scholarly journals Nanoscale electrochemical response of lithium-ion cathodes: a combined study using C-AFM and SIMS

2018 ◽  
Vol 9 ◽  
pp. 1623-1628 ◽  
Author(s):  
Jonathan Op de Beeck ◽  
Nouha Labyedh ◽  
Alfonso Sepúlveda ◽  
Valentina Spampinato ◽  
Alexis Franquet ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Lithium Ion ◽  
Chemical Information ◽  
Battery Cell ◽  
Individual Layer ◽  
Analysis Techniques ◽  
Starting Point ◽  
Li Ion ◽  
The Impact

The continuous demand for improved performance in energy storage is driving the evolution of Li-ion battery technology toward emerging battery architectures such as 3D all-solid-state microbatteries (ASB). Being based on solid-state ionic processes in thin films, these new energy storage devices require adequate materials analysis techniques to study ionic and electronic phenomena. This is key to facilitate their commercial introduction. For example, in the case of cathode materials, structural, electrical and chemical information must be probed at the nanoscale and in the same area, to identify the ionic processes occurring inside each individual layer and understand the impact on the entire battery cell. In this work, we pursue this objective by using two well established nanoscale analysis techniques namely conductive atomic force microscopy (C-AFM) and secondary ion mass spectrometry (SIMS). We present a platform to study Li-ion composites with nanometer resolution that allows one to sense a multitude of key characteristics including structural, electrical and chemical information. First, we demonstrate the capability of a biased AFM tip to perform field-induced ionic migration in thin (cathode) films and its diagnosis through the observation of the local resistance change. The latter is ascribed to the internal rearrangement of Li-ions under the effect of a strong and localized electric field. Second, the combination of C-AFM and SIMS is used to correlate electrical conductivity and local chemistry in different cathodes for application in ASB. Finally, a promising starting point towards quantitative electrochemical information starting from C-AFM is indicated.

scholarly journals A New All-Solid-State Lithium-Ion Battery Working without a Separator in an Electrolyte

2018 ◽  
Author(s):  
Seonggyu Cho ◽  
Shinho Kim ◽  
Wonho Kim ◽  
Seok Kim ◽  
Sungsook Ahn
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Solid Electrolyte ◽  
System Development ◽  
Lithium Ion ◽  
Internal Resistance ◽  
Li Ion Battery ◽  
Battery Cell ◽  
Metal Anode ◽  
Li Ion

Considering the safety issues of Li ion batteries, all-solid-state polymer electrolyte has been one of the promising solutions. In this point, achieving a Li ion conductivity in the solid state electrolytes comparable to liquid electrolytes (>1 mS/cm) is particularly challenging. Employment of polyethylene oxide (PEO) solid electrolyte has not been not enough in this point due to high crystallinity. In this study, hybrid solid electrolyte (HSE) systems are designed with Li1.3Al0.3Ti0.7(PO4)3(LATP), PEO and Lithium hexafluorophosphate (LiPF6) or Lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). Hybrid solid cathode (HSC) is also designed using LATP, PEO and lithium cobalt oxide (LiCoO2, LCO)—lithium manganese oxide (LiMn2O4, LMO). The designed HSE system displays 3.0 × 10−4 S/cm (55 ℃) and 1.8 × 10−3 S/cm (23 ℃) with an electrochemical stability as of 6.0 V without any separation layer introduction. Li metal (anode)/HSE/HSC cell in this study displays initial charge capacity as of 123.4/102.7 mAh/g (55 ℃) and 73/57 mAh/g (25 °C). To these systems, Succinonitrile (SN) has been incorporated as a plasticizer for practical secondary Li ion battery system development to enhance ionic conductivity. The incorporated SN effectively increases the ionic conductivity without any leakage and short-circuits even under broken cell condition. The developed system also overcomes the typical disadvantages of internal resistance induced by Ti ion reduction. In this study, optimized ionic conductivity and low internal resistance inside the Li ion battery cell have been obtained, which suggests a new possibility in the secondary Li ion battery development.

A new approach for synthesizing bulk-type all-solid-state lithium-ion batteries

2019 ◽  
Vol 7 (16) ◽  
pp. 9748-9760 ◽  
Author(s):  
Linchun He ◽  
Chao Chen ◽  
Masashi Kotobuki ◽  
Feng Zheng ◽  
Henghui Zhou ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Energy Density ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Energy Storage Devices ◽  
New Approach ◽  
Storage Devices ◽  
Safety Issues ◽  
Li Ion

All-solid-state Li-ion batteries (ASSLiB) have been considered to be the next generation energy storage devices that can overcome safety issues and increase the energy density by replacing the organic electrolyte with inflammable solid electrolyte.

scholarly journals Stochastic Expansion Planning of Various Energy Storage Technologies in Active Power Distribution Networks

