scholarly journals Electronic Currents Induced by Optical Fields and Rotatory Power Density in Chiral Molecules

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4195
Author(s):  
Francesco Ferdinando Summa ◽  
Guglielmo Monaco ◽  
Riccardo Zanasi ◽  
Stefano Pelloni ◽  
Paolo Lazzeretti

The electric dipole–magnetic dipole polarizability tensor κ′, introduced to interpret the optical activity of chiral molecules, has been expressed in terms of a series of density functions kαβ′, which can be integrated all over the three-dimensional space to evaluate components καβ′ and trace καα′. A computational approach to kαβ′, based on frequency-dependent electronic current densities induced by monochromatic light shining on a probe molecule, has been developed. The dependence of kαβ′ on the origin of the coordinate system has been investigated in connection with the corresponding change of καβ′. It is shown that only the trace kαα′ of the density function defined via dynamic current density evaluated using the continuous translation of the origin of the coordinate system is invariant of the origin. Accordingly, this function is recommended as a tool that is quite useful for determining the molecular domains that determine optical activity to a major extent. A series of computations on the hydrogen peroxide molecule, for a number of different HO–OH dihedral angles, is shown to provide a pictorial documentation of the proposed method.

Free-flying houseflies have been filmed simultaneously from two sides. The orientation of the flies’ body axes in three-dimensional space can be seen on the films. A method is presented for the reconstruction of the flies’ movements in a fly-centred coordinate system, relative to an external coordinate system and relative to the airstream. The flies are regarded as three-dimensionally rigid bodies. They move with respect to the six degrees of freedom they thus possess. The analysis of the organization of the flight motor from the kinematic data leads to the following conclusions: the sideways movements can, at least qualitatively, be explained by taking into account the sideways forces resulting from rolling the body about the long axis and the influence of inertia. Thus, the force vector generated by the flight motor is most probably located in the fly’s midsagittal plane. The direction of this vector can be varied by the fly in a restricted range only. In contrast, the direction of the torque vector can be freely adjusted by the fly. No coupling between the motor force and the torques is indicated. Changes of flight direction may be explained by changes in the orientation of the body axes: straight flight at an angle of sideslip differing from zero is due to rolling. Sideways motion during the banked turns as well as the decrease of translation velocity observed in curves are a consequence of the inertial forces and rolling. The results are discussed with reference to studies about the aerodynamic performance of insects and the constraints for aerial pursuit.


2012 ◽  
Vol 246-247 ◽  
pp. 22-27
Author(s):  
Zheng Zhang ◽  
Xiao Wei Liu ◽  
Guang You Yang

A kind of calculation model of 3D space transformation is introduced, which is applicable to the monocular vision of robot manipulator, and the three-dimensional space plane mapping problem of image plane to the actual horizontal plane of monocular vision has been solved. It transforms the imaging coordinate system of target in monocular vision into the world coordinate system of the manipulator, so as to calculate the relative position of targets and the manipulator. The algorithm has better accuracy and reliability, which is proved by contrasting and testing the calculation result of object coordinate system transformed to the actual position coordinates to the sampling points in embedded platform.


2021 ◽  
pp. 1-24
Author(s):  
María da Fonseca ◽  
Inés Samengo

In trichromats, color vision entails the projection of an infinite-dimensional space (the one containing all possible electromagnetic power spectra) onto the three-dimensional space that modulates the activity of the three types of cones. This drastic reduction in dimensionality gives rise to metamerism, that is, the perceptual chromatic equivalence between two different light spectra. The classes of equivalence of metamerism are revealed by color-matching experiments in which observers adjust the intensity of three monochromatic light beams of three preset wavelengths (the primaries) to produce a mixture that is perceptually equal to a given monochromatic target stimulus. Here we use the linear relation between the color matching functions and the absorption probabilities of each type of cone to find particularly useful triplets of primaries. As a second goal, we also derive an analytical description of the trial-to-trial variability and the correlations of color matching functions stemming from Poissonian noise in photon capture. We analyze how the statistical properties of the responses to color-matching experiments vary with the retinal composition and the wavelengths of peak absorption probability, and compare them with experimental data on subject-to-subject variability obtained previously.


