luminescence characteristics of SiO2@YAG:Ce core–shell particles were compared with that of SiO2/YAG:Ce mixture composite, which is now used in commercial LEDs. Obtained results showed that core–shell nanoparticles have comparatively much better optical properties, compared to SiO2/YAG:Ce mixture composite and can therefore be potentially used in LEDs.


2014 ◽  
Vol 2 (16) ◽  
pp. 2851-2858 ◽  
Author(s):  
B. B. Wang ◽  
K. Ostrikov ◽  
K. Zheng ◽  
L. Wang ◽  
S. S. Zou

Carbon nanoflakes (CNFLs) are synthesized on silicon substrates deposited with carbon islands in a methane environment using hot filament chemical vapor deposition.


Author(s):  
Chen-Kang Huang ◽  
Jeng-Gang Sung

Benefited by the progress of material science, Light-Emitting Diodes (LED) with UV-emitting have been produced successfully. Like other LEDs, UV-LEDs exhibit several advantages, such as energy conservation, long life, compact, and quick response. The UV-LED application to microlithography is attractive. In contrast to point light sources requiring lens to generate parallel light beams, an array of UV-LEDs can emit nearly parallel light beams easily. UV-LEDs only need 3 to 4 voltages to ignite, which is much lower than that required by mercury short arc lamps. The cost of using UV-LEDs is also much lower than current solutions. In this study, we used UV-LEDs as the light source in the laboratory lithography system. LEDs, whose emitting spectrum distributed between 370 to 410 nm mostly, were displaced on the bottom of a heat sink. Two 10-by-10 cm2 test masks, where the smallest pattern was 20 μm, were used to examine the resolution ability of this combination. Each light module was utilized to exposure photosensitized printed circuit board (PCB). After etching, the printed patterns were observed under microscope. The minimum reproducible feature size was 100 μm. Through the 4” mask, the uniformity was decent, and could be improved by using LEDs from the same batch, collimator, or LED displacement optimization. In the future, standard g-line process can be performed, and further tests will be performed to check the limits of the UV-LED system. Based on these preliminary tests, it seems like the usage of UV-LEDs should be a feasible solution for microlithography.


2000 ◽  
Vol 622 ◽  
Author(s):  
M. H. Crawford ◽  
J. Han ◽  
R. J. Shul ◽  
M. A. Banas ◽  
J. J. Figiel ◽  
...  

ABSTRACTWe overview several of the challenges in achieving high efficiency nitride-based UV (< 400 nm) LEDs. The issue of optical efficiency is presented through temperature-dependent photoluminescence studies of various UV active regions. These studies demonstrate enhanced optical efficiencies for active regions with In-containing alloys ( InGaN, AlInGaN). We compare the performance of two distinct UV LED structures. GaN/AlGaN quantum well LEDs with λ < 360 nm emission have demonstrated output powers > 0.1 mW, but present designs suffer from internal absorption effects. InGaN/AlInGaN quantum well LEDs with 370 nm< λ < 390 nm emission and > 1 mW output power are also presented.


2016 ◽  
Vol 4 (40) ◽  
pp. 9561-9568 ◽  
Author(s):  
Fei Tang ◽  
Zhicheng Su ◽  
Honggang Ye ◽  
Mingzheng Wang ◽  
Xin Lan ◽  
...  

Transition-metal ion activated solid-state phosphors are of particular interest for the development of LED-based white light sources.


ACS Nano ◽  
2020 ◽  
Vol 14 (6) ◽  
pp. 7161-7169 ◽  
Author(s):  
Iñigo Ramiro ◽  
Biswajit Kundu ◽  
Mariona Dalmases ◽  
Onur Özdemir ◽  
María Pedrosa ◽  
...  

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