Preparation and Characterization of Sn-β Zeolites by a Two-Step Postsynthesis Method and Their Catalytic Performance for Baeyer-Villiger Oxidation of Cyclohexanone

2013 ◽  
Vol 33 (5) ◽  
pp. 898-904 ◽  
Author(s):  
Zihua KANG ◽  
Hai’ou LIU ◽  
Xiongfu ZHANG
2016 ◽  
Vol 6 (8) ◽  
pp. 2787-2795 ◽  
Author(s):  
Ryoichi Otomo ◽  
Ryota Kosugi ◽  
Yuichi Kamiya ◽  
Takashi Tatsumi ◽  
Toshiyuki Yokoi

Sn-Beta modified with cations such as Li and Na showed better catalytic performance than non-modified Sn-Beta with “open” sites in Baeyer–Villiger oxidation.


ChemInform ◽  
2016 ◽  
Vol 47 (27) ◽  
Author(s):  
Prakash Chhattise ◽  
Kalpana Handore ◽  
Amit Horne ◽  
Kakasaheb Mohite ◽  
Atul Chaskar ◽  
...  

2008 ◽  
Vol 8 (1 & 2) ◽  
pp. 19
Author(s):  
Anton Purnomo ◽  
Susan Gellardo ◽  
Leonila Abella ◽  
Hirofumi Hinode ◽  
Chris Salim

Catalytic performance and characterization of Ni/CeO2/ZrO2 and commercial catalyst from Indonesia were investigated in steam reforming of methane. Ni/CeO2/ZrO2 catalyst was prepared using co-impregnation of cerium nitrate and nickel nitrate onto zirconia support material. BET, SEM, EDS, XRD, TPD, TG, and ICP analyses were employed for the characterization of the catalysts. Remarkable catalytic performance of Ni/CeO2/ZrO2 catalyst at 600oC operating temperature and atmospheric pressure of about 74.9% methane conversion was obtained compared to 55.9% using the commercial catalyst. In addition, the presence of cerium in Ni/CeO2/ZrO2 was effective in improving the stability and resistance to coke formation. Less carbon formation was confirmed from the thermo-gravimetric analysis. These results showed that the prepared catalyst is promising in the industrial application which can be used at lower operation temperature for energy saving.


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