scholarly journals Microstructural and plasmonic modifications in Ag–TiO2 and Au–TiO2 nanocomposites through ion beam irradiation

2014 ◽  
Vol 5 ◽  
pp. 1419-1431 ◽  
Author(s):  
Venkata Sai Kiran Chakravadhanula ◽  
Yogendra Kumar Mishra ◽  
Venkata Girish Kotnur ◽  
Devesh Kumar Avasthi ◽  
Thomas Strunskus ◽  
...  

The development of new fabrication techniques of plasmonic nanocomposites with specific properties is an ongoing issue in the plasmonic and nanophotonics community. In this paper we report detailed investigations on the modifications of the microstructural and plasmonic properties of metal–titania nanocomposite films induced by swift heavy ions. Au–TiO2 and Ag–TiO2 nanocomposite thin films with varying metal volume fractions were deposited by co-sputtering and were subsequently irradiated by 100 MeV Ag8+ ions at various ion fluences. The morphology of these nanocomposite thin films before and after ion beam irradiation has been investigated in detail by transmission electron microscopy studies, which showed interesting changes in the titania matrix. Additionally, interesting modifications in the plasmonic absorption behavior for both Au–TiO2 and Ag–TiO2 nanocomposites were observed, which have been discussed in terms of ion beam induced growth of nanoparticles and structural modifications in the titania matrix.

2016 ◽  
Vol 7 (3) ◽  
pp. 172-179 ◽  
Author(s):  
B. A. Gurovich ◽  
K. E. Prikhodko ◽  
M. A. Tarkhov ◽  
A. G. Domantovsky ◽  
D. A. Komarov ◽  
...  

Author(s):  
R. Rathika ◽  
M. Kovendhan ◽  
D. Paul Joseph ◽  
A. Sendil Kumar ◽  
K. Vijayarangamuthu ◽  
...  

2020 ◽  
Vol 52 (11) ◽  
pp. 2585-2593 ◽  
Author(s):  
R. Rathika ◽  
M. Kovendhan ◽  
D. Paul Joseph ◽  
Rekha Pachaiappan ◽  
A. Sendil Kumar ◽  
...  

2014 ◽  
Vol 116 (4) ◽  
pp. 043517 ◽  
Author(s):  
Pragati Kumar ◽  
Nupur Saxena ◽  
Vinay Gupta ◽  
Fouran Singh ◽  
Avinash Agarwal

2020 ◽  
Vol 27 (09) ◽  
pp. 1950214 ◽  
Author(s):  
A. ATTA ◽  
A. M. ABDEL REHEEM ◽  
E. ABDELTWAB

Polymer nanocomposites composed of zinc oxide nanoparticles (ZnO NPs)-doped polyvinyl alcohol (PVA) polymer matrix have been synthesized using solvent casting preparation method. The ZnO/PVA polymer nanocomposite films are irradiated with different argon ion beam fluences using broad-beam ion source. The prepared films are characterized using X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and UV–visible spectroscopy. The XRD shows that ZnO NPs are successfully formed on PVA polymer and the mean size of ZnO NPs is 31.2[Formula: see text]nm. The FTIR peaks indicate that ZnO NPs are attached to the polymer chains, whereas the SEM analysis shows that ZnO NPs are homogeneously dispersed into the PVA polymer surface. The optical bandgap, band tail width and number of carbon atoms in cluster are obtained and discussed using UV–visible spectroscopy. The transmittance is shown with low transmittance intensity in the UV region with the addition of ZnO NPs and ion beam irradiation. The optical bandgap [Formula: see text] showed significant decrease from 5.25[Formula: see text]eV for pristine PVA to 3.10[Formula: see text]eV by adding ZnO and from 3.10[Formula: see text]eV for un-irradiated ZnO/PVA to 2.98[Formula: see text]eV after being irradiated by [Formula: see text][Formula: see text]cm[Formula: see text]. The number of carbon atoms in cluster [Formula: see text] is increased by ZnO addition, whereas the Urbach energy [Formula: see text] is decreased. These results confirmed that there are significant modifications in PVA polymer, and the produced flexible ZnO/PVA is a good polymer nanocomposite film for technological applications.


2010 ◽  
Vol 165 (12) ◽  
pp. 930-937 ◽  
Author(s):  
Aditya Sharma ◽  
K. D. Verma ◽  
Mayora Varshney ◽  
Devendra Singh ◽  
Moti Singh ◽  
...  

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