scholarly journals Relationship between Viscosity, Microstructure and Electrical Conductivity in Copolyamide Hot Melt Adhesives Containing Carbon Nanotubes

Materials ◽  
2020 ◽  
Vol 13 (20) ◽  
pp. 4469
Author(s):  
Paulina Latko-Durałek ◽  
Rafał Kozera ◽  
Jan Macutkevič ◽  
Kamil Dydek ◽  
Anna Boczkowska
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Lightning Strike ◽  
Real Problem ◽  
Conductive Adhesives ◽  
Electrically Conductive ◽  
Thermoset Composites ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Hot Melt

The polymeric adhesive used for the bonding of thermoplastic and thermoset composites forms an insulating layer which causes a real problem for lightning strike protection. In order to make that interlayer electrically conductive, we studied a new group of electrically conductive adhesives based on hot melt copolyamides and multi-walled carbon nanotubes fabricated by the extrusion method. The purpose of this work was to test four types of hot melts to determine the effect of their viscosity on the dispersion of 7 wt % multi-walled carbon nanotubes and electrical conductivity. It was found that the dispersion of multi-walled carbon nanotubes, understood as the amount of the agglomerates in the copolyamide matrix, is not dependent on the level of the viscosity of the polymer. However, the electrical conductivity, analyzed by four-probe method and dielectric spectroscopy, increases when the number of carbon nanotube agglomerates decreases, with the highest value achieved being 0.67 S/m. The inclusion of 7 wt % multi-walled carbon nanotubes into each copolyamide improved their thermal stability and changed their melting points by only a few degrees. The addition of carbon nanotubes makes the adhesive’s surface more hydrophilic or hydrophobic depending on the type of copolyamide used.

scholarly journals Electrically Conductive Composite based on Functionalized Carbon Nanotubes/Epoxy Resin

2020 ◽  
Vol 9 (4) ◽  
pp. 1401-1404
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Epoxy Resin ◽  
Isopropyl Alcohol ◽  
Electrophysical Properties ◽  
Electrically Conductive ◽  
Functionalized Carbon Nanotubes ◽  
Multi Walled Carbon Nanotubes ◽  
Electrically Conductive Composite ◽  
Walled Carbon Nanotubes

This work is devoted to the study of the effect of carbon nanotubes functionalization on the electrical conductivity of composite materials based on them. Carbon nanotubes were functionalized by treatment in nitric acid and isopropyl alcohol. Changes in the morphology of multi-walled carbon nanotubes during liquid-phase functionalization were investigated using Auger-electron microscopy. Samples of composite material on the basis of initial and functionalized carbon nanotubes and epoxy resin were prepared and the concentration dependence of electrical conductivity using the four-probe method was studied. The study reveals the effect of functionalization in various solutions on the electrophysical properties of the obtained carbon nanotubes/epoxy composites.

Preparation and Characterization of Purified Multi-Walled Carbon Nanotubes Filled Conductive Adhesive

2013 ◽  
Vol 341-342 ◽  
pp. 175-178
Author(s):  
Fan Zhang ◽  
Shu Hua Qi ◽  
Yi Zhang
Keyword(s):  
Carbon Nanotubes ◽  
Conductive Adhesives ◽  
Pressure Sensitive Adhesive ◽  
Electrically Conductive ◽  
Oxidation Treatment ◽  
Pressure Sensitive ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes ◽  
Xrd And Tem

In this paper, purified multi-walled carbon nanotubes (MWNTs) were obtained by acid treatment and oxidation treatment using the crude MWNTs, then purified MWNTs were filled into acrylate pressure-sensitive adhesive (PSA) to produce electrically conductive adhesives (ECAs). XRD and TEM results showed that the impurities were greatly eliminated after purification treatment. The electrical conductivity of the ECAs increased gradually as the content of the purified MWNTs increased. When the content of the purified MWNTs is 4.0vol%, the properties of ECAs are optimum.

scholarly journals Enhancement of Electrical Conductivity of Aluminum-Based Nanocomposite Produced by Spark Plasma Sintering

Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1150
Author(s):  
Nicolás A. Ulloa-Castillo ◽  
Roberto Hernández-Maya ◽  
Jorge Islas-Urbano ◽  
Oscar Martínez-Romero ◽  
Emmanuel Segura-Cárdenas ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Spark Plasma Sintering ◽  
Experimental Tests ◽  
Powder Morphology ◽  
Plasma Sintering ◽  
Multi Walled Carbon Nanotubes ◽  
Spark Plasma ◽  
Ball Milling Technique ◽  
Walled Carbon Nanotubes

This article focuses on exploring how the electrical conductivity and densification properties of metallic samples made from aluminum (Al) powders reinforced with 0.5 wt % concentration of multi-walled carbon nanotubes (MWCNTs) and consolidated through spark plasma sintering (SPS) process are affected by the carbon nanotubes dispersion and the Al particles morphology. Experimental characterization tests performed by scanning electron microscopy (SEM) and by energy dispersive spectroscopy (EDS) show that the MWCNTs were uniformly ball-milled and dispersed in the Al surface particles, and undesirable phases were not observed in X-ray diffraction measurements. Furthermore, high densification parts and an improvement of about 40% in the electrical conductivity values were confirmed via experimental tests performed on the produced sintered samples. These results elucidate that modifying the powder morphology using the ball-milling technique to bond carbon nanotubes into the Al surface particles aids the ability to obtain highly dense parts with increasing electrical conductivity properties.

