scholarly journals V-Substituted ZnIn2S4: A (Visible+NIR) Light-Active Photocatalyst

Photochem ◽  
2021 ◽  
Vol 1 (1) ◽  
pp. 1-9
Author(s):  
Raquel Lucena ◽  
José C. Conesa
Keyword(s):  
Photocatalytic Activity ◽  
Dft Calculations ◽  
Visible Light ◽  
H2 Generation ◽  
Nir Light ◽  
Visible Light Range ◽  
Visible Light Active ◽  
Photocatalytic H2 Generation ◽  
Photovoltaic Characteristics

ZnIn2S4 is known to be a visible light-active photocatalyst. In this work, it is shown that by substituting part of the In atoms with vanadium, the visible light range of photocatalytic activity of such material can be extended, using the so-called in-gap band scheme that has been shown to enhance photovoltaic characteristics. Characterization of this material using several techniques, complemented by DFT calculations, will support this statement. While here only the degradation of aqueous HCOOH in well-aerated conditions is discussed, the same material may be used, with an adequate sacrificial reagent, for photocatalytic H2 generation.

Synthesis and Characterization of C-N-Cl-Codoped TiO2 with Enhanced Visible Light Response

2011 ◽  
Vol 382 ◽  
pp. 431-434
Author(s):  
Long Hui Nie ◽  
Zheng Qing Huang ◽  
Wang Xi Zhang
Keyword(s):  
Photocatalytic Activity ◽  
Visible Light ◽  
Light Response ◽  
Synthesis And Characterization ◽  
Tio2 Photocatalyst ◽  
Simple Process ◽  
Codoped Tio2 ◽  
Visible Light Response ◽  
Visible Light Active

A novel visible-light-active C-N-Cl-codoped TiO2 photocatalyst was prepared by a simple process. The as-prepared sample was characterized by XRD, XPS, and UV-Vis. The analysis results showed that the as-synthesized sample was anatase and possessed a narrow bad gap of 2.4 eV after the doping of carbon, nitrogen and chlorine. An obvious absorption for visible light was observed in the range of 400~700 nm for C-N-Cl-codoped TiO2. By degrading of methyl orange (MO) solution under the visible light (l>420 nm) irradiation, the synthesized photocatalyst showed 5 times photocatalytic activity than that of P25.

scholarly journals Facile Preparation of Efficient WO3Photocatalysts Based on Surface Modification

2015 ◽  
Vol 2015 ◽  
pp. 1-7 ◽  
Author(s):  
Min Liu ◽  
Hongmei Li ◽  
Yangsu Zeng
Keyword(s):  
Photocatalytic Activity ◽  
Surface Modification ◽  
Visible Light ◽  
Photoelectron Spectroscopy ◽  
Impregnation Method ◽  
Light Spectra ◽  
Simple Strategy ◽  
Visible Light Active ◽  
Efficient Charge ◽  
Surface Modified

Tungsten trioxide (WO3) was surface modified with Cu(II) nanoclusters and titanium dioxide (TiO2) nanopowders by using a simple impregnation method followed by a physical combining method. The obtained nanocomposites were studied by scanning electron microscope, X-ray photoelectron spectroscopy spectra, UV-visible light spectra, and photoluminescence, respectively. Although the photocatalytic activity of WO3was negligible under visible light irradiation, the visible light photocatalytic activity of WO3was drastically enhanced by surface modification of Cu(II) nanoclusters and TiO2nanopowders. The enhanced photocatalytic activity is due to the efficient charge separation by TiO2and Cu(II) nanoclusters functioning as cocatalysts on the surface. Thus, this simple strategy provides a facile route to prepare efficient visible-light-active photocatalysts for practical application.

Quantum dots in photocatalytic applications: efficiently enhancing visible light photocatalytic activity by integrating CdO quantum dots as sensitizers

2017 ◽  
Vol 19 (36) ◽  
pp. 24915-24927 ◽  
Author(s):  
A. H. Reshak
Keyword(s):  
Quantum Dots ◽  
Photocatalytic Activity ◽  
Visible Light ◽  
Band Gap ◽  
Visible Light Irradiation ◽  
Photocatalytic Performance ◽  
Optical Band Gap ◽  
Visible Light Active ◽  
Photocatalytic Applications ◽  
Visible Light Photocatalytic

The amalgamation of a wide optical band gap photocatalyst with visible-light-active CdO quantum dots (QDs) as sensitizers is one of the most efficient ways to improve photocatalytic performance under visible light irradiation.

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