New insights into organic matter accumulation from high-resolution geochemical analysis of a black shale: Middle and Upper Devonian Horn River Group, Canada

Organic matter (OM) accumulation in organic matter-rich mudstones, or black shales, is generally recognized to be controlled by combinations of bioproductivity, preservation, and dilution. However, specific triggers of OM deposition in these formations are commonly difficult to identify with geochemical proxies, in part because of feedbacks that cause geochemical proxies for these controls to vary synchronously. This apparent synchronicity is partly a function of sample spacing, commonly at decimeter to meter intervals, which may represent longer periods of time than is required for the development of feedbacks. Higher resolution data sets may be required to fully interpret OM accumulation. This study applies a novel combination of technologies to develop a high-resolution geochemical data set, integrating energy-dispersive X-ray fluorescence (EDXRF) and infrared imagery analyses, to record proxies for redox conditions, bioproductivity, and clastic and carbonate dilution in millimeter-resolution profiles of 133 core slabs from the Middle and Upper Devonian Horn River shale in the Western Canada Sedimentary Basin, which provides decadal-scale temporal resolution. A comparison to a more coarsely sampled data set from the same core results in substantially different interpretations of variations in bioproductivity, redox, and dilution proxies. Stratigraphic distributions of organic matter accumulation patterns (bioproductivity-control, siliciclastic/carbonate-dilution, and redox conditions-control) show that organic enrichment events were highly varied during deposition of the shale and were closely related to second- and third-order sea-level changes. High-resolution profiles indicate that bioproductivity was the predominant trigger for organic matter accumulation in a second-order highstand, particularly during deposition of third-order transgressive systems tracts. Organic matter accumulation was largely controlled by dilution from either carbonate or clastic sediments in a second-order lowstand. Bioproductivity-redox feedbacks developed on timescales of decades to centuries.

Reconstruction of the last cretaceous anoxic event in the Tarfaya Laayoune basin (South of Morocco): Biostratigraphy and Paleoenvironment of the Oum Debaa Formation

The Tarfaya-Laayoune coastal basin developed in a stable passive margin, where sedimentation occurred in shallow bays. During the Late Cretaceous, bituminous and phosphatic series were deposited in the shallow depression such as Sebkha Oum Debaa. In this work, the age of these Cretaceous layers are refined using a palynological approach and their paleoenvironments are described using organic geochemistry. Based on quantitative and qualitative palynological analyses, the sediments revealed a rich and diverse dinoflagellate cyst assemblage (65 taxa); among them 9 important biostratigraphic markers: Andalusiella inflata, Andalusiella ivoirensis, Andalusiella mauthei, Cerodinium diebelii, Cerodinium speciosum, Dinogymnium acuminatum, Odontochitina porifera, Trichodinium castanea, and Trithyrodinium evittii. According to the reported stratigraphic dinoflagellate taxa distribution, an age range of late Campanian to early Maastrichtian is herein proposed for the Oum Debaa Formation. This biostratigraphy update has been correlated to the Tethyan and Sub-Boreal domains. On the paleoenvironmental level, geochemical proxies have displayed an anoxic lagoon depositional which is dominated by an intermediate climate between hot / humid and arid with an often low paleoproductivity regime which induces redox conditions.

Early to middle Eocene calcareous nannofossils of the SW Pacific: Paleobiogeography and paleoclimate

