scholarly journals Special Issue: Green Sustainable Chemical Processes

Processes ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 1097
Author(s):  
Francisco J. Hernández Fernández ◽  
Antonia Pérez de los Ríos

Sustainable chemical process engineering results from applying the principles of green chemistry or sustainable chemistry to chemical process engineering [...]

2007 ◽  
Vol 79 (11) ◽  
pp. vi
Author(s):  
Pietro Tundo

This Special Topic issue on green chemistry pursues the same objectives as the Special Topic issue published in July 2000 and can be considered as its continuation. The articles have been selected (with great difficulty) from the massive and valuable scientific contributions on green chemistry by numerous professors and researchers during the 1st International IUPAC Conference on Green-Sustainable Chemistry held 10-15 September 2006 (for more details on the conference, see Chemistry International, Vol. 29, No. 3, 2007).The wide selection of topics was chosen with the intent to attract industrial researchers and representatives, colleagues from universities, as well as politicians and students who are interested in green and sustainable chemistry.The week-long conference was divided into five topics, each of which included several subtopics. This special issue covers the following topics discussed during the conference:benign syntheses routes (heterogeneous catalysis, new reagents, and catalysis for degradation of pollutants);benign process technology (microwave technology, photochemistry, new regulation devices);use of renewable sources (starch, cellulose, sugar, new detergents, biomass technology); andfuture green energy sources (hydrogen technology, fuel cell technology, biodiesel).All the articles reported in this issue point out a general need for novel green processes which comes from a new paradigm in process and product evaluation that must include environmental and health issues (see Chemistry International, Vol. 29, No. 5, 2007). In order to reach this objective, one priority should be to push for more basic research on chemical reactions related to green chemistry, where our knowledge is far from completion.In recent times, in fact, the difference between sustainable chemistry and green chemistry is becoming more evident. Sustainable chemistry envisages an industrial involvement and promotion with the aim of achieving fewer pollutant processes and more valuable products, maintaining, at the same time, profits. Whereas green chemistry is more innovative because it is not necessarily connected to profits, it involves fundamental aspects and does not aim automatically at an industrial process. There is a great need to create a new type of chemistry focused on a new production system and utilization of chemical derivatives, in order to prepare the younger generation to reach a greener future. Following this scenario, this special issue has been planned with the aim of extending the knowledge on green chemistry, not disregarding, however, the industrial interest.Nowadays, globalization (induced by many factors such as industrial development) pushes the chemistry community to adopt ethical issues. In this respect, green chemistry can achieve, better than sustainable chemistry, the approval of society by teaching students to be confident in science and at the same time by convincing people that it is possible to achieve technological development respecting and taking care of the environment in which we live. In order to realize these objectives, it is important that education and fundamental research are strictly connected, so that democracy and development can also grow and progress side by side. In my personal experience I think that the young generation is very interested and passionate about green chemistry. An example is dott. Fabio Aricò (postdoctorate fellow in my group) who helped me through the organization of the IUPAC conference and the preparation of this special issue with enthusiasm and passion.Pietro TundoConference Chairman


Author(s):  
Héctor Botero ◽  
Hernán Álvarez

This paper proposes a new composite observer capable of estimating the states and unknown (or changing) parameters of a chemical process, using some input-output measurements, the phenomenological based model and other available knowledge about the process. The proposed composite observer contains a classic observer (CO) to estimate the state variables, an observer-based estimator (OBE) to obtain the actual values of the unknown or changing parameters needed to tune the CO, and an asymptotic observer (AO) to estimate the states needed as input to the OBE. The proposed structure was applied to a CSTR model with three state variables. With the proposed structure, the concentration of reactants and other CSTR parameters can be estimated on-line if the reactor and jacket temperatures are known. The procedure for the design of the proposed structure is simple and guarantees observer convergence. In addition, the convergence speed of state and parameter estimation can be adjusted independently.


2021 ◽  
Author(s):  
Vânia G. Zuin ◽  
Ingo Eilks ◽  
Myriam Elschami ◽  
Klaus Kümmerer

Central role of future professionals in chemistry to promote alternatives towards sustainability.


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 1054
Author(s):  
Dimitri Lefebvre ◽  
Sébastien Leveneur

Chemistry plays an essential role in our modern society [...]


2021 ◽  
Vol 1 (1) ◽  
pp. 50-69
Author(s):  
Wilson Uzochukwu Eze ◽  
◽  
Reginald Umunakwe ◽  
Henry Chinedu Obasi ◽  
Michael Ifeanyichukwu Ugbaja ◽  
...  

<abstract> <p>The world is today faced with the problem of plastic waste pollution more than ever before. Global plastic production continues to accelerate, despite the fact that recycling rates are comparatively low, with only about 15% of the 400 million tonnes of plastic currently produced annually being recycled. Although recycling rates have been steadily growing over the last 30 years, the rate of global plastic production far outweighs this, meaning that more and more plastic is ending up in dump sites, landfills and finally into the environment, where it damages the ecosystem. Better end-of-life options for plastic waste are needed to help support current recycling efforts and turn the tide on plastic waste. A promising emerging technology is plastic pyrolysis; a chemical process that breaks plastics down into their raw materials. Key products are liquid resembling crude oil, which can be burned as fuel and other feedstock which can be used for so many new chemical processes, enabling a closed-loop process. The experimental results on the pyrolysis of thermoplastic polymers are discussed in this review with emphasis on single and mixed waste plastics pyrolysis liquid fuel.</p> </abstract>


2020 ◽  
Vol 10 (2) ◽  
pp. 2258-2271

Inceptions for chemical process automation are presented in this study. A chemical process demonstrated by neutralization reaction was designed, built, and tested experimentally towards evaluating automation and control algorithms through the Arduino Mega platform. The main objective parameter in this work was selected to be the product pH value, which was evaluated based on several scenarios that targeted various changes in direct and indirect effects. Two main branched ideas were investigated in this study; the first was dealt with the application of Arduino board in the automation of chemical process; the second was dedicated to studying integration of Arduino board in controlling the targeted pH parameter in the product side. Upon examining different automation scenarios, an algorithm was developed to approach the product quality of specific pH and temperature efficiently. The automation algorithm was further developed by integrating the process dynamics and control concepts towards speeding up the pH set point's reach. To make this happen, the pump's speed was corrected and tuned based on the feedback signal from the pH sensor. Consequently, the setpoint was reached in shorter periods, attaining considerable savings in time (≈ 35%). Based on the study outcomes, it is believed that Arduino open source is a challenging and promising low-cost platform, proved useful for mimicking control and automation of chemical processes.


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