Hydrogen Storage in Depleted Gas Fields – First Insights from Conceptual Reservoir Modelling

Author(s):  
T. Huijskes ◽  
W. Eikelenboom
2018 ◽  
Vol 8 (11) ◽  
pp. 2282 ◽  
Author(s):  
Christina Hemme ◽  
Wolfgang van Berk

Underground hydrogen storage is a potential way to balance seasonal fluctuations in energy production from renewable energies. The risks of hydrogen storage in depleted gas fields include the conversion of hydrogen to CH4(g) and H2S(g) due to microbial activity, gas–water–rock interactions in the reservoir and cap rock, which are connected with porosity changes, and the loss of aqueous hydrogen by diffusion through the cap rock brine. These risks lead to loss of hydrogen and thus to a loss of energy. A hydrogeochemical modeling approach is developed to analyze these risks and to understand the basic hydrogeochemical mechanisms of hydrogen storage over storage times at the reservoir scale. The one-dimensional diffusive mass transport model is based on equilibrium reactions for gas–water–rock interactions and kinetic reactions for sulfate reduction and methanogenesis. The modeling code is PHREEQC (pH-REdox-EQuilibrium written in the C programming language). The parameters that influence the hydrogen loss are identified. Crucial parameters are the amount of available electron acceptors, the storage time, and the kinetic rate constants. Hydrogen storage causes a slight decrease in porosity of the reservoir rock. Loss of aqueous hydrogen by diffusion is minimal. A wide range of conditions for optimized hydrogen storage in depleted gas fields is identified.


2021 ◽  
Vol 61 (2) ◽  
pp. 366
Author(s):  
Mohammad Bahar ◽  
Reza Rezaee

Depleted gas fields are considered a low-risk location for underground hydrogen storage purposes to balance seasonal fluctuations in hydrogen supply and demand. The objective of this study was to identify any significant risk of hydrogen leakages stored in depleted gas fields. The capability of the storage area in terms of sealing efficiency varies with parameters such as rate of diffusion, solubility, thickness and capillary threshold pressure of the caprock. The most common caprock are shales, which contain organic material. The solubility of hydrogen into organic material could change the petrophysical properties of the rock, such as porosity and permeability. Any changes in these petrophysical characteristics can reduce the capillary threshold pressure thus reducing the caprock efficiency for the safe storage of hydrogen. There is about 20% of the remaining gas volume in the depleted gas field, which helps to prevent brine from entering the production streamlines and maintain reservoir pressure. The characteristic data of hydrogen at different high pressures and temperatures have been evaluated and imported into the simple finite element model using the Python programming language. Most of the parameters that influence reducing the strength of the caprock are identified. Crucial parameters are the rate of diffusion, the solubility of hydrogen in kerogen, geomechanical deformation, threshold capillary pressure, long period of injection and withdrawing of hydrogen. The model shows that the native gas production with hydrogen is low due to significant density variation and mobility ratio between methane and hydrogen. Finally, a wide range of parameters and reservoir conditions has been considered for minimising the potential risks of possible leakages.


2021 ◽  
Author(s):  
Joaquim Juez-Larre ◽  
Cintia Gonçalves Machado ◽  
Hamid Yousefi ◽  
Remco Groenenberg

<p>The Netherlands is seeking ways to integrate large amounts of renewable energy production capacity (wind/solar) into its energy system, in order to reduce CO<sub>2</sub> emissions and decrease dependency on future energy imports. Currently the Netherlands uses underground gas storage (UGS) to provide flexibility to its natural gas system, and secure supply during the winter season. However, hydrogen is considered to be a potential candidate to substitute natural gas, because it is a versatile energy carrier that can be produced from renewable electricity and be used as a CO<sub>2</sub>-neutral fuel and feedstock. It can also be stored in large amounts underground. Storage of compressed hydrogen in salt caverns is a proven technology, with single-cavern storage capacities in the range of 10-100 million m<sup>3</sup>. Yet some studies on the future Dutch energy system suggest much larger volumes of hydrogen storage may be required (1 to 50 billion m<sup>3</sup>). This large storage capacity can only be practically achieved in depleted natural gas fields. UHS in gas fields is not yet a proven technology. Only some pilot projects have successfully injected small amounts of hydrogen in some available underground reservoirs. In order to make possible future development of UHS, screening methodologies are needed for the readily identification and characterization of potential underground candidates. In this study, we develop a methodology that allows assessing UHS performances of large portfolios of underground reservoirs. As a case study we use the entire portfolio of natural gas fields in the Netherlands, including three UGSs.</p><p>In a first stage of our study, we conducted a nodal analysis of the Inflow Performance Relationship (IPR) and the vertical flow performance (outflow) curves, in order to obtain a first order estimate of the potential UHS performance for each field (e.g. rates of injection/withdrawal, working/cushion gas volumes and ranges of working pressures). Results show that withdrawal performances of wells in an UHS can be 2-3 times higher than those in an UGS. High bottom-hole drawdowns and erosional velocities in the production tubing may however significantly restrict the potential flow of hydrogen. Furthermore, the working gas volume of an UHS may contain up to four times less energy than that of an UGS, if operated at the same ranges of working pressures. Secondly, we used Eclipse 300, and the geological Petrel model of some of the best candidates, to conduct a more detail analysis of their potential UHS performances and the controlling factors. For that we ran consecutive injection/withdrawal cycles at different timescales (daily-weekly-monthly), and distinct working pressure ranges and types of cushion gas (e.g. nitrogen/hydrogen). Results allow to determine the efficiency of the different operational strategies and the number of wells required to match the expected future demands of hydrogen in the Netherlands. They also show the degree of hydrogen mixing with the residual and cushion gas during each cycle. Therefore our analytical/numerical modelling approach provides a good methodology to quantify and rank potential UHS reservoir candidates, and a means to classify the potential storage capacity of the entire portfolio.</p>


2020 ◽  
Author(s):  
Jonathan Scafidi ◽  
Mark Wilkinson ◽  
Stuart Gilfillan ◽  
Niklas Heinemann

<p>Increasing the amount of renewable energy in the UK reduces greenhouse gas emissions but will also lead to intermittency of supply, especially on a seasonal timescale. Over-producing energy when demand is low and under producing when demand is high requires large-scale storage to redress the balance.  Hydrogen stored over seasonal timescales in subsurface porous rocks can act as a giant battery for the UK and is a flexible energy vector that can be used for heat, transport and electricity generation.</p><p>No large scale assessment of the hydrogen storage capacity of an industrialised region has yet been undertaken. Here, we present a novel method for calculating the hydrogen storage capacity of gas fields and saline aquifers on the UK continental shelf using data previously used to assess carbon-dioxide storage potential.</p>


2015 ◽  
Vol 53 (12) ◽  
pp. 904-910 ◽  
Author(s):  
Myoung Youp Song ◽  
Daniel R. Mumm ◽  
Young Jun Kwak ◽  
Hye Ryoung Park
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