scholarly journals Nickel nanoparticles supported on a covalent triazine framework as electrocatalyst for oxygen evolution reaction and oxygen reduction reactions

2020 ◽  
Vol 11 ◽  
pp. 770-781
Author(s):  
Secil Öztürk ◽  
Yu-Xuan Xiao ◽  
Dennis Dietrich ◽  
Beatriz Giesen ◽  
Juri Barthel ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxygen Reduction ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Nickel Nanoparticles ◽  
Reduction Reaction ◽  
High Catalytic Activity ◽  
Potential Candidate ◽  
Half Wave ◽  
Covalent Triazine Framework

Covalent triazine frameworks (CTFs) are little investigated, albeit they are promising candidates for electrocatalysis, especially for the oxygen evolution reaction (OER). In this work, nickel nanoparticles (from Ni(COD)2) were supported on CTF-1 materials, which were synthesized from 1,4-dicyanobenzene at 400 °C and 600 °C by the ionothermal method. CTF-1-600 and Ni/CTF-1-600 show high catalytic activity towards OER and a clear activity for the electrochemical oxygen reduction reaction (ORR). Ni/CTF-1-600 requires 374 mV overpotential in OER to reach 10 mA/cm2, which outperforms the benchmark RuO2 catalyst, which requires 403 mV under the same conditions. Ni/CTF-1-600 displays an OER catalytic activity comparable with many nickel-based electrocatalysts and is a potential candidate for OER. The same Ni/CTF-1-600 material shows a half-wave potential of 0.775 V for ORR, which is slightly lower than that of commercial Pt/C (0.890 V). Additionally, after accelerated durability tests of 2000 cycles, the material showed only a slight decrease in activity towards both OER and ORR, demonstrating its superior stability.

Single crystalline thallium rhodium oxide pyrochlore for highly improved round trip efficiency of hybrid Na–air batteries

2018 ◽  
Vol 47 (42) ◽  
pp. 15217-15225 ◽  
Author(s):  
Myeongjin Kim ◽  
Hyun Ju ◽  
Jooheon Kim
Keyword(s):  
Catalytic Activity ◽  
Electron Transport ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Reduction Reaction ◽  
Oxidation Potential ◽  
Round Trip ◽  
Rhodium Oxide

Tl2Rh2O7 nanoparticles are developed for effective bifunctional electrocatalysts for the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). The favorable oxidation potential of Tl and Rh ions means that they can easily donate their electrons, improving the electron transport and bifunctional catalytic activity.

Metal free-covalent triazine frameworks as oxygen reduction reaction catalysts – structure–electrochemical activity relationship

2021 ◽  
Author(s):  
Turgut Sönmez ◽  
Kendra Solveig Belthle ◽  
Andree Iemhoff ◽  
Jan Uecker ◽  
Jens Artz ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Reduction Reaction ◽  
High Catalytic Activity ◽  
Carbon Electrode ◽  
Metal Free ◽  
Covalent Triazine Framework

A covalent triazine framework coated on glassy carbon electrode performs high catalytic activity towards the ORR.

Recent progress in pristine MOF-based catalysts for electrochemical hydrogen evolution, oxygen evolution and oxygen reduction

2021 ◽  
Author(s):  
Lili Fan ◽  
Zixi Kang ◽  
Mengfei Li ◽  
Daofeng Sun
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Hydrogen Evolution ◽  
Oxygen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Oxygen Evolution Reaction ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Reduction Reaction ◽  
Metal Organic

Among various kinds of materials that have been investigated as electrocatalysts for hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and oxygen reduction reaction (ORR), metal-organic frameworks (MOFs) emerge as...

Tunable mesoporous manganese oxide for high performance oxygen reduction and evolution reactions

2016 ◽  
Vol 4 (2) ◽  
pp. 620-631 ◽  
Author(s):  
Islam M. Mosa ◽  
Sourav Biswas ◽  
Abdelhamid M. El-Sawy ◽  
Venkatesh Botu ◽  
Curtis Guild ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Manganese Oxide ◽  
Oxygen Reduction ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
High Performance ◽  
Reduction Reaction ◽  
Noble Metal Catalysts ◽  
Highly Active ◽  
State Of Art

Understanding the origin of manganese oxide activity for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is a key step towards rationally designing of highly active catalysts capable of competing with the widely used, state-of-art noble metal catalysts.

