scholarly journals Crystallization Behavior and Properties of Glass Fiber Reinforced Polypropylene Composites

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1198 ◽  
Author(s):  
Yuming Wang ◽  
Lihong Cheng ◽  
Xiaoqian Cui ◽  
Weihong Guo

Glass fiber with different content and different kinds of compatibilizers were used to prepare glass fiber-reinforced polypropylene (GFRP) composites. β-nucleating agent with different content was used to prepare β-polypropylene (PP), after which the toughness, crystallization ability and heat resistance were all enhanced. Differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) showed that the crystallite degree and crystallization ability were all greatly improved and β-PP was in dominant position. At last, both β-nucleating agent and glass fiber were used to modify the PP composites (β-GFRP). The formation of β-form PP made the matrix softer, which was beneficial for energy absorption and enhancement of toughness. The tensile strength, flexural strength and flexural modulus were improved dramatically, which were attributed to the coeffect of framework structure of GF and β-form PP.

RSC Advances ◽  
2014 ◽  
Vol 4 (28) ◽  
pp. 14766-14776 ◽  
Author(s):  
Yan-Hui Chen ◽  
Zhang-Yong Huang ◽  
Zhong-Ming Li ◽  
Jian-Hua Tang ◽  
Benjamin S. Hsiao

Glass fiber reinforced isotactic polypropylene composites with specific skin–core structure demonstrate simultaneous improvement of strength and toughness.


2020 ◽  
Vol 21 (12) ◽  
pp. 2915-2926
Author(s):  
Aimin Zhang ◽  
Guoqun Zhao ◽  
Jialong Chai ◽  
Junji Hou ◽  
Chunxia Yang ◽  
...  

2020 ◽  
pp. 096739112096510
Author(s):  
Pan Wang ◽  
Qing Lin ◽  
Yaming Wang ◽  
Chuntai Liu ◽  
Changyu Shen

This work aims to perform a systematic investigation on the crystallization behavior and morphologies of carbon and glass fiber reinforced PEEK. The nonisothermal and isothermal crystallization behavior was investigated by differential scanning calorimetry (DSC). The resultant morphologies were assessed by wide angle X-ray diffraction (WAXD), small angle X-ray scattering (SAXS), and polarized optical microscopy (POM) to provide details on spherulitic level, crystalline structure at unit cell, and lamellar levels. It was found that the crystallization ability of carbon fiber filled PEEK was better than that of neat PEEK, while the behavior of glass fiber filled PEEK was in an opposite trend. The incorporation of carbon fiber (or glass fiber) led to a looser packing of the unit cell or a less crystal perfection of PEEK but did not change its crystal form as well as its long period of lamellae. The isothermal crystallization kinetics was analyzed by the Avrami model, suggesting that the crystallization mechanism of carbon fiber filled PEEK was different from that of neat PEEK and its glass fiber filled composites. Nevertheless, the POM results showed that fiber-induced transcrystallization in PEEK matrix was not evidenced for either carbon or glass fiber filled PEEK. Finally, the effect of carbon and glass fiber on the crystallization of PEEK matrix was discussed to some extent.


Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 463 ◽  
Author(s):  
Ke Chen ◽  
Mingyin Jia ◽  
Hua Sun ◽  
Ping Xue

In this paper, glass fiber-reinforced polyamide-6 (PA-6) composites with up to 70 wt% fiber contents were successfully manufactured using a pultrusion process, utilizing the anionic polymerization of caprolactam (a monomer of PA-6). A novel thermoplastic reaction injection pultrusion test line was developed with a specifically designed injection chamber to achieve complete impregnation of fiber bundles and high speed pultrusion. Process parameters like temperature of injection chamber, temperature of pultrusion die, and pultrusion speed were studied and optimized. The effects of die temperature on the crystallinity, melting point, and mechanical properties of the pultruded composites were also evaluated. The pultruded composites exhibited the highest flexural strength and flexural modulus, reaching 1061 MPa and 38,384 MPa, respectively. Then, effects of fiber contents on the density, heat distortion temperature, and mechanical properties of the composites were analyzed. The scanning electron microscope analysis showed the great interfacial adhesion between fibers and matrix at 180 °C, which greatly improved the mechanical properties of the composites. The thermoplastic reaction injection pultrusion in this paper provided an alternative for the preparation of thermoplastic composites with high fiber content.


e-Polymers ◽  
2017 ◽  
Vol 17 (2) ◽  
pp. 159-166 ◽  
Author(s):  
Hyeong Min Yoo ◽  
Dong-Jun Kwon ◽  
Joung-Man Park ◽  
Sang Hyuk Yum ◽  
Woo Il Lee

AbstractA lab scale structural reaction injection molding (S-RIM) piece of equipment was designed and used to fabricate glass fiber reinforced polydicyclopentadiene (p-DCPD) composites for three different fiber contents. In order to obtain information regarding the optimal process temperature (>80°C) and the curing time (<30 s), differential scanning calorimetry (DSC) was used to investigate the curing behavior of DCPD resin under isothermal conditions. Further, a norbornene-based silane treatment was used to improve the interfacial adhesion between the glass fibers and DCPD as confirmed by the micro-droplet pull-out test and scanning electron microscopy (SEM). Fabrication of glass fiber/p-DCPD composites with improved mechanical properties was carried out based on the optimized process conditions and surface treatment of glass fiber.


2017 ◽  
Vol 39 (12) ◽  
pp. 4322-4332 ◽  
Author(s):  
Pibulchai Kasemphaibulsuk ◽  
Marcel Holzner ◽  
Takashi Kuboki ◽  
Andrew Hrymak

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