<p>Earth’s climate underwent a long-term warming trend from the late Paleocene to early Eocene (~58–51 Ma), with global temperature reaching a sustained maximum during the Early Eocene Climatic Optimum (EECO; 53–50 Ma). Geochemical proxies indicate tropical or warm subtropical sea-surface temperature (SST) conditions in middle and high latitudes in the early Eocene, implying a very low latitudinal temperature gradient. This study investigates whether calcareous nannofossil assemblages in the southwest (SW) Pacific provide evidence of these conditions at middle latitudes in the early to middle Eocene, particularly during the EECO. Specifically, this study documents the biogeographic changes of warm- and cold-water nannofossil species along a paleolatitudinal transect through the EECO to track changes in water masses/ocean circulation at that time. Early to middle Eocene calcareous nannofossil assemblages were examined from four sites along a latitudinal transect in the SW Pacific, extending from Lord Howe Rise in the north to Campbell Plateau in the south and spanning a paleolatitude of ~46–54°S. All of the sections studied in this project span nannofossil zones NP10–16 (Martini, 1971). The data indicate up to three regional unconformities through the sections: at mid-Waipara, Deep Sea Drilling Project (DSDP) Site 207 and 277, part or all of Zone NP10 (lower Waipawan) is missing; at Sites 207 and 277 a possible hiatus occurs within NP12 (upper Waipawan–lower Mangaorapan); and at all sites part or all of Zone NP15 (lower Bortonian) is missing. Results of this study indicate that nannofossil assemblages in the SW Pacific are more similar to floras at temperate to polar sites rather than those at tropical/subtropical sites. However, variations in the relative abundance of key species in the SW Pacific are broadly consistent with the trends seen in the geochemical proxy records: an increase in warm-water taxa coincided with the EECO, corroborating geochemical evidence for a temperature maximum in the SW Pacific during this interval. The increase in the abundance and diversity of warm-water taxa and decrease in the abundance of cool-water taxa through the EECO supports previous suggestions that a warm-water mass (northward of the proto-Tasman Front) extended to ~55°S paleolatitude during this interval in response to enhanced poleward heat transport and intensification of the proto-East Australian Current. At the southernmost site, DSDP Site 277, a relatively short-lived influx of warm-water taxa at ~51 Ma suggests that warm waters expanded south at this time. However, greater diversity and abundance of warm-water taxa throughout the EECO at DSDP Site 207, suggests that the proto-East Australian Current exerted greater influence at this latitude for a longer duration than at Site 277. An increase in the abundance of cool-water taxa and decrease in diversity and abundance of warm-water taxa at all sites is recorded following the termination of the EECO. This corresponds with the contraction of the proto-Tasman Front due to weakened proto-East Australian Current flow and associated amplification of the proto-Ross Gyre. Previous estimates of SSTs from geochemical proxies in the SW Pacific during the EECO indicate that there was virtually no latitudinal temperature gradient and temperatures were tropical to subtropical (>20°C). However, nannofossil data from this study indicate warm temperate conditions (~15–20°C) during the EECO, suggesting that a reduced latitudinal gradient was maintained through this interval, which is in agreement with climate models.</p>

Early to middle Eocene calcareous nannofossils of the SW Pacific: Paleobiogeography and paleoclimate

<p>Earth’s climate underwent a long-term warming trend from the late Paleocene to early Eocene (~58–51 Ma), with global temperature reaching a sustained maximum during the Early Eocene Climatic Optimum (EECO; 53–50 Ma). Geochemical proxies indicate tropical or warm subtropical sea-surface temperature (SST) conditions in middle and high latitudes in the early Eocene, implying a very low latitudinal temperature gradient. This study investigates whether calcareous nannofossil assemblages in the southwest (SW) Pacific provide evidence of these conditions at middle latitudes in the early to middle Eocene, particularly during the EECO. Specifically, this study documents the biogeographic changes of warm- and cold-water nannofossil species along a paleolatitudinal transect through the EECO to track changes in water masses/ocean circulation at that time. Early to middle Eocene calcareous nannofossil assemblages were examined from four sites along a latitudinal transect in the SW Pacific, extending from Lord Howe Rise in the north to Campbell Plateau in the south and spanning a paleolatitude of ~46–54°S. All of the sections studied in this project span nannofossil zones NP10–16 (Martini, 1971). The data indicate up to three regional unconformities through the sections: at mid-Waipara, Deep Sea Drilling Project (DSDP) Site 207 and 277, part or all of Zone NP10 (lower Waipawan) is missing; at Sites 207 and 277 a possible hiatus occurs within NP12 (upper Waipawan–lower Mangaorapan); and at all sites part or all of Zone NP15 (lower Bortonian) is missing. Results of this study indicate that nannofossil assemblages in the SW Pacific are more similar to floras at temperate to polar sites rather than those at tropical/subtropical sites. However, variations in the relative abundance of key species in the SW Pacific are broadly consistent with the trends seen in the geochemical proxy records: an increase in warm-water taxa coincided with the EECO, corroborating geochemical evidence for a temperature maximum in the SW Pacific during this interval. The increase in the abundance and diversity of warm-water taxa and decrease in the abundance of cool-water taxa through the EECO supports previous suggestions that a warm-water mass (northward of the proto-Tasman Front) extended to ~55°S paleolatitude during this interval in response to enhanced poleward heat transport and intensification of the proto-East Australian Current. At the southernmost site, DSDP Site 277, a relatively short-lived influx of warm-water taxa at ~51 Ma suggests that warm waters expanded south at this time. However, greater diversity and abundance of warm-water taxa throughout the EECO at DSDP Site 207, suggests that the proto-East Australian Current exerted greater influence at this latitude for a longer duration than at Site 277. An increase in the abundance of cool-water taxa and decrease in diversity and abundance of warm-water taxa at all sites is recorded following the termination of the EECO. This corresponds with the contraction of the proto-Tasman Front due to weakened proto-East Australian Current flow and associated amplification of the proto-Ross Gyre. Previous estimates of SSTs from geochemical proxies in the SW Pacific during the EECO indicate that there was virtually no latitudinal temperature gradient and temperatures were tropical to subtropical (>20°C). However, nannofossil data from this study indicate warm temperate conditions (~15–20°C) during the EECO, suggesting that a reduced latitudinal gradient was maintained through this interval, which is in agreement with climate models.</p>

