scholarly journals Bromination of hydrocarbons with CBr4, initiated by light-emitting diode irradiation

2013 ◽  
Vol 9 ◽  
pp. 1663-1667 ◽  
Author(s):  
Yuta Nishina ◽  
Bunsho Ohtani ◽  
Kotaro Kikushima

The bromination of hydrocarbons with CBr4 as a bromine source, induced by light-emitting diode (LED) irradiation, has been developed. Monobromides were synthesized with high efficiency without the need for any additives, catalysts, heating, or inert conditions. Action and absorption spectra suggest that CBr4 absorbs light to give active species for the bromination. The generation of CHBr3 was confirmed by NMR spectroscopy and GC–MS spectrometry analysis, indicating that the present bromination involves the homolytic cleavage of a C–Br bond in CBr4 followed by radical abstraction of a hydrogen atom from a hydrocarbon.

2021 ◽  
pp. 2101137
Author(s):  
Lei Cai ◽  
Jungui Zhou ◽  
Guilin Bai ◽  
Jiaqing Zang ◽  
Abdelhamid El‐Shaer ◽  
...  

2003 ◽  
Vol 200 (1) ◽  
pp. 102-105 ◽  
Author(s):  
Hisao Sato ◽  
Hong-Xing Wang ◽  
Daisuke Sato ◽  
Ryohei Takaki ◽  
Naoki Wada ◽  
...  

2018 ◽  
Vol 10 (50) ◽  
pp. 43291-43298 ◽  
Author(s):  
Yi Zhu ◽  
Ziyuan Li ◽  
Linglong Zhang ◽  
Bowen Wang ◽  
Zhenqing Luo ◽  
...  

2021 ◽  
Vol 9 ◽  
Author(s):  
Wenqing Zhu ◽  
Kuangyu Ding ◽  
Chen Yi ◽  
Ruilin Chen ◽  
Bin Wei ◽  
...  

In this study, we have synthesized the molybdenum sulfide quantum dots (MoS2 QDs) and zinc sulfide quantum dots (ZnS QDs) and demonstrated a highly efficient green phosphorescent organic light-emitting diode (OLED) with hybrid poly (3,4-ethylenedioxythiophene)/poly (styrenesulfonate) (PEDOT:PSS)/QDs hole injection layer (HIL). The electroluminescent properties of PEDOT:PSS and hybrid HIL based devices were explored. An optimized OLED based on the PEDOT:PSS/MoS2 QDs HIL exhibited maximum current efficiency (CE) of 72.7 cd A−1, which shows a 28.2% enhancement as compared to counterpart with single PEDOT:PSS HIL. The higher device performance of OLED with hybrid HIL can be attributed to the enhanced hole injection capacity and balanced charge carrier transportation in the OLED devices. The above analysis illustrates an alternative way to fabricate the high efficiency OLEDs with sulfide quantum dots as a HIL.


2015 ◽  
Vol 3 (17) ◽  
pp. 4283-4289 ◽  
Author(s):  
Zhan Chen ◽  
Xiao-Ke Liu ◽  
Cai-Jun Zheng ◽  
Jun Ye ◽  
Xin-Yang Li ◽  
...  

High-efficiency hybrid white organic light-emitting diode enabled by a new blue fluorophor.


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