Engineering Mn Atomic Sites in Multi-Dimensional Nitrogen-Doped Carbon for Highly Efficient Oxygen Reduction Reaction

2022 ◽  
Author(s):  
Huixin Ma ◽  
Daijie Deng ◽  
Honghui Zhang ◽  
Feng Chen ◽  
Junchao Qian ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Reduction Reaction ◽  
Single Atom ◽  
Two Dimensional ◽  
One Dimensional ◽  
Nitrogen Doped ◽  
Half Wave ◽  
Nitrogen Doped Carbon

Nitrogen-coordinated single-atom manganese in multi-dimensional nitrogen-doped carbon electrocatalysts (Mn-NC) was successful constructed by combing two-dimensional nanosheets and one-dimensional nanofibers. The Mn-NC exhibited excellent oxygen reduction reaction catalytic activity with half-wave...

PtNiFe Nanoalloys with Co-existence of Energy-optimized Active surfaces for Synergistic Catalysis of Oxygen Reduction and Evolution

2021 ◽  
Author(s):  
wei yang ◽  
Wenbin Gong ◽  
Yanhong Shi ◽  
Xiaona Wang ◽  
Yulian Wang ◽  
...  
Keyword(s):  
Transition Metals ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Reduction Reaction ◽  
Synergistic Catalysis ◽  
Active Surfaces

Platinum nanocatalysts mediated by 3d transition metals show improved activity for oxygen reduction reaction (ORR) but poor activity for oxygen evolution reaction (OER). Herein, we report the preparation of a...

scholarly journals Effect of Pyrolysis Conditions on the Performance of Co–Doped MOF–Derived Carbon Catalysts for Oxygen Reduction Reaction

Catalysts ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1163
Author(s):  
Ning Cui ◽  
Kexiao Bi ◽  
Wei Sun ◽  
Qianqian Wu ◽  
Yinan Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Heating Rate ◽  
Reduction Reaction ◽  
Half Wave ◽  
Step Heating ◽  
The Stability ◽  
Carbon Catalysts ◽  
Co Doped

MOF–derived porous carbon is a type of promising catalyst to replace expensive Pt–based catalysts for oxygen reduction reaction (ORR). The catalytic activity for ORR depends closely on pyrolysis conditions. In this work, a Co–doped ZIF–8 material was chosen as a research object. The effect of pyrolysis conditions (temperature, heating rate, two–step heating) on the ORR performance of ZIF–derived carbon catalysts was systematically studied. The Co–ZIF–8 catalyst carbonized at 900 °C exhibits better ORR catalytic activity than that carbonized at 800 °C and 1000 °C. Moreover, a low heating rate can enhance catalytic activity. Two–step pyrolysis is proven to be an effective way to improve the performance of catalysts. Reducing the heating rate in the low–temperature stage is more beneficial to the ORR performance, compared to the heating rate in the high–temperature stage. The results show that the Co–ZIF–8 catalyst exhibits the best performance when the precursor was heated to 350 °C at 2 °C/min, and then heated to 900 °C at 5 °C/min. The optimum Co–ZIF–8 catalyst shows a half–wave potential of 0.82 V and a current density of 5.2 mA·cm−2 in 0.1 M KOH solution. It also exhibits high content of defects and good graphitization. TEM mapping shows that Co and N atoms are highly dispersed in the polyhedral carbon skeleton. However, two–step pyrolysis has no significant effect on the stability of the catalyst.

Enhanced Activity towards Oxygen Electrocatalysis for Rechargeable Zn-Air Batteries by Alloying Fe and Co in N-doped Carbon

2021 ◽  
Author(s):  
Fengjiao Yu ◽  
Qi Ying ◽  
Shaofeng Ni ◽  
Chenxue Li ◽  
Daxiang Xue ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Oxygen Evolution ◽  
Oxygen Evolution Reaction ◽  
Noble Metals ◽  
Large Scale ◽  
Low Cost ◽  
Reduction Reaction ◽  
Enhanced Activity ◽  
Feco Nanoparticles

Large-scale application of rechargeable Zn-air batteries requires low-cost electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) as alternatives to noble metals. Herein, FeCo nanoparticles embedded in N-doped...

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