2019 ◽  
Vol 20 (1-2) ◽  
pp. 234-240
Author(s):  
Jakub Grabiński ◽  
Konrad Waluś

As part of the work, a measuring system is presented that allows collecting and recording vehicle motion parameters. To build the system, an inertial navigation module was used, consisting of two-axis accelerometers and gyroscopes made in MEMS technology. The tests were carried out and calculation methods were developed to allow the collected data to be referenced, to a point in the three-dimensional space, in order to determine the trajectory of the vehicle's movement. The built-in measuring system uses three types of sensors: accelerometer, gyroscope, magnetometer. Each of these sensors allows the measurement of the physical size in three orthogonal axes of the Cartesian coordinate system. In addition, the work uses a satellite navigation module (GPS), as a reference on the "macro" scale (coordinate system related to the center of the globe with a radius of about 6371 km) for the inertial updating module (INS / IMU), enabling accurate measurement in the "micro" scale (the coordinate system associated with the starting point of the traffic for the route, the length of which does not exceed several hundred meters). The article presents an overview of available measuring sensors with special consideration of the parameters of selected sensors and errors introduced into the measurement system.


1976 ◽  
Vol 16 (06) ◽  
pp. 327-336 ◽  
Author(s):  
N.P. Callas

Callas, N.P., Colorado School ofMines, Golden, Colo. Abstract Before the introduction of the radius of curvaturemethod in 1968, departures were computed alongstraight-line segments with the so-called tangentialmethod. Since 1968 many variations of the curvaturemethod have been developed. This paper extendsavailable departure methods to a helical methodthat uses torsional as well as curvature informationin the raw directional-survey data. Fortran routineshave been written implementing this method. Thealgorithms presented here were used to implementthese routines. Introduction The raw directional-survey data collected at adrilling site consists of measurements of the driftdeclination angles from the vertical direction andthe drift directions of the borehole in the horizontalplane, using a plumb and compass (or gyro) atselected measurement stations. Further, the amountof drilling pipe in the hole gives the accumulatedlength of the borehole at each station. Translatedgeometrically, this information represents acollection of unit vectors, where (Ui, i = 1, 2,..., n, in three-dimensional space; each datumindicates the direction of the borehole at a measuredposition, where n represents the total number of station points. The direction vectors are represented as (1) The vector components or so-called direction cosinesare given byCx = COS beta sin delta, Cy = sin beta sin delta, andCz = cos delta....................(2) where the angle beta is the drift direction measuredfrom due east in a counterclockwise direction anddelta is the drift declination angle measured from thedownward vertical direction. From these data thecourse of the borehole is to be integrated asaccurately as possible to obtain the horizontal andvertical departures of intermediate or bottom-hole positions.If station readings are taken sufficiently closetogether, it is evident that even the tangentialapproach for computing directional surveys wouldbe satisfactory to give acceptable departure results.Since the economics of the situation place a limiton the amount of data that may be collected, it isof interest to consider mathematical models for theborehole that account for its curvature and/ortorsional properties, thus better simulating its trueshape.Wilson's radius of curvature method provided thefirst published example of such a curvature model.Since 1968 many variations of this basic methodhave been developed and used. In 1973, Zarembadeveloped an explicit circular arcs method thatpieces together circular arcs that fit the raw dataat station points. CIRCULAR ARCS MODEL-> -> ->Let the set U1, U2, ...., Un represent the surveydata as a collection of consecutive boreholedirection vectors. Suppose that we know the x, y, and z coordinates of the kth station point, Pk, instandard rectangular coordinates, where the index kassumes any of the values k=1, 2,..., n - 1. Theorigin of the coordinate system may convenientlybe taken as the starting position of the borehole atground level. Further, we shall consider that thez axis of the coordinate system points straightdown, so that the z values of departures will besynonymous with the vertical departure of theborehole.The first objective of this paper is to modelthe kth segment of the borehole with a circulararc segment spanning the points Pk and Pk+ 1 insuch a manner that the direction vectors-> -> Uk and Uk + 1 are tangent to the circular arc atits respective end-points. The existence of sucha space arc is quite clear. To compute thecoordinates of the (k + 1) station point, Pk + 1, a rigid motion, three-dimensional transformation, T, will be performed on this arc to place it in acanonical or vertical frame of reference such that-> the vector Uk is transformed into the vector (0, 0,1). (See Appendix A for T's functional representation. SPEJ P. 327^


