scholarly journals Self-Diffusion in Simple Liquids as a Random Walk Process

Molecules ◽  
2021 ◽  
Vol 26 (24) ◽  
pp. 7499
Author(s):  
Sergey A. Khrapak

It is demonstrated that self-diffusion in dense liquids can be considered a random walk process; its characteristic length and time scales are identified. This represents an alternative to the often assumed hopping mechanism of diffusion in the liquid state. The approach is illustrated using the one-component plasma model.

2002 ◽  
Vol 29 (9) ◽  
pp. 1295-1300 ◽  
Author(s):  
J.A. Vasut ◽  
M.D. Lennek ◽  
T.W. Hyde

2020 ◽  
Vol 10 (14) ◽  
pp. 4968
Author(s):  
Cheng Ke ◽  
Yanning Zheng ◽  
Shengli Wang

With the combination of multi-GNSS data, the precise-point positioning (PPP) technique can improve its accuracy, availability and reliability: Inter-system bias (ISB) is the non-negligible parameter in multi-GNSS PPP. To further enhance the performance of multi-GNSS PPP, it is crucial to analyze the characterization of inter system biases (ISBs) and model them properly. In this contribution, we comprehensively investigate the characterization of ISBs between global positioning system (GPS) and BeiDou navigation satellite system (BDS) in different situations. (1) We estimate ISB by using different precise products from the Center for Orbit Determination (CODE), Deutsches GeoForschungsZentrum (GFZ) and Wuhan University (WHU). The results indicate that the one-day estimates of ISB are stable when using CODE and WHU products, whereas the estimates based on GFZ products vary remarkably. As for the three-day time series of ISB, a sudden jump exists between two adjacent days, which is due to the change of satellite clock datum; (2) We investigate the ISB characterization affected by the ambient environments of the receivers. The result shows that the ISBs estimated from receivers (and antennas) with same type are still inconsistent, which indicates that the ambient environment, probably the temperature, influences the ISB characterization as well, since the receivers are in different areas; (3) We analyze the ISB characterization affected by receiver and antenna type with the same ambient environment. To ensure the same ambient environment, the ultra-short baselines were applied to investigate the ISB characterization affected by the receiver and antenna type. With the insights into ISB characterizations, we carry out combined GPS and BDS PPP with modeling the ISB as time constant, random walk process and white noise. The results suggest that the random walk process outperforms in most cases, since it strengthens the model to some extend and, at the same time, considers the variation of ISBs.


Author(s):  
Nicola Molinari ◽  
Jonathan P. Mailoa ◽  
Boris Kozinsky

We show that strong cation-anion interactions in a wide range of lithium-salt/ionic liquid mixtures result in a negative lithium transference number, using molecular dynamics simulations and rigorous concentrated solution theory. This behavior fundamentally deviates from the one obtained using self-diffusion coefficient analysis and agrees well with experimental electrophoretic NMR measurements, which accounts for ion correlations. We extend these findings to several ionic liquid compositions. We investigate the degree of spatial ionic coordination employing single-linkage cluster analysis, unveiling asymmetrical anion-cation clusters. Additionally, we formulate a way to compute the effective lithium charge that corresponds to and agrees well with electrophoretic measurements and show that lithium effectively carries a negative charge in a remarkably wide range of chemistries and concentrations. The generality of our observation has significant implications for the energy storage community, emphasizing the need to reconsider the potential of these systems as next generation battery electrolytes.<br>


2021 ◽  
Vol 11 (11) ◽  
pp. 5070
Author(s):  
Xesús Prieto-Blanco ◽  
Carlos Montero-Orille

In the last few years, some advances have been made in the theoretical modelling of ion exchange processes in glass. On the one hand, the equations that describe the evolution of the cation concentration were rewritten in a more rigorous manner. This was made into two theoretical frameworks. In the first one, the self-diffusion coefficients were assumed to be constant, whereas, in the second one, a more realistic cation behaviour was considered by taking into account the so-called mixed ion effect. Along with these equations, the boundary conditions for the usual ion exchange processes from molten salts, silver and copper films and metallic cathodes were accordingly established. On the other hand, the modelling of some ion exchange processes that have attracted a great deal of attention in recent years, including glass poling, electro-diffusion of multivalent metals and the formation/dissolution of silver nanoparticles, has been addressed. In such processes, the usual approximations that are made in ion exchange modelling are not always valid. An overview of the progress made and the remaining challenges in the modelling of these unique processes is provided at the end of this review.


2021 ◽  
Vol 28 (6) ◽  
pp. 1679-1691
Author(s):  
Ali Bahari ◽  
Aref Sadeghi-Nik ◽  
Elena Cerro-Prada ◽  
Adel Sadeghi-Nik ◽  
Mandana Roodbari ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document