Selectively fluorinated cyclohexane building blocks: Derivatives of carbonylated all-cis-3-phenyl-1,2,4,5-tetrafluorocyclohexane
2015 ◽
Vol 11
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pp. 2671-2676
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Keyword(s):
Palladium catalysed carbonylation reactions using the meta- and para-iodo derivatives of all-cis-3-phenyl-1,2,4,5-tetrafluorocyclohexane (4) are illustrated as the start point for a variety of functional group interconversions. The resultant benzaldehyde and benzoic acids offer novel building blocks for further derivatisation and facilitate the incorporation of the facially polarised all-cis-1,2,4,5-tetrafluorocyclohexane motif into more advanced molecular scaffolds.
1985 ◽
Vol 20
(2)
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pp. 36-43
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2019 ◽
Vol 16
(7)
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pp. 653-688
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1982 ◽
Vol 12
(2)
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pp. 197-204
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1989 ◽
Vol 28
(4)
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pp. 447-448
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Keyword(s):