2016 ◽  
Vol 2 (10) ◽  
pp. e1601306 ◽  
Author(s):  
Nora Tischler ◽  
Mario Krenn ◽  
Robert Fickler ◽  
Xavier Vidal ◽  
Anton Zeilinger ◽  
...  

The phenomenon of molecular optical activity manifests itself as the rotation of the plane of linear polarization when light passes through chiral media. Measurements of optical activity and its wavelength dependence, that is, optical rotatory dispersion, can reveal information about intricate properties of molecules, such as the three-dimensional arrangement of atoms comprising a molecule. Given a limited probe power, quantum metrology offers the possibility of outperforming classical measurements. This has particular appeal when samples may be damaged by high power, which is a potential concern for chiroptical studies. We present the first experiment in which multiwavelength polarization-entangled photon pairs are used to measure the optical activity and optical rotatory dispersion exhibited by a solution of chiral molecules. Our work paves the way for quantum-enhanced measurements of chirality, with potential applications in chemistry, biology, materials science, and the pharmaceutical industry. The scheme that we use for probing wavelength dependence not only allows one to surpass the information extracted per photon in a classical measurement but also can be used for more general differential measurements.


Author(s):  
Lanfeng Zhou ◽  
Ling Li

Traditional Hough circle detection algorithm usually determines the center and radius of a circle by mapping points in cartesian coordinate system to polar coordinate system. Since it accumulates in the three-dimensional space, it requires more calculation consumption. In this paper, we solve the problem of high time complexity of Hough algorithm in judging circle radius and circle center from two aspects of circle angle and circle radius according to the geometric features of quasi-circles. A large number of experiments show that, compared with the traditional algorithm, this algorithm can not only identify quasi-circles, but also improve the detection success rate of circles by about 10%, with efficient running speed, and obtain good experimental results in the detection of craters.


2017 ◽  
Vol 23 (2) ◽  
pp. 273-279 ◽  
Author(s):  
Vyacheslav Shulunov

Purpose This study aims to give a description of conformal transformation Cartesian coordinates into spiral coordinates using the example of roll powder sintering (RPS) additive manufacturing (AM) technology. RPS has several advantages over dominant AM processes currently available in the market. RPS allows accomplishing designs, which are impossible, very expensive and difficult to create by other methods. The technology requires slicing a 3D object with spiral scanning. Design/methodology/approach The paper describes the possibility of accurate 3D object transformation into a flat ribbon by spiral coordinate system. Parameters of conformal transformation are calculated according to the equation of equivalence between (x, y, z) and (l, z) coordinates. Findings As numerical examples show, it is possible to convert three-dimensional space to two-dimensional one if you know the thickness of the spatial layer. The proposed methodology can be used for the transformation of 3D computer-aided design models into 2D strip models. Originality/value In this paper, the author proposes a method of converting Cartesian coordinates into spiral coordinates. Conformal transformation of three-dimensional space to two-dimensional one by use of spiral coordinate system is demonstrated by RPS AM technology, which allows to produce objects with high accuracy.


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