2021 ◽  
Vol 13 (10) ◽  
pp. 5752
Author(s):  
Reza Sabzehgar ◽  
Diba Zia Amirhosseini ◽  
Saeed D. Manshadi ◽  
Poria Fajri
Keyword(s):  
Energy Storage ◽  
Power Distribution ◽  
Power Flow ◽  
Lithium Ion ◽  
Distribution Networks ◽  
Renewable Energy Resources ◽  
Flow Equations ◽  
Second Order Cone ◽  
Li Ion ◽  
The Cost

This work aims to minimize the cost of installing renewable energy resources (photovoltaic systems) as well as energy storage systems (batteries), in addition to the cost of operation over a period of 20 years, which will include the cost of operating the power grid and the charging and discharging of the batteries. To this end, we propose a long-term planning optimization and expansion framework for a smart distribution network. A second order cone programming (SOCP) algorithm is utilized in this work to model the power flow equations. The minimization is computed in accordance to the years (y), seasons (s), days of the week (d), time of the day (t), and different scenarios based on the usage of energy and its production (c). An IEEE 33-bus balanced distribution test bench is utilized to evaluate the performance, effectiveness, and reliability of the proposed optimization and forecasting model. The numerical studies are conducted on two of the highest performing batteries in the current market, i.e., Lithium-ion (Li-ion) and redox flow batteries (RFBs). In addition, the pros and cons of distributed Li-ion batteries are compared with centralized RFBs. The results are presented to showcase the economic profits of utilizing these battery technologies.

Real-Time Estimation of Lithium-Ion Concentration in Both Electrodes of a Lithium-Ion Battery Cell Utilizing Electrochemical–Thermal Coupling

2017 ◽  
Vol 139 (3) ◽  
Author(s):  
Satadru Dey ◽  
Beshah Ayalew
Keyword(s):  
Real Time ◽  
Unscented Kalman Filter ◽  
Lithium Ion ◽  
Time Estimation ◽  
Li Ion Battery ◽  
Battery Cell ◽  
Thermal Dynamics ◽  
Estimation Scheme ◽  
Real Time Estimation ◽  
Li Ion

This paper proposes and demonstrates an estimation scheme for Li-ion concentrations in both electrodes of a Li-ion battery cell. The well-known observability deficiencies in the two-electrode electrochemical models of Li-ion battery cells are first overcome by extending them with a thermal evolution model. Essentially, coupling of electrochemical–thermal dynamics emerging from the fact that the lithium concentrations contribute to the entropic heat generation is utilized to overcome the observability issue. Then, an estimation scheme comprised of a cascade of a sliding-mode observer and an unscented Kalman filter (UKF) is constructed that exploits the resulting structure of the coupled model. The approach gives new real-time estimation capabilities for two often-sought pieces of information about a battery cell: (1) estimation of cell-capacity and (2) tracking the capacity loss due to degradation mechanisms such as lithium plating. These capabilities are possible since the two-electrode model needs not be reduced further to a single-electrode model by adding Li conservation assumptions, which do not hold with long-term operation. Simulation studies are included for the validation of the proposed scheme. Effect of measurement noise and parametric uncertainties is also included in the simulation results to evaluate the performance of the proposed scheme.

Innovative Antriebe 2016

2016 ◽  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Electric Vehicles ◽  
Electrode Materials ◽  
Lifetime Cost ◽  
Lithium Ion ◽  
Automotive Applications ◽  
Battery Electric Vehicles ◽  
Storage Technologies ◽  
Lithium Sulfur

Rechargeable Energy Storage Technologies for Automotive Applications Abstract This paper provides an extended summary of the available relevant rechargeable energy storage electrode materials that can be used for hybrid, plugin and battery electric vehicles. The considered technologies are the existing lithium-ion batteries and the next generation technologies such as lithium sulfur, solid state, metal-air, high voltage materials, metalair and sodium based. This analysis gives a clear overview of the battery potential and characteristics in terms of energy, power, lifetime, cost and finally the technical hurdles. Inhalt Seite Vorwort 1 Alternative Energiespeicher – und Wandler S. Hävemeier, Neue Zelltechnologien und die Chance einer deutschen 3 M. Hackmann, Zellproduktion – Betrachtung von Technologie, Wirtschaft- R. Stanek lichkeit und dem Standort Deutschland N. Omar, Rechargeable Energy Storage Technologies for 7 R. Gopalakrishnan Automotive Applications – Present and Future ...

Self-Balancing by Design in Hybrid Electrochemical Battery Packs

2018 ◽  
Author(s):  
Nur Adilah Aljunid ◽  
Michelle A. K. Denlinger ◽  
Hosam K. Fathy
Keyword(s):  
Feedback Loop ◽  
Lithium Ion ◽  
Battery Pack ◽  
Hybrid Cells ◽  
Battery Cell ◽  
Battery Packs ◽  
Li Ion ◽  
Electrochemical Battery ◽  
Novel Concept ◽  
Physics Based Simulation