Chemostratigraphy as a tool for sequence stratigraphy in the Devonian Hare Indian Formation in the Mackenzie Mountains and Central Mackenzie Valley, Northwest Territories, Canada

The Hare Indian Formation (HIF) is a late Eifelian to Givetian organic-rich mudstone constituting the lower portion of the Horn River Group (HRG), which has been minimally scrutinized in the literature. This paper proposes depositional environments and a sequence stratigraphic framework for the HIF. Using composition data collected via energy-dispersive X-ray fluorescence, geochemical proxies inform detrital input, silica source, and paleoredox conditions. Cross-plots and chemostratigraphic profiles of detritally sourced Al, Ti, and K and redox-sensitive Mo and V inform depositional and stratigraphic constraints. Silica proportions vary, indicating that sediment was derived from detrital and biogenic sources. Al, Ti, and K distributions increase upwards, showing increased continentally sourced minerals. Redox-sensitive metals are highest in the Bluefish Member (BM), suggesting intermittent euxinia. Based on the presence of continental and pelagic sediments, the sedimentary environment is interpreted as proximal- to mid-shelf. These proxies guide systems tract interpretations. Si and redox-sensitive metal concentrations peak higher in the BM, accompanied by lowered concentrations of Al, Ti, and K, suggesting a maximum flooding surface. At the top of the Prohibition and Bell Creek members, redox-sensitive enrichments are lower with higher concentrations of Al, Ti, and K, suggesting a maximum regressive surface. Transgression occurred during the initial deposition of the BM, followed by regression for the remainder of the HIF. The sedimentology of the HIF can be difficult to decipher; the use of chemostratigraphy supports its geological history (including sedimentation trends and a local record of relative sea level) using methods that may be applied to other fine-grained successions.

Chemical Classification of Sediments in JVX -Well, Greater Ughelli Depobelt Niger Delta Basin, Nigeria

This study evaluate the Chemical classification of sediments in JVX well, Greater Ughelli Depo belt Niger Delta Basin. Samples collected from different intervals were analyzed using geochemical proxies. Agbada Formation was suggested for the sampled intervals due to the presence of shaleand sand intercalations. lithofacies units gotten from sampled intervals are Sand, Shale and Shaly sand facies . The sands are milky in colour, translucent to opaque, medium to coarse grain, subangular to subrounded and are moderately sorted while the shales are Grey in colour,fissile with the presence of lignite streak and calcareous materials.The geochemical studies of the sediments revealed that SiO2 is the dominant oxide followed by Al2O3 and Fe2O3 which constitutes over 90% while others like CaO, K2O, TiO2, Na2O and MgO constitute 10%. The sediments were classified as Fe-shale, Fe-sand and Quartz arenite. Samples that plotted in the quartz arenites region suggests an intense degree of weathering and reworking. The SiO2/Al2O3 ratios for the sediments in the well are appreciably high indicating that the samples have been heavily weathered, evidenced from the enrichment of quartz and depletion of feldspars. Also, the relatively high concentrations of Fe2O3 and TiO2 is an indication of iron-titanium minerals such as haematite and anatase retiles.