scholarly journals Development of Trans-1,4-Polyisoprene Shape-Memory Polymer Composites Reinforced with Carbon Nanotubes Modified by Polydopamine

Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 110
Author(s):  
Chuang Zhang ◽  
Long Li ◽  
Yuanhang Xin ◽  
Jiaqi You ◽  
Jing Zhang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Thermal Stability ◽  
Shape Memory ◽  
Polymer Composites ◽  
Photoelectron Spectroscopy ◽  
Memory Performance ◽  
Shape Memory Polymer ◽  
Structure And Properties ◽  
X Ray

In this study, which was inspired by mussel-biomimetic bonding research, carbon nanotubes (CNTs) were interfacially modified with polydopamine (PDA) to prepare a novel nano-filler (CNTs@PDA). The structure and properties of the CNTs@PDA were studied using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The CNTs and the CNTs@PDA were used as nanofillers and melt-blended into trans-1,4 polyisoprene (TPI) to create shape-memory polymer composites. The thermal stability, mechanical properties, and shape-memory properties of the TPI/CNTs and TPI/CNTs@PDA composites were systematically studied. The results demonstrate that these modifications enhanced the interfacial interaction, thermal stability, and mechanical properties of TPI/CNTs@PDA composites while maintaining shape-memory performance.

Thermal stability of carbon nitride thin films

2001 ◽  
Vol 16 (11) ◽  
pp. 3188-3201 ◽  
Author(s):  
Niklas Hellgren ◽  
Nian Lin ◽  
Esteban Broitman ◽  
Virginie Serin ◽  
Stefano E. Grillo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Photoelectron Spectroscopy ◽  
Carbon Nitride ◽  
Amorphous Structure ◽  
X Ray ◽  
Bonding Structure ◽  
Higher Temperature ◽  
Electron Energy Loss ◽  
Thermal Stability Of

The thermal stability of carbon nitride films, deposited by reactive direct current magnetron sputtering in N2 discharge, was studied for postdeposition annealing temperatures TA up to 1000 °C. Films were grown at temperatures of 100 °C (amorphous structure) and 350 and 550 °C (fullerenelike structure) and were analyzed with respect to thickness, composition, microstructure, bonding structure, and mechanical properties as a function of TA and annealing time. All properties investigated were found to be stable for annealing up to 300 °C for long times (>48 h). For higher TA, nitrogen is lost from the films and graphitization takes place. At TA = 500 °C the graphitization process takes up to 48 h while at TA = 900 °C it takes less than 2 min. A comparison on the evolution of x-ray photoelectron spectroscopy, electron energy loss spectroscopy and Raman spectra during annealing shows that for TA > 800 °C, preferentially pyridinelike N and –C≡N is lost from the films, mainly in the form of molecular N2 and C2N2, while N substituted in graphite is preserved the longest in the structure. Films deposited at the higher temperature exhibit better thermal stability, but annealing at temperatures a few hundred degrees Celsius above the deposition temperature for long times is always detrimental for the mechanical properties of the films.

Multi-Scale Analysis of Thermo-Mechanical Properties of 2.5D Angle-Interlock Woven Shape Memory Polymer Composites

2018 ◽  
Vol 35 (4) ◽  
pp. 475-486
Author(s):  
H. Y. Sun ◽  
J. P. Gu ◽  
Y. Tang ◽  
Z. M. Xie
Keyword(s):  
Mechanical Properties ◽  
Shape Memory ◽  
Polymer Composites ◽  
Shape Memory Polymer ◽  
Small Strain ◽  
Constitutive Relationship ◽  
Nonlinear Fitting ◽  
Multi Scale ◽  
Hereditary Integral ◽  
Relationship Of

ABSTRACTA multi-scale strategy is employed in the paper to investigate the thermo-mechanical properties of 2.5D angle-interlock woven shape memory polymer composites (SMPCs). In the study, the mesoscopic model of 2.5D woven SMPCs and microscopic model of yarns are firstly developed. After that, the themo-viscoelastic constitutive relationship of the yarn is described in the form of hereditary integral and the parameters of relaxation moduli are obtained from nonlinear fitting of Prony series based on the results of finite element method (FEM). Based on the multi-scale models and the constitutive relationship, the effects of warp and weft arranged densities on viscoelastic properties of 2.5D woven SMPCs are studied in detail. Finally, the shape memory behavior along the warp direction in small strain region is also analyzed. The research in the paper lays a foundation for design and application of woven SMPCs in engineering.

Thermo-mechanical properties of shape memory polymer nanocomposites reinforced by carbon nanotubes

2019 ◽  
Vol 129 ◽  
pp. 80-98 ◽  
Author(s):  
Mohammad Kazem Hassanzadeh-Aghdam ◽  
Reza Ansari ◽  
Mohammad Javad Mahmoodi
Keyword(s):  
Mechanical Properties ◽  
Carbon Nanotubes ◽  
Shape Memory ◽  
Polymer Nanocomposites ◽  
Shape Memory Polymer

scholarly journals Analysis of Shape Memory Behavior and Mechanical Properties of Shape Memory Polymer Composites Using Thermal Conductive Fillers

Micromachines ◽  
2021 ◽  
Vol 12 (9) ◽  
pp. 1107
Author(s):  
Mijeong Kim ◽  
Seongeun Jang ◽  
Sungwoong Choi ◽  
Junghoon Yang ◽  
Jungpil Kim ◽  
...  
Keyword(s):  
Physical Properties ◽  
Shape Memory ◽  
Polymer Composites ◽  
Shape Recovery ◽  
Memory Performance ◽  
Shape Memory Polymer ◽  
Scanning Calorimetry ◽  
Wide Range ◽  
Nanocarbon Materials ◽  
Shape Memory Composite

Shape memory polymers (SMPs) are attracting attention for their use in wearable displays and biomedical materials due to their good biocompatibility and excellent moldability. SMPs also have the advantage of being lightweight with excellent shape recovery due to their low density. However, they have not yet been applied to a wide range of engineering fields because of their inferior physical properties as compared to those of shape memory alloys (SMAs). In this study, we attempt to find optimized shape memory polymer composites. We also investigate the shape memory performance and physical properties according to the filler type and amount of hardener. The shape memory composite was manufactured by adding nanocarbon materials of graphite and non-carbon additives of Cu. The shape-recovery mechanism was compared, according to the type and content of the filler. The shape fixation and recovery properties were analyzed, and the physical properties of the shape recovery composite were obtained through mechanical strength, thermal conductivity and differential scanning calorimetry analysis.

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