This paper explores the novel concept that a hybrid battery pack containing both lithium-ion (Li-ion) and vanadium redox flow (VRF) cells can self-balance automatically, by design. The proposed hybrid pack connects the Li-ion and VRF cells in parallel to form “hybrid cells”, then connects these hybrid cells into series strings. The basic idea is to exploit the recirculation and mixing of the VRF electrolytes to establish an internal feedback loop. This feedback loop attenuates state of charge (SOC) imbalances in both the VRF battery and the lithium-ion cells connected to it. This self-balancing occurs automatically, by design. This stands in sharp contrast to today’s battery pack balancing approaches, all of which require either (passive/active) power electronics or an external photovoltaic source to balance battery cell SOCs. The paper demonstrates this self-balancing property using a physics-based simulation of the proposed hybrid pack. To the best of the authors’ knowledge, this work represents the first report in the literature of self-balancing “by design” in electrochemical battery packs.

scholarly journals Lithium-ion conductivity in Li6Y(BO3)3: a thermally and electrochemically robust solid electrolyte

2016 ◽  
Vol 4 (18) ◽  
pp. 6972-6979 ◽  
Author(s):  
Beatriz Lopez-Bermudez ◽  
Wolfgang G. Zeier ◽  
Shiliang Zhou ◽  
Anna J. Lehner ◽  
Jerry Hu ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid Electrolyte ◽  
Solid Electrolytes ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Ion Diffusion ◽  
New Energy ◽  
Li Ion ◽  
Lithium Ion Conductivity ◽  
Storage Technologies

The development of new frameworks for solid electrolytes exhibiting fast Li-ion diffusion is critical for enabling new energy storage technologies.

All-Crystal-State Lithium-Ion Batteries: Innovation Inspired by Novel Flux Coating Method.

2013 ◽  
Vol 2013 (CICMT) ◽  
pp. 000187-000191
Author(s):  
Katsuya Teshima ◽  
Hajime Wagata ◽  
Shuji Oishi
Keyword(s):  
Solid State ◽  
Lithium Ion ◽  
Hybrid Vehicle ◽  
Ambient Atmosphere ◽  
Flux Method ◽  
High Quality ◽  
Active Materials ◽  
Crystal State ◽  
Coating Method ◽  
Li Ion

All-solid-state lithium-ion rechargeable batteries (LIBs) consisting of solid electrolyte materials have attracted a number of research interests because no use of organic liquid electrolyte increases packaging density and intrinsic safety of LIB, which contribute the development on environmentally-friendly automobiles such as electric vehicle (EV), hybrid vehicle (HV), and plug-in hybrid vehicle (HEV), in addition to efficient utilization of electric energy in smart grid. Among various solid electrolytes, inorganic electrolyte materials have achieved relatively high lithium-ion conductivity and better stability at an ambient atmosphere. Nevertheless, there is a drawback that is relatively high internal resistance owing to relatively slow Li ion movement caused by low crystallinity of materials, scattering at interfaces such as current collector/electrode active materials and electrode active materials/electrolyte materials. In this context, we have proposed a concept, all-crystal-state LIB, in which all the component materials have high crystallinity and those interfaces are effective for Li ion diffusion. Here, we present the fabrication of oxide crystals and crystal layers via flux method and flux coating. Flux method is one of the solution processes in which idiomorphic highly crystalline materials can be obtained under the melting point of the target ones. In addition, it provides simple, low-cost and environmentally-benign pathway compared to conventional solid-state-reaction method. Flux coating method is developed to fabricate high-quality crystal layers (films) on various substrates. High-quality crystals and crystal layers of cathode, anode and electrolyte materials were successfully fabricated.

Cationic covalent organic framework based all-solid-state electrolytes

2020 ◽  
Vol 4 (4) ◽  
pp. 1164-1173 ◽  
Author(s):  
Zhen Li ◽  
Zhi-Wei Liu ◽  
Zhen-Jie Mu ◽  
Chen Cao ◽  
Zeyu Li ◽  
...  
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolytes ◽  
Lithium Ion ◽  
Ion Conductivity ◽  
Li Ion Battery ◽  
Covalent Organic Framework ◽  
Li Ion ◽  
Lithium Ion Conductivity ◽  
Organic Framework

Two new imidazolium-based cationic COFs were synthesized and employed as all-solid electrolytes, and exhibited high lithium ion conductivity at high temperature. The assembled Li-ion battery displays preferable battery performance at 353 K.

scholarly journals Quantifying the impact of disorder on Li-ion and Na-ion transport in perovskite titanate solid electrolytes for solid-state batteries

2020 ◽  
Vol 8 (37) ◽  
pp. 19603-19611
Author(s):  
Adam R. Symington ◽  
John Purton ◽  
Joel Statham ◽  
Marco Molinari ◽  
M. Saiful Islam ◽  
...  
Keyword(s):  
Solid State ◽  
Ion Transport ◽  
Solid Electrolytes ◽  
Research Interest ◽  
Considerable Research ◽  
Solid State Batteries ◽  
Li Ion ◽  
All Solid State Batteries ◽  
And Performance ◽  
The Impact

Solid electrolytes for all-solid-state batteries are generating considerable research interest as a means to improving their safety, stability and performance.

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