scholarly journals Dry Oxidation and Vacuum Annealing Treatments for Tuning the Wetting Properties of Carbon Nanotube Arrays

Author(s):  
Adrianus Indrat Aria ◽  
Morteza Gharib
2012 ◽  
Vol 1407 ◽  
Author(s):  
Adrianus I. Aria ◽  
Morteza Gharib

ABSTRACTIn this study, the effect of dry oxidation on the electrochemical properties of carbon nanotube arrays is investigated. Oxygenated surface functional groups were introduced to the arrays by oxygen plasma treatment, where their surface concentrations were varied by controlling the exposure time. The finding presented herein shows an augmentation of nearly thirty times in term of specific capacitance when the arrays are oxidized. Similar behavior is also observed in the non-aqueous electrolytes where the specific capacitance of the oxidized carbon nanotube arrays is measured more than three times higher than that of the pristine ones. However, overexposure to oxygen plasma treatment reverses this effect. At such high oxidation level, the damage to the graphitic structure becomes more pronounced such that the capacitive behavior of the arrays is overshadowed by their resistive behavior. These findings are important for further development of carbon nanotube based electrochemical capacitors.


2021 ◽  
Author(s):  
Jeonyoon Lee ◽  
Luiz H. Acauan ◽  
Estelle Kalfon-Cohen ◽  
Seth S. Kessler ◽  
Brian L. Wardle

Nanoscale ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 261-271
Author(s):  
Ashley L. Kaiser ◽  
Dale L. Lidston ◽  
Sophie C. Peterson ◽  
Luiz H. Acauan ◽  
Stephen A. Steiner ◽  
...  

Aligned carbon nanotube (CNT) array adhesion strength evolves with CNT process time, decreasing and then increasing during growth and annealing, as captured by models relating CNT diameter, array effective modulus, and CNT–substrate work of adhesion.


Nanomaterials ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 1810
Author(s):  
Mengjie Li ◽  
Qilong Wang ◽  
Ji Xu ◽  
Jian Zhang ◽  
Zhiyang Qi ◽  
...  

Due to the high field enhancement factor and photon-absorption efficiency, carbon nanotubes (CNTs) have been widely used in optically induced field-emission as a cathode. Here, we report vertical carbon nanotube arrays (VCNTAs) that performed as high-density electron sources. A combination of high applied electric field and laser illumination made it possible to modulate the emission with laser pulses. When the bias electric field and laser power density increased, the emission process is sensitive to a power law of the laser intensity, which supports the emission mechanism of optically induced field emission followed by over-the-barrier emission. Furthermore, we determine a polarization dependence that exhibits a cosine behavior, which verifies the high possibility of optically induced field emission.


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