scholarly journals Supramolecular Aggregates: Hardness Plus Softness

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4233
Author(s):  
Lia Queiroz do Amaral

The properties of supramolecular aggregates cross several disciplines, embracing the sciences of nature and joining theory, experiment, and application. There are few articles centering on the problems of interdisciplinarity, and this paper gives an alternative approach, starting with scientific divulgation, bringing concepts from their origin, to facilitate the access of young scientists to the scientific content. Didactic examples are taken from the experience of the author in changing directions of research due to several circumstances of life (including maternity), starting from the view of a rigorous student of physics and evolving to several subjects in chemistry. The scientific part starts with concepts related to nuclear interactions, using the technique of neutron scattering in reactors, and evolves to research in molecular physics. Finally, it arrives at the academic context, with research in condensed matter physics, with X-ray and other techniques, starting with detergents forming nematic lyotropic liquid crystals and the phase transition sequence of isotropic to nematics to hexagonal. The scientific subjects evolved to biological and bio-inspired liquid crystals, including DNA and also specific lipids and phospholipids in biomimetic membranes. Special attention is given to the question of distribution of matter in these complex systems and the non-trivial connections between biochemistry, structures, auto-aggregation, and biology.

2012 ◽  
Vol 90 (12) ◽  
pp. 1056-1062 ◽  
Author(s):  
Joseph K.-H. Hui ◽  
Jian Jiang ◽  
Mark J. MacLachlan

Schiff-base macrocycles 1, which have a crown ether-like interior, form ionic nematic lyotropic liquid crystals in various organic solvents when functionalized with long alkoxy substituents and complexed to diverse ammonium and alkali metal salts. From X-ray diffraction and transmission electron microscopy studies, and by comparison with the organization of macrocycles functionalized with shorter chains, these macrocycles assemble into lyotropic liquid crystals where the macrocycles are stacked and the cation is included in their interiors.


1991 ◽  
Vol 113 (15) ◽  
pp. 5809-5816 ◽  
Author(s):  
Stefania Bonazzi ◽  
Massimo Capobianco ◽  
Monica Mirande De Morais ◽  
Anna Garbesi ◽  
Giovanni Gottarelli ◽  
...  

1979 ◽  
Vol 57 (9) ◽  
pp. 1108-1110 ◽  
Author(s):  
Paulo C. Isolani ◽  
Leonard W. Reeves ◽  
J. Atílio Vanin

Depolarized components of laser light scattering patterns have been investigated for type II lyotropic liquid crystals. These patterns are characterized by intensity maxima and minima with constant angular separation. By using the Bragg equation, a set of distances typical for lamellar arrays can be derived. Two possible models are proposed to explain the results: the first is that the distances are related to the average diameter of lyomesomorphic micelles not accessible to low angle X-ray studies and the second model is a repeating hyperstructure of micellar microdomains.


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