scholarly journals Fractionation Trends and Variability of Rare Earth Elements and Selected Critical Metals in Pelagic Sediment from Abyssal Basin of NE Pacific (Clarion-Clipperton Fracture Zone)

Minerals ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 320 ◽  
Author(s):  
Dominik Zawadzki ◽  
Łukasz Maciąg ◽  
Tomasz Abramowski ◽  
Kevin McCartney

The geochemical and mineralogical characteristics of pelagic sediments collected from the Interoceanmetal Joint Organization (IOM) claim area, located in the eastern part of the Clarion-Clipperton Fracture Zone (CCFZ; eastern tropical Pacific), are described in this paper. The concentrations of rare earth elements (REE), as well as other selected critical elements contained in 135 sediment samples of siliceous clayey silts, are presented. The vertical and spatial variabilities of elements, with particular emphasis on REE as well as metals of the highest economic interest such as Cu, Ni, and Co, are detailed. The applied methods include grain size analysis by laser diffraction, geochemistry examination using ICP-MS, XRF, AAS, and CNS spectrometry, and XRD analysis of mineral composition (Rietveld method). Additionally, statistical methods such as factor analysis (FA) and principal components analysis (PCA) were applied to the results. Finally, a series of maps was prepared by geostatistical methods (universal kriging). Grain size analysis showed poor sorting of the examined fine-grained silts. ICP-MS indicated that total REE contents varied from 200 to 577 ppm, with a mean of 285 ppm, which is generally low. The contents of critical metals such as Cu, Ni, and Co were also low to moderate, apart from some individual sampling stations where total contents were 0.15% or more. Metal composition in sediments was dominated by Cu, Ni, and Zn. A mineral composition analysis revealed the dominance of amorphous biogenic opaline silica (27–58%), which were mostly remnants of diatoms, radiolarians, and sponges associated with clay minerals (23% to 48%), mostly Fe-smectite and illite, with mixed-layered illite/smectite. The high abundance of diagenetic barite crystals found in SEM−EDX observations explains the high content of Ba (up to 2.4%). The sediments showed complex lateral and horizontal fractionation trends for REE and critical metals, caused mostly by clay components, early diagenetic processes, admixtures of allogenic detrital minerals, or scavenging by micronodules.

2020 ◽  
Vol 8 (4) ◽  
pp. T981-T990
Author(s):  
Haijun Gao ◽  
Delu Li ◽  
Dingming Dong ◽  
Hongjun Jing ◽  
Hao Tang

The Chang 7 oil layer from the upper Triassic Yanchang Formation is an important layer for hydrocarbon exploration. Most studies on the Chang 7 oil layer have focused on the source rocks, while research on the sandstone is still inadequate, especially on the petrography and geochemical characteristics. Using seven sandstone samples of the Chang 7 oil layer in the Yanhe profile, the grain-size analysis, major elements, trace elements, and rare earth elements were tested. The results find that the sandstone of fine-grained sediments of the Chang 7 oil layer is dominated by arkose with a minor number of lithic arkose. The range of grain size (Mz) is from 2.72 to 3.92 Φ, and the C value and M value of the sandstone samples suggest characteristics of turbidity deposition. The Al/Si ratios of all of the samples imply high clay mineral content. The results of trace and rare earth elements demonstrate the reducing condition, freshwater, and cold and dry weather. The provenance of the sandstone samples is mainly from island arc acidic volcanic rock, and the type of provenance is mixed with sedimentary rock, granite, and alkaline basalt. The tectonic background is continental island arc. This study provides a systematic geologic foundation for the formation of sandstone of Chang 7 oil layer in Ordos Basin.


Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 28
Author(s):  
Srećko Bevandić ◽  
Rosie Blannin ◽  
Jacqueline Vander Auwera ◽  
Nicolas Delmelle ◽  
David Caterina ◽  
...  

Mine wastes and tailings derived from historical processing may contain significant contents of valuable metals due to processing being less efficient in the past. The Plombières tailings pond in eastern Belgium was selected as a case study to determine mineralogical and geochemical characteristics of the different mine waste materials found at the site. Four types of material were classified: soil, metallurgical waste, brown tailings and yellow tailings. The distribution of the mine wastes was investigated with drill holes, pit-holes and geophysical methods. Samples of the materials were assessed with grain size analysis, and mineralogical and geochemical techniques. The mine wastes dominantly consist of SiO2, Al2O3 and Fe2O3. The cover material, comprising soil and metallurgical waste is highly heterogeneous in terms of mineralogy, geochemistry and grain size. The metallurgical waste has a high concentration of metals (Zn: 0.1 to 24 wt.% and Pb: 0.1 to 10.1 wt.%). In the tailings materials, Pb and Zn vary from 10 ppm to 8.5 wt.% and from 51 ppm to 4 wt.%, respectively. The mining wastes comprises mainly quartz, amorphous phases and phyllosilicates, with minor contents of Fe-oxide and Pb- and Zn-bearing minerals. Based on the mineralogical and geochemical properties, the different potential applications of the four waste material types were determined. Additionally, the theoretical economic potential of Pb and Zn in the mine wastes was estimated.


2021 ◽  
Vol 11 (6) ◽  
pp. 2799
Author(s):  
Yanping Chen ◽  
Wenzhe Lyu ◽  
Tengfei Fu ◽  
Yan Li ◽  
Liang Yi

The Huanghe River (Yellow River) is the most sediment laden river system in the world, and many efforts have been conducted to understand modern deltaic evolution in response to anthropological impacts. However, the natural background and its linkage to climatic changes are less documented in previous studies. In this work, we studied the sediments of core YDZ–3 and marine surface samples by grain-size analysis to retrieve Holocene dynamics of the Huanghe River delta in detail. The main findings are as follows: The mean value of sediment grain size of the studied core is 5.5 ± 0.9 Φ, and silt and sand contents are 5.2 ± 2.3% and 8.2 ± 5.3%, respectively, while the variance of clay particles is relatively large with an average value of 86.4 ± 8.5%. All grain-size data can be mathematically partitioned by a Weibull-based function formula, and three subgroups were identified with modal sizes of 61.1 ± 28.9 μm, 30.0 ± 23.9 μm, and 2.8 ± 1.6 μm, respectively. There are eight intervals with abrupt changes in modal size of core YDZ–3, which can be correlated to paleo-superlobe migration of the Huanghe River in the Holocene. Based on these observations, the presence of seven superlobes in the history are confirmed for the first time and their ages are well constrained in this study, including Paleo-Superlobes Lijin (6400–5280 yr BP), Huanghua (4480–4190 yr BP), Jugezhuang (3880–3660 yr BP), Shajinzi (3070–2870 yr BP), Nigu (2780–2360 yr BP), Qikou (2140–2000 yr BP), and Kenli (1940–1780 and 1700–1650 yr BP). By tuning geomorphological events to a sedimentary proxy derived from core YDZ–3 and comparing to various paleoenvironmental changes, we proposed that winter climate dominated Holocene shifts of the Huanghe River delta on millennial timescales, while summer monsoons controlled deltaic evolution on centennial timescales.


1996 ◽  
Vol 2 (1) ◽  
pp. 1-15 ◽  
Author(s):  
Andrew J. C. Hogg ◽  
Alan W. Mitchell ◽  
Susan Young

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