Preparation and Characterization of BaTiO3-BaAl2O4-Al2O3 Composite Support and Catalytic Performance of Its Nickel-Based Catalyst for CO2 Reforming of Methane

2013 ◽  
Vol 33 (3) ◽  
pp. 563-569
Author(s):  
Quanhong HU ◽  
Xiancai LI ◽  
Aijun YANG ◽  
Chunyan YANG
ChemInform ◽  
2016 ◽  
Vol 47 (27) ◽  
Author(s):  
Prakash Chhattise ◽  
Kalpana Handore ◽  
Amit Horne ◽  
Kakasaheb Mohite ◽  
Atul Chaskar ◽  
...  

2008 ◽  
Vol 8 (1 & 2) ◽  
pp. 19
Author(s):  
Anton Purnomo ◽  
Susan Gellardo ◽  
Leonila Abella ◽  
Hirofumi Hinode ◽  
Chris Salim

Catalytic performance and characterization of Ni/CeO2/ZrO2 and commercial catalyst from Indonesia were investigated in steam reforming of methane. Ni/CeO2/ZrO2 catalyst was prepared using co-impregnation of cerium nitrate and nickel nitrate onto zirconia support material. BET, SEM, EDS, XRD, TPD, TG, and ICP analyses were employed for the characterization of the catalysts. Remarkable catalytic performance of Ni/CeO2/ZrO2 catalyst at 600oC operating temperature and atmospheric pressure of about 74.9% methane conversion was obtained compared to 55.9% using the commercial catalyst. In addition, the presence of cerium in Ni/CeO2/ZrO2 was effective in improving the stability and resistance to coke formation. Less carbon formation was confirmed from the thermo-gravimetric analysis. These results showed that the prepared catalyst is promising in the industrial application which can be used at lower operation temperature for energy saving.


Catalysts ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 215 ◽  
Author(s):  
Penghe Su ◽  
Ya Chen ◽  
Xiaotong Liu ◽  
Hongyuan Chuai ◽  
Hongchi Liu ◽  
...  

A simple and practical Rh-catalyzed hydroformylation of vinyl acetate has been synthesized via impregnation-calcination method using silicate nanotubes (MgSNTs) as the supporter. The Rh0 (zero valent state of rhodium) was obtained by calcination. The influence of calcination temperature on catalytic performance of the catalysts was investigated in detail. The catalysts were characterized in detail by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectrometer (XPS), atomic emission spectrometer (ICP), and Brunauer–Emmett–Teller (BET) surface-area analyzers. The Rh/MgSNTs(a2) catalyst shows excellent catalytic activity, selectivity and superior cyclicity. The catalyst could be easily recovered by phase separation and was used up to four times.


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