Is the Uranium Content in Black Shale a Suitable Parameter to Assess the Alteration of Organic Matter and Petroleum Potential?

Author(s):  
H. Schulz
Minerals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 793
Author(s):  
Shuangbiao Han ◽  
Yuanlong Zhang ◽  
Jie Huang ◽  
Yurun Rui ◽  
Zhiyuan Tang

The black shale deposited in the Niutitang Formation and its adjacent strata is considered to be a favorable source rock in northern Guizhou of south China and has become a target horizon for shale gas exploration in recent years. Based on SQ-1 and CY-1 core samples, the organic matter properties and geochemical elements were obtained through experimental analysis. Provenance, paleoredox, paleoclimate, paleoproductivity and deposition conditions were analyzed, and the sedimentary effects on organic matter enrichment were discussed. The results show that total organic carbon (TOC) is between 0.22–10.10 wt.% in SQ-1, with an average of 2.60 wt.%, and TOC is between 0.23–7.7 wt.% in CY-1, with an average of 1.45 wt.%. The geochemical data of the samples indicate that the black shale of the Niutitang Formation and adjacent strata are deposited in the tectonic background of the passive continental margin. The provenance shows moderate weathering, with hot and humid paleoenvironmental characteristics and fast deposition rate. Using multiple ancient redox indicators, it is concluded that the formation has undergone changes in the oxidizing environment and anaerobic environment during deposition. According to the (La/Yb)N value (the average value of SQ-1 is 1.23 and the average value of CY-1 is 1.26), it shows a faster deposition rate of the two wells and shortens the residence time of organic matter in the microbial degradation zone. The Babio indicates that the bottom has a high paleoproductivity when deposited. Considering the influencing factors, the paleoproductivity mainly controls the organic matter enrichment, followed by ancient redox conditions and the deposition rate. The research results provide a reference for deepening sedimentary understanding and shale gas exploration in the study area.


1999 ◽  
Vol 39 (1) ◽  
pp. 322 ◽  
Author(s):  
G.M. Carlsen ◽  
S.N. Apak ◽  
K.A.R. Ghori K. Grey ◽  
M.K. Stevens

The sedimentology, palaeontology and geochemistry of Neoproterozoic, organic-rich, clastic and related carbonate deposits in Western Australia provide new insights into the first-order depositional controls on hydrocarbon source rocks in the Neoproterozoic. Organic facies are correlated with depositional facies, revealing the impact of organic productivity and transport of organic rich sediments on the accumulation of organic matter in different depositional environments. Sedimentation is largely limited to ramp, platform, shoal, lagoon and sabkha environments.Growth of benthic organisms in the photic zone was the primary process controlling the production of organic matter in the ramp-shoreline system of the Kanpa Formation. Storms and floods were the primary mechanism for moving organic rich sediments into dysoxic and anoxic depositional environments. Variations in organic facies are indicated by: 1) changes in the palynomorph assemblages, particularly the increase in acritarchs within shallow-water ramp facies and cyanobacterial filaments in quiet-water sediments; 2) organic-rich laminae, containing abundant cyanobacterial filaments and mat material; and 3) the oxidation state of preserved organic remains.Periods of high organic growth rates or periods of mass mortality may have led to the development of an anoxic zone at the water-sediment interface. In the shoal and lagoonal settings, higher rates of clastic sediment dilution combined with oxygenated conditions resulted in lower TOC and hydrogen depleted organic facies.Condensed sections overlying stromatolitic dolomites represent the most effective organic facies of all of the potential source laminae sampled in Empress–IA. Most of the Officer Basin succession is currently within the oil-generating window and hydrocarbon shows encourage further exploration.


2014 ◽  
Vol 962-965 ◽  
pp. 203-207 ◽  
Author(s):  
Ping Li ◽  
Zheng Qi Xu ◽  
Ye Wang ◽  
Peng Chong Wang

The 373 deposit,as a typical carbonanceous-siliceous-pelitic rock type uranium deposit,is rich in organic matter and pyrite.Close relationships exist between organic matter and uranium mineralization in a lot of uranium deposits. But few people have studied the relationship between uranium mineralization and organic matter of carbonanceous-siliceous-pelitic rock type uranium deposit.The organic matter type of 373 uranium deposit is type-II2.The sources of organic matter are mainly marine plankton,microbial and terrestrial plant. The organic maturity is relatively low,at the immature-low mature stage.Compared with the surrounding rock ,the ore has gone through higher paletemperature on account of hydrothermal and fault. The type and the maturity of organic matter result in the generation of large amount of humic acid during thermal evolution that could be preserved in strata. The contents of chloroform bitumen “A” of organic matter in the mineralized layer are 0.47—10.42ug/g .Asphaltene is the main component of chloroform bitumen “A”.The correlation between chloroform bitumen “A” and uranium content is high,as well as the correlation between the content of asphaltene and uranium content. Study shows that the functions of organic matter in 373 uranium deposit are mainly adsorption,complexation and reduction.


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