scholarly journals Electrically Conductive Networks from Hybrids of Carbon Nanotubes and Graphene Created by Laser Radiation

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1875
Author(s):  
Alexander Yu. Gerasimenko ◽  
Artem V. Kuksin ◽  
Yury P. Shaman ◽  
Evgeny P. Kitsyuk ◽  
Yulia O. Fedorova ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Laser Irradiation ◽  
Flexible Electronics ◽  
Threshold Energy ◽  
Wavelength Region ◽  
Hybrid Nanostructures ◽  
Graphene Sheets ◽  
Electrically Conductive ◽  
Walled Carbon Nanotubes

A technology for the formation of electrically conductive nanostructures from single-walled carbon nanotubes (SWCNT), multi-walled carbon nanotubes (MWCNT), and their hybrids with reduced graphene oxide (rGO) on Si substrate has been developed. Under the action of single pulses of laser irradiation, nanowelding of SWCNT and MWCNT nanotubes with graphene sheets was obtained. Dependences of electromagnetic wave absorption by films of short and long nanotubes with subnanometer and nanometer diameters on wavelength are calculated. It was determined from dependences that absorption maxima of various types of nanotubes are in the wavelength region of about 266 nm. It was found that contact between nanotube and graphene was formed in time up to 400 fs. Formation of networks of SWCNT/MWCNT and their hybrids with rGO at threshold energy densities of 0.3/0.5 J/cm2 is shown. With an increase in energy density above the threshold value, formation of amorphous carbon nanoinclusions on the surface of nanotubes was demonstrated. For all films, except the MWCNT film, an increase in defectiveness after laser irradiation was obtained, which is associated with appearance of C–C bonds with neighboring nanotubes or graphene sheets. CNTs played the role of bridges connecting graphene sheets. Laser-synthesized hybrid nanostructures demonstrated the highest hardness compared to pure nanotubes. Maximum hardness (52.7 GPa) was obtained for MWCNT/rGO topology. Regularity of an increase in electrical conductivity of nanostructures after laser irradiation has been established for films made of all nanomaterials. Hybrid structures of nanotubes and graphene sheets have the highest electrical conductivity compared to networks of pure nanotubes. Maximum electrical conductivity was obtained for MWCNT/rGO hybrid structure (~22.6 kS/m). Networks of nanotubes and CNT/rGO hybrids can be used to form strong electrically conductive interconnections in nanoelectronics, as well as to create components for flexible electronics and bioelectronics, including intelligent wearable devices (IWDs).

scholarly journals Synthesis, Characterization and Study of DC Electrical Conductivity of Poly[MWCNT/Imidoselenium] Composite

2019 ◽  
Author(s):  
Abeer O. Obeid ◽  
Fatma Al-Yusufy ◽  
Sama A Al-Aghbari ◽  
omar alshujaa ◽  
Yassin Gaber ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Selenium Dioxide ◽  
Chemical Functionalization ◽  
Dc Electrical Conductivity ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

<p>The chemical functionalization of amino multi-walled carbon nanotubes (MWCNT-NH<sub>2</sub>) by selenium dioxide (SeO<sub>2</sub>) was used to produce Poly [MWCNT/Imidoselenium] composite. The prepared poly-composite was characterized by FTIR, SEM, TEM, XRD, UV, DSC and TGA. The DC electrical conductivity of poly-composite was 4.3×10<sup>-4</sup> S/cm due to the interaction between the nanotubes. </p>

The effect of functionalization on structure and electrical conductivity of multi-walled carbon nanotubes

2008 ◽  
Vol 10 (S1) ◽  
pp. 77-88 ◽  
Author(s):  
Cher Hon Lau ◽  
Raoul Cervini ◽  
Stephen R. Clarke ◽  
Milena Ginic Markovic ◽  
Janis G. Matisons ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Multi Walled Carbon Nanotubes ◽  
Walled Carbon Nanotubes

A Comparison of the Effect of Hydroxyl Modified Carbon Nanotubes and Graphenes on the Electrical and Mechanical Properties of Their Polyurethane Composites

2012 ◽  
Vol 622-623 ◽  
pp. 781-786
Author(s):  
Sarojini Swain ◽  
Subhendu Bhattacharya ◽  
Ram Avatar Sharma ◽  
Lokesh Chaudhari
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Filler Content ◽  
Graphene Nanosheets ◽  
Three Dimensional ◽  
Conduction System ◽  
Multi Walled Carbon Nanotubes ◽  
Electrical Conduction Mechanisms ◽  
Modified Carbon Nanotubes ◽  
Walled Carbon Nanotubes

Hydroxyl modified multi-walled carbon nanotubes (OH-MWCNT)/ polyurethane (PU) and graphene nanosheets (GNS)/PU composites were prepared by dispersing the OH-MWCNT and GNS at different wt % in to the PU matrix. It was found that the electrical percolation threshold of the GNS/PU composite is much higher compared to that of OH-MWCNT/PU and also the electrical conductivity of the OH-MWCNT/PU composite is higher than the GNS/PU composite in the same level of filler content. This may be due to the two composites having different electrical conduction mechanisms: The OH-MWCNT/PU composite represents a three dimensional conduction system while, the GNS/PU composite represents a two dimensional conduction system. The improvement in the electrical conductivity with the incorporation of GNS as a filler in the composite is far lower than what theoretically expected. It is also observed that the tensile strength of the OH-MWCNT/PU composite is higher compared to the GNS/PU in the same level filler content.

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